Research article Special Issues

Anisotropic SmCo5/FeCo core/shell nanocomposite chips prepared via electroless coating

  • We report the preparation of anisotropic SmCo5/FeCo core/shell nanocomposite chip-like particles via an electroless coating process. The anisotropic SmCo5 nanoscale chips were first prepared by surfactant-assisted ball milling then coated with soft magnetic FeCo using cobalt sulfate (CoSO4.7H2O) and iron sulfate (FeSO4.7H2O) as metal precursors in presence of complexing agents. The influence of the soft-phase coating on the magnetic properties of the nanocomposite particles has been studied. The saturation magnetization of the composite particles increases with increasing coating while the coercivity decreases. The FeCo coated chips have an enhanced remanence (Mr = 44.5 emu/g with 16 wt % of FeCo) compared to the uncoated chips (Mr = 36.7 emu/g), indicating exchange coupling between the hard and soft phases for the optimal soft-phase coating. Results of magnetic field alignment show the strong anisotropy of SmCo5/FeCo core/shell nanocomposite particles which can be used as building blocks of high-strength anisotropic magnets.

    Citation: Narayan Poudyal, Kinjal Gandha, Kevin Elkins, J. Ping Liu. Anisotropic SmCo5/FeCo core/shell nanocomposite chips prepared via electroless coating[J]. AIMS Materials Science, 2015, 2(3): 294-302. doi: 10.3934/matersci.2015.3.294

    Related Papers:

    [1] Khang Duy Vu Nguyen, Khoa Dang Nguyen Vo . Magnetite nanoparticles-TiO2 nanoparticles-graphene oxide nanocomposite: Synthesis, characterization and photocatalytic degradation for Rhodamine-B dye. AIMS Materials Science, 2020, 7(3): 288-301. doi: 10.3934/matersci.2020.3.288
    [2] Jing-Fung Lin, Jer-Jia Sheu, Xin-Rong Qiu . Magnetic retardance and magnetic heating in dextran-citrate coated ferrofluids. AIMS Materials Science, 2017, 4(1): 231-249. doi: 10.3934/matersci.2017.1.231
    [3] Yana Fajar Prakasa, Sumari Sumari, Aman Santoso, Muhammad Roy Asrori, Ririn Cahyanti . The performance of radar absorption of MnxFe3–xO4/rGO nanocomposites prepared from iron sand beach and coconut shell waste. AIMS Materials Science, 2023, 10(2): 227-248. doi: 10.3934/matersci.2023013
    [4] Sergey V. Belim . Study of ordering in 2D ferromagnetic nanoparticles arrays: Computer simulation. AIMS Materials Science, 2023, 10(6): 948-964. doi: 10.3934/matersci.2023051
    [5] Omar Hassan Mahmood, Mustafa Sh. Aljanabi, Farouk M. Mahdi . Effect of Cu nanoparticles on microhardness and physical properties of aluminum matrix composite prepared by PM. AIMS Materials Science, 2025, 12(2): 245-257. doi: 10.3934/matersci.2025013
    [6] Imaddin A. Al-Omari, Muna D. Al-Mamari, D.J. Sellmyer . Tuning the giant Magnetocaloric Effect and refrigerant capacity in Gd1–xYxCrO3 (0.0 ≤ x ≤ 0.9) perovskites nanoparticles. AIMS Materials Science, 2022, 9(2): 297-310. doi: 10.3934/matersci.2022018
    [7] Huda A. Al-Salihi, Hadia Kadhim Judran . Effect of Al2O3 reinforcement nanoparticles on the tribological behaviour and mechanical properties of Al6061 alloy. AIMS Materials Science, 2020, 7(4): 486-498. doi: 10.3934/matersci.2020.4.486
    [8] Andrea Ehrmann, Tomasz Blachowicz . Interaction between magnetic nanoparticles in clusters. AIMS Materials Science, 2017, 4(2): 383-390. doi: 10.3934/matersci.2017.2.383
    [9] Denise Arrozarena Portilla, Arturo A. Velázquez López, Rosalva Mora Escobedo, Hernani Yee Madeira . Citrate coated iron oxide nanoparticles: Synthesis, characterization, and performance in protein adsorption. AIMS Materials Science, 2024, 11(5): 991-1012. doi: 10.3934/matersci.2024047
    [10] Saif S. Irhayyim, Hashim Sh. Hammood, Hassan A. Abdulhadi . Effect of nano-TiO2 particles on mechanical performance of Al–CNT matrix composite. AIMS Materials Science, 2019, 6(6): 1124-1134. doi: 10.3934/matersci.2019.6.1124
  • We report the preparation of anisotropic SmCo5/FeCo core/shell nanocomposite chip-like particles via an electroless coating process. The anisotropic SmCo5 nanoscale chips were first prepared by surfactant-assisted ball milling then coated with soft magnetic FeCo using cobalt sulfate (CoSO4.7H2O) and iron sulfate (FeSO4.7H2O) as metal precursors in presence of complexing agents. The influence of the soft-phase coating on the magnetic properties of the nanocomposite particles has been studied. The saturation magnetization of the composite particles increases with increasing coating while the coercivity decreases. The FeCo coated chips have an enhanced remanence (Mr = 44.5 emu/g with 16 wt % of FeCo) compared to the uncoated chips (Mr = 36.7 emu/g), indicating exchange coupling between the hard and soft phases for the optimal soft-phase coating. Results of magnetic field alignment show the strong anisotropy of SmCo5/FeCo core/shell nanocomposite particles which can be used as building blocks of high-strength anisotropic magnets.


