Citation: T.P. Yadav. Recent research and development on Quasicrystals †[J]. AIMS Materials Science, 2017, 4(1): 172-177. doi: 10.3934/matersci.2017.1.172
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The 13th International Conference on Quasicrystals (ICQ13) was held during 18-23 September 2016 in Kathmandu, Nepal. This was one of the series following the 1st workshop in Les Houches, France, the 2nd in Beijing, China, the 3rd Meeting in Vista-Hermosa, Mexico, the 4th Conference in St. Louis, USA, the 5th in Avignon, France, the 6th in Tokyo, Japan, the 7th in Stuttgart, Germany, the 8th in Bangalore, India, the 9th in Ames, USA, the 10th in Zürich, Switzerland, the 11th in Sapporo, Japan, and the 12th in Cracow, Poland. Quasicrystals are a kind of unique materials and characterized by the discrete diffraction patterns which cannot be indexed with the conventional three indices but require additional ones [1,2]. They occur in almost every type of solid including organic and inorganic compounds, minerals, metals and alloys, macromolecules and oxides [3,4,5]. It is convenient to describe their structures in higher dimensional space, a conceptual environment, in which three-dimensional periodic crystals recover their periodicities [6]. The inconvenience of visualization due to extra dimensions is compensated by the mathematical elegance achieved through recovering periodicity. Studies of quasicrystalline structures have greatly enriched our understanding of the physics and chemistry of atomic orders, and have opened up new perspectives for correlating structure with the properties of complex materials.
The ICQ13 conference was attended by 134 participants from all over the world including two participants from India, T.P. Yadav (Banaras Hindu University-Varanasi) and R.R. Shahi (Motilal Nehru National Institute of Technology Allahabad). The details of the conference and the abstract of the papers presented in the conference can be found at https://www.liverpool.ac.uk/conference-on-quasicrystals. There were 15 technical sessions consisting of 56 presentations including three tutorial and 2 poster sessions of 39 papers.
There was an interesting public lecture on Quasi-Periodic Materials: A Paradigm Shift in Crystallography delivered by Professor Dan Shechtman, the 2011 Chemistry Nobel Laureate, who discovered the quasicrystal (QCs) in 1984 [7]. In addition to the public lecture, during the conference there were lively discussions on topics related to formation, growth and phase stability, structure and modeling, mathematics of quasiperiodic and aperiodic structures, physical properties (transport, magnetic, dynamical, mechanical etc.), surfaces and over layers, applications and new frontiers, metamaterials (polymer, macro molecules, photonic/phononic crystals, oxide etc.), incommensurate/modulated structures, metallic glass, complex metallic alloys, clathrate compound, clusters etc. Some of the issues emerging out of this conference are highlighted here which has been discussed by best scientists of the world to talk about the recent developments in the fieldquasicrystal.
The first tutorial was given by Joe Smerdon (University of Central Lancashire, UK) on "Fibonacci, Penrose, Harry Potter: An introduction to the strange world of quasicrystals", second tutorial was given by Cesar Pay Gomez (Uppsala University, Sweden) on "Structure analysis of icosahedral quasicrystals and approximants by X-ray diffraction" and third tutorial was given by Noriaki K. Sato (Nagoya University, Japan) on "Physics hidden in open space between heavy fermions and quasicrystals". Several workers presented on the formation, growth, soft Matter Quasicrystals. T. Dotera (Kindai University, Japan) discussed on the "Bronze-mean hexagonal quasicrystal" simulations of a particle system and obtained a random-tiling of the 6-fold quasicrystal. T. Ishimasa (Hokkaido University, Japan) presented on "Dodecagonal quasicrystal in Mn-based alloy" and has shown the first experimental indication of the presence of an acceptance domain in a dodecagonal quasicrystal viewpoint. P. Boulet (Université de Lorraine, France) shown "Two types of QC approximant in the Ce-Au-Ge system" where a non-centrosymmetric space group F-43m, pointing out the strong relationship of this structure with the gamma-brass structure type. R.R. Shahi (Motilal Nehru National Institute of Technology, India) presented on "Synthesis characterizations and hydrogenation behavior of as quenched Ti45+XZr38−XNi17 (x = 3, 5, 8) nano quasicrystalline ribbons" and discussed the effect of various compositions of Ti and Zr on the structure, microstructure of QC ribbons and their correlation with hydrogen storage characteristics. The atomic structure of ternary Yb-Cd-Mg icosahedral quasicrystals was demonstrated by T. Yamada (Tohoku University, Japan). The "Deformation of icosahedral quasicrystal in a composite of Mg-Zn-Y alloy during severe plastic deformation" was discussed by Alok Singh (National Institute for Materials Science, Japan). He has demonstrated that in