Research article

Microwave-assisted heating in a novel thin film-liquid spinning coaxial reactor


  • Received: 17 March 2024 Revised: 08 October 2024 Accepted: 05 November 2024 Published: 22 November 2024
  • This paper introduces a novel rotating reactor designed for microwave-assisted heating and chemical processes. It consists of a sealed coaxial waveguide with a dielectric hollow mixer that rotates along the length of the central conductor. A heating liquid flows in a narrow gap between this rotor and the outer shield of the coaxial waveguide, powered by microwaves. It is hypothesized that the acceleration of the conversation rate of chemical reactions is due to the excitation of micro-vortices for better mixing and the direct application of microwaves to a mix of polar reagents within the narrow gap. This study presents initial experimental results of microwave liquid heating, hydrodynamics, and mechanics in this reactor.

    Citation: Guennadi A. Kouzaev. Microwave-assisted heating in a novel thin film-liquid spinning coaxial reactor[J]. AIMS Electronics and Electrical Engineering, 2024, 8(4): 478-497. doi: 10.3934/electreng.2024023

    Related Papers:

  • This paper introduces a novel rotating reactor designed for microwave-assisted heating and chemical processes. It consists of a sealed coaxial waveguide with a dielectric hollow mixer that rotates along the length of the central conductor. A heating liquid flows in a narrow gap between this rotor and the outer shield of the coaxial waveguide, powered by microwaves. It is hypothesized that the acceleration of the conversation rate of chemical reactions is due to the excitation of micro-vortices for better mixing and the direct application of microwaves to a mix of polar reagents within the narrow gap. This study presents initial experimental results of microwave liquid heating, hydrodynamics, and mechanics in this reactor.



