In the context of the fight against climate change and the development of renewable and new energies, the management of cashew nutshells is an issue. The physico-chemical and energetic properties of cashew nutshells show that they are good raw materials that can be used in thermochemical processes. Cashew nutshells were heated to temperatures of 300 ℃, 350 ℃ and 400 ℃ for 40 to 120 minutes to extract the liquid from the cashew nutshells. Biochar yields by mass were 46.5–52.8 wt%, 46.2–35.9 wt% and 37.8–30.3 wt% at temperatures of 300 ℃, 350 ℃ and 400 ℃, respectively. Biochar with high higher heating value and low residual oil content was obtained at a heating temperature of 300 ℃ for a time of 120 min. The biochar obtained under these optimum conditions has a residual oil content of less than 1 wt% and a higher heating value of 32.1 MJ·kg-1. The other two products, bio-oil and smoke, have higher heating values of 36 MJ·kg-1 and 10.2 MJ·Nm-3, respectively. Temperature and heating time improve the energy density and quality of biochar with low residual oil content. Heat treatment is therefore a promising technique for the production of an environmentally friendly and sustainable high energy solid biofuel from cashew nutshells.
Citation: Boua Sidoine KADJO, Mohamed Koïta SAKO, Kouadio Alphonse DIANGO, Amélie DANLOS, Christelle PERILHON. Characterization and optimization of the heat treatment of cashew nutshells to produce a biofuel with a high-energy value[J]. AIMS Energy, 2024, 12(2): 387-407. doi: 10.3934/energy.2024018
In the context of the fight against climate change and the development of renewable and new energies, the management of cashew nutshells is an issue. The physico-chemical and energetic properties of cashew nutshells show that they are good raw materials that can be used in thermochemical processes. Cashew nutshells were heated to temperatures of 300 ℃, 350 ℃ and 400 ℃ for 40 to 120 minutes to extract the liquid from the cashew nutshells. Biochar yields by mass were 46.5–52.8 wt%, 46.2–35.9 wt% and 37.8–30.3 wt% at temperatures of 300 ℃, 350 ℃ and 400 ℃, respectively. Biochar with high higher heating value and low residual oil content was obtained at a heating temperature of 300 ℃ for a time of 120 min. The biochar obtained under these optimum conditions has a residual oil content of less than 1 wt% and a higher heating value of 32.1 MJ·kg-1. The other two products, bio-oil and smoke, have higher heating values of 36 MJ·kg-1 and 10.2 MJ·Nm-3, respectively. Temperature and heating time improve the energy density and quality of biochar with low residual oil content. Heat treatment is therefore a promising technique for the production of an environmentally friendly and sustainable high energy solid biofuel from cashew nutshells.
[1] | FAO (2023) Crops and livestock products 2023. Available from: https://www.fao.org/faostat/en/#data/QCL. |
[2] | Away4Africa, ACA (2018) Environmental Study of Waste Management in Cashew Processing in eight African countries Benin, Burkina Faso, Côte d'Ivoire, Ghana, Guinea-Bissau, Kenya, Mozambique, Tanzania. Final report, funding from the AfTra Project (African Development Bank) For African Cashew Alliance. Available from: https://www.away4africa.nl/wp-content/uploads/2019/06/2018-A4A_Report_ACA-study-cashew-by-products_Final.pdf |
[3] | Kouamé KM, Fofana A, Abouo NV, et al. (2020) Sustainable thermochemical valorization of cashew nut waste in West Africa: Experimental study and evaluation of the energy potential in Côte d'Ivoire. Int J Renew Energy Res 10: 1404–1414. https://doi.org/10.20508/ijrer.v10i3.11106.g8016 doi: 10.20508/ijrer.v10i3.11106.g8016 |
[4] | Mubofu EB, Mgaya JE (2018) Chemical valorization of cashew nut shell waste. Top Curr Chem 376: 8. https://doi.org/10.1007/s41061-017-0177-9 doi: 10.1007/s41061-017-0177-9 |
[5] | Godjo T, Tagutchou JP, Naquin P, et al. (2015) Valorisation des coques d'anacarde par pyrolyse au Bénin. Déchets Sci Tech 70: 11–18. https://doi.org/10.4267/dechets-sciences-techniques.3282 doi: 10.4267/dechets-sciences-techniques.3282 |
[6] | Sawadogo M, Tanoh ST, Sidibé S, et al. (2018) Cleaner production in Burkina Faso: Case study of fuel briquettes made from cashew industry waste. J Cleaner Prod 195: 1047–1056. https://doi.org/10.1016/j.jclepro.2018.05.261 doi: 10.1016/j.jclepro.2018.05.261 |
[7] | Panwar NL, Pawar A, Salvi BL (2019) Comprehensive review on production and utilization of biochar. Appl Sci 1: 19. https://doi.org/10.1007/s42452-019-0172-6 doi: 10.1007/s42452-019-0172-6 |
[8] | Pandiyan VC, Shylaja G, Srinivasan RG, et al. (2020) Studies on use of Cashew Nut Shell Liquid (CNSL) in biopesticide and biofertilizer. Nat Env Poll Tech 19: 103–111. https://neptjournal.com/upload-images/(9)B-3614.pdf |
[9] | Nyirenda J, Zombe K, Kalaba G, et al. (2021) Exhaustive valorization of cashew nut shell waste as a potential bioresource material. Sci Rep 11: 14. https://doi.org/10.1038/s41598-021-91571-y doi: 10.1038/s41598-021-91571-y |
[10] | Papadaki MI, Mendoza-Castillo DI, Reynel-Avila HE, et al. (2021) Nut Shells as Adsorbents of Pollutants: Research and perspectives. Front Chem Eng 3: 15. https://doi.org/10.3389/fceng.2021.640983 doi: 10.3389/fceng.2021.640983 |
[11] | Jijo J, Roshna R, Santhiya S (2022) Cashew nut shell ash as a supplementary additive in lime stabilized expansive soil composites. Mater Today Proc 62: 644–649. https://doi.org/10.1016/j.matpr.2022.03.627 doi: 10.1016/j.matpr.2022.03.627 |
[12] | Ba MS, Ndiaye LG, Youm I (2019) Thermochemical characterization of Casamance biomass residues for production of combustibles briquettes. Open J Phys Chem 9: 170–181. https://doi.org/10.4236/ojpc.2019.93009 doi: 10.4236/ojpc.2019.93009 |
[13] | Ifa L, Yani S, Nurjannah N, et al. (2020) Techno-economic analysis of bio-briquette from cashew nut shell waste. Heliyon 6: 9. https://doi.org/10.1016/j.heliyon.2020.e05009 doi: 10.1016/j.heliyon.2020.e05009 |
[14] | Ajith Kumar TT, Mech N, Ramesh ST, et al. (2022) Evaluation of composite briquettes from dry leaves in energy applications for agrarian communities in India. J Clean Prod 350: 131312. https://doi.org/10.1016/j.jclepro.2022.131312 doi: 10.1016/j.jclepro.2022.131312 |
[15] | Nikiema M, Somda MK, Sawadogo JB, et al. (2020) Valorization of agricultural waste: theoretical estimation and experimental biomethane yield from cashew nut hulls. J Sustain Bioeng Syst 10: 113–130. https://doi.org/10.4236/jsbs.2020.104009 doi: 10.4236/jsbs.2020.104009 |
[16] | Moreira R, Dos Reis Orsini R, Vaz JM, et al. (2017) Production of biochar, bio-oil and synthesis gas from cashew nut shell by slow pyrolysis. Waste Biomass Valorization 8: 217–224. https://doi.org/10.1007/s12649-016-9569-2 doi: 10.1007/s12649-016-9569-2 |
[17] | Nam NH, Anh KD, Truc LGT, et al. (2020) Pyrolysis of cashew nut shell: A parametric study. Vietnam J Chem 5: 506–511. https://doi.org/10.1002/vjch.202000015 doi: 10.1002/vjch.202000015 |
[18] | Coulibaly A, Sako MK, Soro D, et al. (2022) Valuation of cashew nut shell for the production of biofuel. Energy Rep 8: 691–707. http://dx.doi.org/10.1016/j.egyr.2022.07.090 doi: 10.1016/j.egyr.2022.07.090 |
[19] | Sakulkit P, Palamanit A, Dejchanchaiwong R, et al. (2020) Characteristics of pyrolysis products from pyrolysis and co-pyrolysis of rubber wood and oil palm trunk biomass for biofuel and value-added applications. J Environ Chem Eng 8: 15. https://doi.org/10.1016/j.jece.2020.104561 doi: 10.1016/j.jece.2020.104561 |
[20] | Van Soest PJ, Robertson JB, Lewis BA (1991) Methods for dietary fiber, neutral detergent fiber, and nonstarch polysaccharides in relation to animal nutrition. J Dairy Sci 74: 3583–3597. https://doi.org/10.3168/jds.S0022-0302(91)78551-2 doi: 10.3168/jds.S0022-0302(91)78551-2 |
[21] | Kaur R, Kumar VT, Krishna BB, et al. (2023) Characterization of slow pyrolysis products from three different cashew wastes. Bioresour Technol 376: 128859. https://doi.org/10.1016/j.biortech.2023.128859 doi: 10.1016/j.biortech.2023.128859 |
[22] | Ábrego J, Plaza D, Luño F, et al. (2018) Pyrolysis of cashew nutshells: Characterization of products and energy balance. Energy 158: 72–80. https://doi.org/10.1016/j.energy.2018.06.011 doi: 10.1016/j.energy.2018.06.011 |
[23] | Mehetre SA, Sengar SH, Panwar NL, et al. (2016) Performance evaluation of improved carbonized cashew nut shell based cookstove. Waste Biomass Valorization 7: 1221–1225. https://doi.org/10.1007/s12649-016-9497-1 doi: 10.1007/s12649-016-9497-1 |
[24] | Anand A, Gautam S, Chand Ram LC (2023) A characteristic-based decision tree approach for sustainable energy applications of biomass residues from two major classes. Fuel 339: 127483. https://doi.org/10.1016/j.fuel.2023.127483 doi: 10.1016/j.fuel.2023.127483 |
[25] | Homchat K, Ramphueiphad S (2022). The continuous carbonisation of rice husk on the gasifier for high yield charcoal production. Results Eng 15: 6. https://doi.org/10.1016/j.rineng.2022.100495 doi: 10.1016/j.rineng.2022.100495 |
[26] | Raza M, Abu-Jdayil B (2023) Synergic interactions, kinetic and thermodynamic analyses of date palm seeds and cashew shell waste co-pyrolysis using Coats–Redfern meth-od. Case Stud Therm Eng 47: 14. https://doi.org/10.1016/j.csite.2023.103118 doi: 10.1016/j.csite.2023.103118 |
[27] | Nunes LJR, Matias JCO, Loureiro LMEF, et al. (2021) Evaluation of the potential of agricultural waste recovery: energy densification as a factor for residual biomass logistics optimization. Appl Sci 11: 23. https://dx.doi.org/10.3390/app11010020 doi: 10.3390/app11010020 |
[28] | Muthu Dineshkumar R, Meera Sheriffa Begum KMKM, Ramanathan A (2020) Comprehensive characterization of cashew nutshell for biomass gasification. Mater Today Proc 46: 9814–9819. https://doi.org/10.1016/j.matpr.2020.10.932 doi: 10.1016/j.matpr.2020.10.932 |
[29] | Rodriguez-Jimenez S, Duarte-Aranda S, Canche-Escamilla G (2019) Chemical composition and thermal properties of tropical wood from the Yucatán dry forests. Bioresources 14: 2651–2666. https://doi.org/10.15376/biores.14.2.2651-2666 doi: 10.15376/biores.14.2.2651-2666 |
[30] | Preradovic M, Papuga S, Kolundžija A (2023) Torrefaction: Process review. Period Polytech Chem Eng 67: 49–61. https://doi.org/10.3311/PPch.20636 doi: 10.3311/PPch.20636 |
[31] | Chen WH, Peng J, Bi XT (2015) A state-of-the-art review of biomass torrefaction, densification and applications. Renew Sust Energ Rev 44: 847–866. https://doi.org/10.1016/j.rser.2014.12.039 doi: 10.1016/j.rser.2014.12.039 |
[32] | Mamvura TA, Danha G (2020) Biomass torrefaction as an emerging technology to aid in energy production. Heliyon 6: 17. https://doi.org/10.1016/j.heliyon.2020.e03531 doi: 10.1016/j.heliyon.2020.e03531 |
[33] | Ducom G, Gautier M, Pietraccini M, et al. (2020) Comparative analyses of three olive mill solid residues from different countries and processes for energy recovery by gasification. Renew Energ 145: 180–189. https://doi.org/10.1016/j.renene.2019.05.116 doi: 10.1016/j.renene.2019.05.116 |
[34] | Castilla-Caballero D, Barraza-Burgos J, Gunasekaran S, et al. (2020) Experimental data on the production and characterization of biochars derived from coconut-shell wastes obtained from the Colombian Pacific Coast at low temperature pyrolysis. Data in Brief 28: 11. https://doi.org/10.1016/j.dib.2019.104855 doi: 10.1016/j.dib.2019.104855 |
[35] | Diedhiou A, Ndiaye LG, Bensakhria A, et al. (2019) Thermochemical conversion of cashew nut shells, palm nut shells and peanut shells char with CO2 and/or steam to aliment a clay brick firing unit. Renew Energ 142: 581–590. https://doi.org/10.1016/j.renene.2019.04.129 doi: 10.1016/j.renene.2019.04.129 |
[36] | Lu F, Rodriguez-Garcia J, Van Damme I, et al. (2018) Valorisation strategies for cocoa pod husk and its fractions. Curr Opin Green Sustain Chem 14: 80–88. https://doi.org/10.1016/j.cogsc.2018.07.007 doi: 10.1016/j.cogsc.2018.07.007 |
[37] | Vásquez ZS, de Carvalho Neto DP, Pereira GVM, et al. (2019) Biotechnological approaches for cocoa waste management: A review. Waste Manage 90: 72–83. https://doi.org/10.1016/j.wasman.2019.04.030 doi: 10.1016/j.wasman.2019.04.030 |
[38] | Adjin-Tetteh M, Asiedu N, Dodoo-Arhin D, et al. (2018) Thermochemical conversion and characterization of cocoa pod husks a potential agricultural waste from Ghana. Ind Crops Prod 119: 304–312. https://doi.org/10.1016/j.indcrop.2018.02.060 doi: 10.1016/j.indcrop.2018.02.060 |
[39] | Zinla D, Gbaha P, Koffi PME, et al. (2021) Characterization of rice, coffee and cocoa crops residues as fuel of thermal power plant in Côte d'Ivoire. Fuel 283: 9. https://doi.org/10.1016/j.fuel.2020.119250 doi: 10.1016/j.fuel.2020.119250 |
[40] | Kaliyan N, Morey RV (2009) Factors affecting strength and durability of densified biomass products. Biomass Bioenergy 33: 337–359. https://doi.org/10.1016/j.biombioe.2008.08.005 doi: 10.1016/j.biombioe.2008.08.005 |
[41] | Kosakowski W, Bryszewska MA, Dziugan P (2022) Biochars from post-production biomass and waste from wood management: Analysis of carbonization products. Materials 13: 13. https://doi.org/10.3390/ma13214971 doi: 10.3390/ma13214971 |
[42] | Srisang S, Phetpan K, Ruttanadech N, et al. (2022) Charcoal briquette production from waste in the coffee production process using hydrothermal and torrefaction techniques: A comparative study with carbonization technique. J Cleaner Prod 372: 133744. https://doi.org/10.1016/j.jclepro.2022.133744 doi: 10.1016/j.jclepro.2022.133744 |
[43] | Lubwama M, Yiga VA (2018) Characteristics of briquettes developed from rice and coffee husks for domestic cooking applications in Uganda. Renew Energ 118: 43–55. https://doi.org/10.1016/j.renene.2017.11.003 doi: 10.1016/j.renene.2017.11.003 |
[44] | Hawash SI, Farah JY, El-Diwani G (2017) Pyrolysis of agriculture wastes for bio-oil and char production. J Anal Appl Pyrolysis 124: 369–372. https://doi.org/10.1016/j.jaap.2016.12.021 doi: 10.1016/j.jaap.2016.12.021 |