Mg-Zn-Y alloy, i-phase formed as eutectic phase in the interdendritic spaces of α-Mg phase with arm widths in the range of 10 to 20 μm. Due to HPT strain, severe deformation occurred in the Mg-matrix, as described in our earlier study on a Mg-3Zn-0.5Y alloy and recrystallization of α-Mg grains occurred over i-phase. No noticeable deformation was noticed in the i-phase until an applied strain of N = 3. Formation of planar low angle boundarieswas observed on fivefold plane. C. Dong (Dalian University of Technology, China) dealt with the "Quasicrystal composition formulas and the hardness evaluation via the cluster-plus-glue-atom model". It was shown within the framework of this model that the hardness of quasicrystals is determined by the number of the ruptured weakest bonds per unit cluster formula. Typically, theoretical hardness values of 8~9 GPa was obtained using ~18 broken inter-cluster bonds, which accounts for half of all the inter-cluster bonds. The statistical description of the Cd-Yb icosahedral quasicrystal with the application of the novel concept of the phason disorder correction and the fundamentals of statistical description of diffraction patterns of crystals was discussed by I. Buganski and J. Wolny (AGH—University of Science and Technology, Poland) independently. The "Structure and stability of γ-brass related complex phase in the Au-Zn System" was discussed by P. Jana (Lund University, Sweden and Indian Institute of Technology Kharagpur, India). E. Abe (University of Tokyo, Japan) presented about the atomic-resolution scanning transmission electron microscopy combined with multivariate analysis for decagonal quasicrystals. K. Edagawa (The University of Tokyo, Japan) presented about the photonic band structure calculations done for a series of crystal approximants to a two dimensional dodecagonal quasicrystal. Further, properties of the six-fold symmetric photonic quasicrystal fibers were presented by C.S. Kee (Gwangju Institute of Science and Technology, South Korea). The "Fibonacci Bloch function in the quasicrystal" discussed by Ron Lifshitz (Tel Aviv University, Israel) where he was shown about the tight-binding model on the 1-dimensional Fibonacci quasicrystal. P. Subramanian (University of Leeds, UK) presented on "Weakly nonlinear analysis of three-dimensional quasicrystals using homotopy continuation". R. Widmer (Paul Scherrer Institute, Switzerland) presented on "Fermi states and anisotropy of Brillouin zone scattering in the decagonal Al-Ni-Co quasicrystal" and "Unified cluster-based description of valence bands in AlIr, RuAl2, RuGa3, and Al-TM quasicrystalline approximants" was discussed by K. Kitahara (The University of Tokyo, Japan). A. Koga (Tokyo Institute of Technology, Japan) presented the extended Anderson lattice model on the Penrose lattice to discuss valence fluctuations at low temperatures combining the real-space dynamical mean-field theory with the continuous-time quantum Monte Carlo method, based on the f-electron number, spin correlations, and local magnetic susceptibility. K. Kimura (The University of Tokyo, Japan) presented semiconducting quasicrystal and high-performance thermoelectric material. J. Dolinšek (Jožef Stefan Institute and University of Ljubljana, Slovenia) presented extraction of the electronic properties of rare-earth-containing quasicrystals from their low-temperature specific heat in the presence of the Schottky effect. The "Gap structure and topological indices on the Fibonacci quasicrystal" was presented by Nicolas Macé (Université Paris-Saclay, France). K. Deguchi (Nagoya University, Japan) discussed on "Magnetism and superconductivity in icosahedral quasicrystals and approximants with Tsai-type clusters" and "Phenomenological magnetic model in Tsai-type approximants" was discussed by T. Sugimoto (Tokyo University of Science, Japan). "Neutron-scattering study on the quasicrystal approximants Au-Si-R (R = rare-earths)" was presented by T. Hiroto (The University of Tokyo, Japan). Anuradha Jagannathan (Université Paris-Sud, France) presented "Screening of magnetic impurities in quasicrystals"
In the concluding remarks some major issues have emerged from this conference which is expected to dominate research in quasicrystal. These are: (i) structural refinement of quasicrystals by using electron diffraction and electron tomography, (ii) structural refinement of quasicrystals using the average lattice concept, (iii) application of quasicrystal at industrial scale.
It was announced by International Advisory Board of the International Conference on Quasicrystals that the next meeting on ICQ14 will be organized by Janez Dolinšek in the Slovenia in 2019.
The author declares that there is no conflict of interest regarding the publication of this paper.
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Mukhopadhyay NK, Lord EA (2002) Least path criterion (LPC) for unique indexing in a two-dimensional decagonal quasilattice. Acta Cryst A 58: 424-428. doi: 10.1107/S0108767302008747
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