    加载中


    [1] Kitson PJ, Marie G, Francoia JP, Zalesskiy SS, Sigerson RC, Mathieson JS, et al. (2018) Digitization of multistep organic synthesis in reactionware for on-demand pharmaceuticals. Science 359: 314‒319. https://doi.org/10.1126/science.aao3466 doi: 10.1126/science.aao3466
    [2] Li J, Ballmer S, Gillis E, Fujii S, Schmidt M, Palazzolo A, et al. (2015) Synthesis of many different types of small organic molecules using one automated process. Science 347: 1221‒1226. https://doi.org/10.1126/science.aaa5414 doi: 10.1126/science.aaa5414
    [3] Mascia S, Heider P, Zhang H (2013) End-to-end continuous manufacturing of pharmaceuticals: integrated synthesis, purification, and final dosage formation. Angew Chem Int Ed 52: 12359‒12363. https://doi.org/10.1002/anie.201305429 doi: 10.1002/anie.201305429
    [4] Yang H, Yan B, Chen W, Fan D (2023) Prediction and innovation of sustainable continuous flow microwave processing based on numerical simulations: A systematic review. Renewable and Sustainable Energy Rev 175: 113183(1-20). https://doi.org/10.1016/j.rser.2023.113183 doi: 10.1016/j.rser.2023.113183
    [5] Wall M (2024) Watch this private Varda Space capsule's blistering return to Earth in amazing onboard video. Space Exploration. Available from: https://www.space.com/varda-in-space-manufacturing-capsule-earth-return-video
    [6] Krakos A (2024) Lab-on-chip technologies for space research — current trends and prospects. Microchimica Acta 191: 31(1-21).
    [7] Kuang S, Sign N, Wu Y, Shen Y, Ren W, Tu L, et al. (2022) Role of microfluidics in accelerating new space missions. Biomicrofluidics 16: 021503. https://doi.org/10.1063/5.0079819 doi: 10.1063/5.0079819
    [8] Nakamura K, Takayanagi T, Sato S (1989) Modified Arrhenius equation. Chem Phys Lett 160: 295‒298.
    [9] Visscher V, van der Schaaf J, Nijhuis T, Schouten JC (2013) Rotating reactors - a review. Chem Eng Res Design 91: 1929‒1940. https://doi.org/10.1016/j.cherd.2013.07.021 doi: 10.1016/j.cherd.2013.07.021
    [10] Qui Z, Zhao L, Weatherley L (2010) Process intensification technologies in continuous biodiesel production. Chem Eng Processing: Proc Intensification 49: 323‒330. https://doi.org/10.1016/j.cep.2010.03.005 doi: 10.1016/j.cep.2010.03.005
    [11] Cihonski J, Gulliver E (2014) Rapid preparation of pharmaceutical intermediates and targets using process intensification. Pharmaceuticals June 2004: 8‒12.
    [12] Hampton PD, Wealton MD, Roberts LM, Yaeger AA, Boydson R (2008) Continuous organic synthesis in a spinning tube-in-tube reactor: TEMPO-catalysed oxidation of alcohols by hypochlorite. Org Process Res Dev 12: 946‒949. https://doi.org/10.1021/op800051t doi: 10.1021/op800051t
    [13] Gonzales M, Ciszewski J (2009) High conversion, solvent-free, continuous synthesis of imidazolium ionic liquids in spinning tube-in-tube reactors. Org Process Res Dev 13: 64‒66. https://doi.org/10.1021/op8001917 doi: 10.1021/op8001917
    [14] Andereck C, Liu S, Swinney H (1986) Flow regimes in a circular Couette system with independently rotating cylinders. J Fluid Mechanics 164: 155–183. https://doi.org/10.1017/S0022112086002513 doi: 10.1017/S0022112086002513
    [15] Loupy A (Ed.) (2006) Microwaves in Organic Synthesis, Weinheim: Wiley-VCH. https://doi.org/10.1002/9783527619559
    [16] Kappe C, Stadler A, Dallinger D, (2012) Microwaves in Organic and Medicinal Chemistry, Weinheim: Wiley-VCH. https://doi.org/10.1002/3527606556
    [17] Khaghanikavkani E, Farid M, Holdem J, Williamson A (2013) Microwave pyrolysis of plastic. J Chem Eng Process Techn 4: 1000150(1-11). https://doi.org/10.1016/j.crcon.2023.03.002 doi: 10.1016/j.crcon.2023.03.002
    [18] Kouzaev G, Kapranov S (2015) Scalable reactor for microwave- and ultrasound-assisted chemistry, UK Patent Application # GB1504690.7 dated 19.03.2015. IPO Searchable Patents J 6572: May 6, 2015.
    [19] Mitani T, Hasegawa N, Nakajima R, Shinohara N, Nozaki Y, Chikata T, et al. (2016) Development of a wideband microwave reactor with a coaxial cable. Chem Eng J 299: 209‒216. https://doi.org/10.1016/j.cej.2016.04.064 doi: 10.1016/j.cej.2016.04.064
    [20] Kapranov S, Kouzaev G (2018) Nonlinear dynamics of dipoles in microwave electric field of a nanocoaxial tubular reactor. Molecular Physics 117: 489‒506. https://doi.org/10.1080/00268976.2018.1524526 doi: 10.1080/00268976.2018.1524526
    [21] Kapranov S, Kouzaev G (2019) Study of microwave heating of reference liquids in a coaxial waveguide reactor using experimental, semi-analytical, and numerical means. Int J Thermal Sci 140: 505‒520. https://doi.org/10.1016/j.ijthermalsci.2019.03.023 doi: 10.1016/j.ijthermalsci.2019.03.023
    [22] Kouzaev G, Kapranov V (2020) Microwave miniature coaxial reactors for on-demand material synthesis. TechRxiv Preprint. https://doi.org/10.36227/techrxiv.11649678.v2 doi: 10.36227/techrxiv.11649678.v2
    [23] Sarabi F, Chorbani M, Stankiewicz A, Nigar H (2020) Coaxial traveling-wave microwave reactors: Design challenges and solutions. Chem Eng Research Design 153: 677‒683. https://doi.org/10.1016/j.cherd.2019.11.022 doi: 10.1016/j.cherd.2019.11.022
    [24] Topcam H, Karatas O, Erol B, Erdogdu F (2020) Effect of rotation on temperature uniformity of microwave processed low-high viscosity liquids: A computational study with experimental validation. Innov Food Sci Emerging Techn 60: Article No. 103306. https://doi.org/10.1016/j.ifset.2020.102306 doi: 10.1016/j.ifset.2020.102306
    [25] Miyakawa M, Kanamori S, Hagihara K, Itagaki A, Nakamura T, Nishioka M (2021) Cylindrical resonator-type microwave heating reactor with real-time monitoring function of dielectric property applied to drying processes. Industr Eng Chem Res 60: 9119‒9127. https://doi.org/10.1021/acs.iecr.1c00569 doi: 10.1021/acs.iecr.1c00569
    [26] Shi WD, Wang C, Yang WC (2022) Model-based design and operation of coaxial-type microwave reactor toward large-scale production of nanoparticles. Chem Eng Sci 264: Article No. 118162. https://doi.org/10.1016/j.ces.2022.118162 doi: 10.1016/j.ces.2022.118162
    [27] Sharma G, Kouzaev G (2023) Miniature glass-metal coaxial waveguide reactors for microwave-assisted liquid heating. AIMS Electro Electri Eng 7: 100‒120. https://doi.org/10.3934/electreng.2023006 doi: 10.3934/electreng.2023006
    [28] Kouzaev G (2022) Glass-metal coaxial-waveguide reactors for on-demand microwave-assisted chemistry. TechRxiv Preprint. https://doi.org/10.36227/techrxiv.20045006.v2 doi: 10.36227/techrxiv.20045006.v2
    [29] Kouzaev G (2017) A method and apparatus for separate supply of microwave and mechanical energies to liquid reagents in coaxial rotating chemical reactors. UK Patent Appl. GB2560545A dated 15.03.2017. IPO Searchable Patents J 6675: April 26 2017. https://patentimages.storage.googleapis.com/5f/6d/c2/cae7c780904d53/GB2560545A.pdf
    [30] Hur D, Say M, Diltemiz S, Duman F, Ersöz A, Say R (2018) 3D micropatterned all-flexible microfluidic platform for microwave-assisted flow organic synthesis. ChemPlusChem 83: 42‒46.
    [31] Gregory A, Clarke R (2012) Tables of the complex permittivity of dielectric reference liquids at frequencies up to 5 GHz. NPL Report Mat 23: 87 p.
    [32] Kapranov S, Kouzaev G (2018) Models of water, methanol, and ethanol and their applications in the design of miniature microwave heating reactors. Int J Thermal Sci 122: 53‒73. https://doi.org/10.1016/j.ijthermalsci.2017.08.007 doi: 10.1016/j.ijthermalsci.2017.08.007
    [33] Kouzaev G (2023) Thin-film rotating coaxial reactor for microwave-assisted rapid chemistry TecharXiv Preprint. https://doi.org/10.36227/techrxiv.24718350.v1 doi: 10.36227/techrxiv.24718350.v1
  • Reader Comments
  • © 2024 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(211) PDF downloads(35) Cited by(0)

Article outline

Figures and Tables

Figures(11)  /  Tables(3)

Other Articles By Authors

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog