Research article

Thermal magnetic analysis on iron ores and banded iron formations (BIFs) in the Hamersley Province: Implications of origins of magnetic minerals and iron ores

  • Received: 26 March 2023 Revised: 13 April 2023 Accepted: 20 April 2023 Published: 06 May 2023
  • The genesis models of the iron-ores hosted in banded iron formations (BIFs) in the Hamersley Province of Western Australia have been debated since the iron-ore deposits were discovered in the 1960s. The existing models considered the few physicochemical conditions for the iron-ore enrichment from BIFs. This study incorporates the latest research outcomes in conversions among the major magnetic minerals under different physicochemical conditions with the thermal magnetic analysis for BIFs and iron-ores collected from the Hamersley Province to fill the gap in knowledge highlighted by existing studies of the iron ores and BIFs. The results indicate that the high-grade hematite ores might have been undergone a physicochemical process under hydrothermal conditions between 120 ℃ and 220 ℃ during the major stage of enrichment from the original BIFs in the Brockman Iron Formation. Such physicochemical conditions would require either that the BIF units were buried 4000–5000 m underground with tilted broad channels formed by large-scale deformation in the region that facilitates hydrothermal reactions and leaching by the fluids flowing down deep to 4000–5000 m, somehow similar to the deep-seated supergene model proposed in previous works, or that the BIF units were still buried but the hydrothermal fluids coming up from deeper sources spread widely over the broad channels to ensure the high-grade hematite ores are consistently uniform over the entire deposit. The large-scale martite-goethite deposits in the Marra Mamba Iron Formation might be derived from multiple supergene phases from hematite-martite ores below 100 ℃ in the natural process of oxidization near surface, somewhat similar to the existing model for the channel iron deposits. Magnetite contained within current BIFs and iron ores was least likely derived from primary hematite in BIFs.

    Citation: William Guo. Thermal magnetic analysis on iron ores and banded iron formations (BIFs) in the Hamersley Province: Implications of origins of magnetic minerals and iron ores[J]. AIMS Geosciences, 2023, 9(2): 311-329. doi: 10.3934/geosci.2023017

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  • The genesis models of the iron-ores hosted in banded iron formations (BIFs) in the Hamersley Province of Western Australia have been debated since the iron-ore deposits were discovered in the 1960s. The existing models considered the few physicochemical conditions for the iron-ore enrichment from BIFs. This study incorporates the latest research outcomes in conversions among the major magnetic minerals under different physicochemical conditions with the thermal magnetic analysis for BIFs and iron-ores collected from the Hamersley Province to fill the gap in knowledge highlighted by existing studies of the iron ores and BIFs. The results indicate that the high-grade hematite ores might have been undergone a physicochemical process under hydrothermal conditions between 120 ℃ and 220 ℃ during the major stage of enrichment from the original BIFs in the Brockman Iron Formation. Such physicochemical conditions would require either that the BIF units were buried 4000–5000 m underground with tilted broad channels formed by large-scale deformation in the region that facilitates hydrothermal reactions and leaching by the fluids flowing down deep to 4000–5000 m, somehow similar to the deep-seated supergene model proposed in previous works, or that the BIF units were still buried but the hydrothermal fluids coming up from deeper sources spread widely over the broad channels to ensure the high-grade hematite ores are consistently uniform over the entire deposit. The large-scale martite-goethite deposits in the Marra Mamba Iron Formation might be derived from multiple supergene phases from hematite-martite ores below 100 ℃ in the natural process of oxidization near surface, somewhat similar to the existing model for the channel iron deposits. Magnetite contained within current BIFs and iron ores was least likely derived from primary hematite in BIFs.



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    [1] Blockley JG (1969) The stratigraphy of the Mount Tom Price orebody and its implication in the genesis of iron ore. Western Australia Geological Survey Annual Report 1968. Perth, Australia: Western Australia Geological Survey.
    [2] Ayers DE (1971) The hematite enrichment ores of Mount Tom Price and Mount Whaleback. Aust Inst Min Metall Proc 238: 47–58.
    [3] Trendall AF, Pepper RS (1977) Chemical composition of the Brockman Iron Formation. Perth, Australia: Western Australia Geological Survey.
    [4] Morris RC (1980) A textural and mineralogical study of the relationship of iron ore to banded iron-formation in the Hamersley iron province of Western Australia. Econ Geol 75: 184–209. https://doi.org/10.2113/gsecongeo.75.2.184 doi: 10.2113/gsecongeo.75.2.184
    [5] Kneeshaw M (1984) Pilbara iron ore classification—a proposal for a common classification for BIF-derived supergene iron ore. Australas Inst Min Metall 289: 157–162.
    [6] Guo WW (1999) Magnetic petrophysics and density investigations of the Hamersley Province, Western Australia: implications for magnetic and gravity interpretation, Australia: The University of Western Australia.
    [7] Li ZX, Guo W, Powell CMA (2000) Timing and genesis of Hamersley BIF-hosted iron deposits: a new palaeomagnetic interpretation, Perth, Australia: Minerals & Energy Research Institute of Western Australia.
    [8] Thorne WS, Hagemann SG, Barley M (2004). Petrographic and geochemical evidence for hydrothermal evolution of the North Deposit, Mt Tom Price, Western Australia. Miner Deposita 39: 766–783. https://doi.org/10.1007/s00126-004-0444-x doi: 10.1007/s00126-004-0444-x
    [9] Bodycoat FM (2010) Stratigraphic and structural setting of iron mineralization at E Deposit (East), Area C, Hamersley Province, Western Australia. Appl Earth Sci 119: 49–55. https://doi.org/10.1179/037174510X12853354810543 doi: 10.1179/037174510X12853354810543
    [10] Clark DA, Foss CA, Austin J, et al. (2015) Three-dimensional mapping of magnetite and hematite concentrations from reprocessing of detailed aeromagnetic data. Proceedings of the Iron Ore Conference, Perth, Australia.
    [11] Morris RC (1985) Genesis of iron ore in banded iron–formation by supergene and supergene–metamorphic processes—a conceptual model, In: Wolf KH, Eds., Handbook of strata–bound and stratiform ore deposits, Elsevier, 73–235.
    [12] Harmsworth RA, Kneeshaw M, Morris RC, et al. (1990) BIF-derived iron ores of the Hamersley Province. Australas Inst Min Metall Mono 14: 617–642.
    [13] Barley M, Pickard AL, Hagemann S, et al. (1999). Hydrothermal origin for the 2 billion year old Mount Tom Price giant iron ore deposit, Hamersley Province, Western Australia. Miner Deposita 34: 784–789. https://doi.org/10.1007/s001260050238 doi: 10.1007/s001260050238
    [14] Powell CMcA, Oliver NHS, Li ZX, et al. (1999) Synorogenic hydrothermal origin for giant Hamersley iron oxide ore bodies. Geology 27: 175–178. https://doi.org/10.1130/0091-7613(1999)027<0175:SHOFGH>2.3.CO;2 doi: 10.1130/0091-7613(1999)027<0175:SHOFGH>2.3.CO;2
    [15] Brocks JJ, Summons RE, Buick R, et al. (2003) Origin and significance of aromatic hydrocarbons in giant iron ore deposits of the late Archean Hamersley Basin, Western Australia. Org Geochem 34: 1161–1175. https://doi.org/10.1016/S0146-6380(03)00065-2 doi: 10.1016/S0146-6380(03)00065-2
    [16] Clout JMF (2006) Iron formation-hosted iron ores in the Hamersley Province of Western Australia. Appl Earth Sci 115: 115–125. https://doi.org/10.1179/174327506X138931 doi: 10.1179/174327506X138931
    [17] Morris RC, Kneeshaw M (2011) Genesis modelling for the Hamersley BIF-hosted iron ores of Western Australia: a critical review. Aust J Earth Sci 58: 417–451. https://doi.org/10.1080/08120099.2011.566937 doi: 10.1080/08120099.2011.566937
    [18] White AJR, Legras M, Smith RE, et al. (2014) Deformation-driven, regional-scale metasomatism in the Hamersley Basin, Western Australia. J Metamorphic Geol 32: 417–433. https://doi.org/10.1111/jmg.12078 doi: 10.1111/jmg.12078
    [19] Perring C, Crowe M, Hronsky J (2020). A new fluid-flow model for the genesis of banded iron formation-hosted martite–goethite mineralization, with special reference to the North and South Flank deposits of the Hamersley Province, Western Australia. Econ Geol 115: 627–659. https://doi.org/10.5382/econgeo.4734 doi: 10.5382/econgeo.4734
    [20] Perring CS (2021) Petrography of martite–goethite ore and implications for ore genesis, South Flank, Hamersley Province, Western Australia. Aust J Earth Sci 68: 782–798. https://doi.org/10.1080/08120099.2021.1863860 doi: 10.1080/08120099.2021.1863860
    [21] Perring CS, Hronsky JMA, Crowe M (2022) Phanerozoic history of the Pilbara region: implications for iron mineralization. Aust J Earth Sci 69: 757–775. https://doi.org/10.1080/08120099.2022.2048888 doi: 10.1080/08120099.2022.2048888
    [22] Tompkins LA, Cowan DR (2001) Opaque mineralogy and magnetic properties of selected banded iron‐formations, Hamersley Basin, Western Australia. Aust J Earth Sci 48: 427–437. https://doi.org/10.1046/j.1440-0952.2001.00869.x doi: 10.1046/j.1440-0952.2001.00869.x
    [23] Rasmussen B, Muhling JR (2018) Making magnetite late again: Evidence for widespread magnetite growth by thermal decomposition of siderite in Hamersley banded iron formations. Precambrian Res 306: 64–93. https://doi.org/10.1016/j.precamres.2017.12.017 doi: 10.1016/j.precamres.2017.12.017
    [24] Warchola T, Lalonde SV, Pecoits E, et al. (2018) Petrology and geochemistry of the Boolgeeda Iron Formation, Hamersley Basin, Western Australia. Precambrian Res 316: 155–173. https://doi.org/10.1016/j.precamres.2018.07.015 doi: 10.1016/j.precamres.2018.07.015
    [25] Guo WW (2015) Magnetic mineralogical characteristics of Hamersley iron ores in Western Australia. J App Math Phys 3: 150–155. http://dx.doi.org/10.4236/jamp.2015.32023
    [26] Blockley JG, Tehnas IJ, Mandyczewsky A, et al. (1993) Proposed stratigraphic subdivision of the Marra Mamba Iron formation and the lower Wittenoom Dolomite, Geological Survey of Western Australia Report 34. Perth, Australia: Western Australia Geological Survey.
    [27] Guo W (2023) Density investigation and implications for exploring iron-ore deposits using gravity method in the Hamersley Province, Western Australia. AIMS Geosci 9: 34–48. https://doi.org/10.3934/geosci.2023003 doi: 10.3934/geosci.2023003
    [28] Tarling DH, Hrouda F (1993) The Magnetic Anisotropy of Rocks, London, UK: Chapman & Hall.
    [29] Dunlop DJ, Ozdemir O (1997) Rock Magnetism, Cambridge University Press, Cambridge, UK: http://dx.doi.org/10.1017/CBO9780511612794
    [30] Thompson R, Oldfield E (1986) Environmental Magnetism, London, UK: Allen and Unwin. http://dx.doi.org/10.1007/978-94-011-8036-8
    [31] Hunt, CP, Moskowitz BM, Banerjee SK (1995) Magnetic properties of rocks and minerals, In Ahrens TJ, Eds., Rock Physics and Phase Relations: A Handbook of Physical Constants, Vol. 3. Washington, DC: American Geophysical Union, 189–204.
    [32] Wang L, Pan Y, Li J, et al. (2008) Magnetic properties related to thermal treatment of pyrite. Sci China Ser D-Earth Sci 51: 1144–1153. https://doi.org/10.1007/s11430-008-0083-7 doi: 10.1007/s11430-008-0083-7
    [33] Pan Y, Zhu R, Liu Q, et al. (1999) Magnetic susceptibility variation and AMS exchange related to thermal treatment of siderite. Chin Sci Bull 44: 1135–1139. https://doi.org/10.1007/BF02886143 doi: 10.1007/BF02886143
    [34] Till JL, Nowaczyk N (2018) Authigenic magnetite formation from goethite and hematite and chemical remanent magnetization acquisition. Geophys J Int 213: 1818–1831. https://doi.org/10.1093/gji/ggy083 doi: 10.1093/gji/ggy083
    [35] Ouyang T, Appel E, Jia G et al. (2013) Magnetic mineralogy and its implication of contemporary coastal sediments from South China. Environ Earth Sci 68: 1609–1617. https://doi.org/10.1007/s12665-012-1854-1 doi: 10.1007/s12665-012-1854-1
    [36] Ter Maat GW, McEnroe SA, Church NS, et al. (2019). Magnetic mineralogy and petrophysical properties of ultramafic rocks: Consequences for crustal magnetism. Geochem Geophys Geosyst 20: 1794–1817. https://doi.org/10.1029/2018GC008132 doi: 10.1029/2018GC008132
    [37] Zhao XY, Liu QS (2010) Effects of the grain size distribution on the temperature-dependent magnetic susceptibility of magnetite nanoparticles. Sci China Earth Sci 53: 1071–1078. https://doi.org/10.1007/s11430-010-4015-y doi: 10.1007/s11430-010-4015-y
    [38] Carlut J, Isambert A, Bouquerel H, et al. (2015) Low temperature magnetic properties of the Late Archean Boolgeeda iron formation (Hamersley Group, Western Australia): environmental implications. Front Earth Sci 3. https://doi.org/10.3389/feart.2015.00018 doi: 10.3389/feart.2015.00018
    [39] Henry B, Jordanova D, Jordanova N, et al. (2005) Transformations of magnetic mineralogy in rocks revealed by difference of hysteresis loops measured after stepwise heating: theory and case studies, Geophys J Int 162: 64–78. https://doi.org/10.1111/j.1365-246X.2005.02644.x doi: 10.1111/j.1365-246X.2005.02644.x
    [40] Li Z, Chanéac C, Berger G, et al. (2019) Mechanism and kinetics of magnetite oxidation under hydrothermal conditions. RSC Adv 58: 33633–33642. https://doi.org/10.1039/c9ra03234g doi: 10.1039/c9ra03234g
    [41] Zhao J, Brugger J, Pring A (2019) Mechanism and kinetics of hydrothermal replacement of magnetite by hematite. Geosci Front 10: 29–41. https://doi.org/10.1016/j.gsf.2018.05.015 doi: 10.1016/j.gsf.2018.05.015
    [42] Yu J, Han Y, Li Y, et al. (2017) Mechanism and kinetics of the reduction of hematite to magnetite with CO–CO2 in a micro-fluidized bed. Minerals 7: 209. https://doi.org/10.3390/min7110209 doi: 10.3390/min7110209
    [43] Du W, Yang S, Pan F, et al. (2017) Hydrogen reduction of hematite ore fines to magnetite ore fines at low temperatures. J Chem. https://doi.org/10.1155/2017/1919720 doi: 10.1155/2017/1919720
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