[45] | Sharma P, Gaur KV, Sirohi R (2020) Valorization of cashew nut processing residues for industrial applications. Ind Crops Prod 152: 11. https://doi.org/10.1016/j.indcrop.2020.112550 doi: 10.1016/j.indcrop.2020.112550 |
[46] | Adekanbi ML, Olugasa TT (2022) Utilizing cashew nut shell liquid for the sustainable production of biodiesel: A comprehensive review. Clean Chem Eng 4: 17. https://doi.org/10.1016/j.clce.2022.100085 doi: 10.1016/j.clce.2022.100085 |
[47] | Scaldaferri CA, Pasa VMD (2019) Green diesel production from upgrading of cashew nut shell liquid. Renew Sustain Energy Rev 111: 303–313. https://doi.org/10.1016/j.rser.2019.04.057 doi: 10.1016/j.rser.2019.04.057 |
[48] | Devarajan Y, Munuswamy DB, Nagappan BK (2017) Emissions analysis on diesel engine fuelled with cashew nut shell biodiesel and pentanol blends. Environ Sci Pollut Res 24: 13136–13141. https://doi.org/10.1007/s11356-017-8915-7 doi: 10.1007/s11356-017-8915-7 |
[49] | Bamgbola AA, Adeyemi OO, Olubomehin OO, et al. (2020) Isolation and characterization of cellulose from cashew (Anacardium occidentale L.) nut shells. Curr Opin Green Sustain Chem 3: 8. https://doi.org/10.1016/j.crgsc.2020.100032 doi: 10.1016/j.crgsc.2020.100032 |
[50] | Selvamuthukumar M, Harish babu B, Sujith bobba, et al. (2021) Investigation on the lubricating behavior of cashew nut shell liquid oil as a renewable and reliable petrochemical product. Mater Today Proc 44: 3583–3588. https://doi.org/10.1016/j.matpr.2020.09.458 doi: 10.1016/j.matpr.2020.09.458 |
[51] | Ganesan S, Vedagiri P (2022) Production of sustainable biomass briquettes from de-oiled cashewnut Shell. Mater Today Proc 68: 2484–2492. https://doi.org/10.1016/j.matpr.2022.09.179 doi: 10.1016/j.matpr.2022.09.179 |
[52] | Cruz Reina LJ, López GD, Durán-Aranguren DD, et al. (2023) Compressed fluids and Soxhlet extraction for the valorization of compounds from Colombian cashew (Anacardium occidentale) nut shells aimed at a cosmetic application. J Supercrit Fluids 192: 105808. https://doi.org/10.1016/j.supflu.2022.105808. doi: 10.1016/j.supflu.2022.105808 |
[53] | Abdulyekeen KA, Umar AA, Patah MFA, et al. (2021) Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass. Renew Sust Energ Rev 150: 21. https://doi.org/10.1016/j.rser.2021.111436 doi: 10.1016/j.rser.2021.111436 |
[54] | Thengane SK, Kung KS, Gomez-Barea A, et al. (2022) Advances in biomass torrefaction: Parameters, models, reactors, applications, deployment, and market. Prog Energy Combust Sci 93: 101040. https://doi.org/10.1016/j.pecs.2022.101040 doi: 10.1016/j.pecs.2022.101040 |
[55] | Ahmadou A, Brun N, Alfredo N, et al. (2019) Effect of pyrolysis temperature on ochratoxin A adsorption mechanisms and kinetics by cashew nut shell biochars. J Food Sci Technol 4: 877–888. https://doi.org/10.25177/JFST.4.7.RA.565 doi: 10.25177/JFST.4.7.RA.565 |
[56] | Tumuluru JS, Yancey NA, Kane JJ (2021) Pilot-scale grinding and briquetting studies on variable moisture content municipal solid waste bales-Impact on physical properties, chemical composition, and calorific value. Waste Manage 125: 316–327. https://doi.org/10.1016/j.wasman.2021.02.013 doi: 10.1016/j.wasman.2021.02.013 |
[57] | Nobre C, Alves O, Longo A, et al. (2019) Torrefaction and carbonization of refuse derived fuel: Char characterization and evaluation of gaseous and liquid emissions. Bioresour Technol 285: 9. https://doi.org/10.1016/j.biortech.2019.121325 doi: 10.1016/j.biortech.2019.121325 |