    1. Introduction

    Nanocomposite magnets consisting of exchange-coupled hard and soft phases have potential applications as advanced permanent magnets with high energy product [1,2,3]. Possible application for nanocomposite permanent magnets are fully dense bulk or bonded magnets used in consumer electronic applications, electrical vehicles and wind turbines. Our recent experimental work has shown a remarkable enhancement on maximum energy product (BH)max of the exchanged-coupled isotropic hard/soft nanocomposite (FePt/Fe3Pt and Sm-Co/Fe(Co)) bulk magnets compared to the single phase counterpart [4,5,6,7,8]. The nanocomposite magnets are also commercially important as they have significantly lower materials cost compared to their single-phase counterpart magnets [9].

    The values of remanence and maximum energy product (BH)max will be significantly enhanced if the crystallographicc-axis of the hard-phase grains or particles of the nanocomposite materials are aligned to form anisotropic nanocomposite magnets [10]. It is still a great challenge to fabricate nanostructured bulk magnets with texture.One of the possible approaches to producing anisotropic bulk nanocomposite magnets is to fabricate anisotropic hard/soft core/shell nanocomposite particles so that anisotropic bulk magnets can be made from the particles [11]. Bimagnetic nanoparticles with core/shell structures with tailored hard and soft dimensions can be ideal building blocks for fabrication of advanced permanent magnetic materialsbecause the intimate contact between the hard and soft magnetic phases in the nanoparticles can lead to effective interphase exchange coupling [12]. Our previous experimental studies have demonstrated that the surfactant-assisted ball milling is a promising technique for producing single-phase anisotropic hard magnetic (Sm-Co and Nd2Fe14B) and soft magnetic (Co, Fe and FeCo) nanoparticles, submicron particles and anisotropic bonded magnets [13,14,15,16,17]. In recent years electroless coatings have been applied to hard magnetic SmCo micron-sized powder particles with soft phase layers [18,19]. In this paper, we report the preparation of anisotropic SmCo5/FeCo core/shellnanocomposite chip-like particles via an electroless coating process and the effect of the soft phase coating on the magnetic properties of the nanocomposite particles.

    2. Materials and Method

    The anisotropic hard/soft SmCo5/FeCo core/shell nanocomposite chip-like particles were prepared via a two-step process: 1. Preparation of anisotropic hard magnetic SmCo5 nanochip-like particles by surfactant-assisted high energy ball milling [17], and 2. Electroless coating of FeCo soft magnetic phase on the SmCo5 nano-chips [19].

    2.1. Preparation of anisotropic SmCo5 nano-chips

    SmCo5 nano-chips were first prepared by surfactant-assisted high energy ball milling method using starting commercial SmCo5 powder of particle size ~45 µm. Heptane with 99.8% purity was used as solvent and oleic acid with 90% purity was used as surfactant. The amount of surfactant used was 50% by weight of the starting powder. The mixture of SmCo5 powder, surfactant and solvent was sealed in an argon gas environment inside a glove box. The mixture was milled for 1 h with balls made of hardened steel by using a Spex 8000 M high-energy ball milling machine with a powder to ball weight ratio of 1:10. Handling of the starting materials and as-milled products was carried out in an argon gas environment inside a glove box to protect the particles from oxidation during processing.

    2.2. Preparation of SmCo5/FeCo core/shell nanocomposite nano-chips

    SmCo5/FeCo core/shell nanocomposite nano-chips were prepared by coating FeCo soft magnetic phase on SmCo5 nanochips by an electroless coating process. As prepared SmCo5 nano-chips were first washed in an acetone then activated in 0.5 M sodium hypophosphite at 90 °C for 20 min. An electroless plating bath was prepared by using 0.09 mol of cobalt sulfate (CoSO4. 7H2O), 0.07 mol of iron sulfate (FeSO4.7H2O), 0.5 mol of sodium hypophosphite (NaH2PO2.H2O), 0.3 mol of sodium citrate (Na3C6H5O7. 2H2O), and 0.1 mol of ammonium sulfate ((NH4)2SO4). Then 0.5 g of activated SmCo5 nanochips were put into the electroplating bath. The pH value of the plating bath was maintained between 9-11 by using sodium hydroxide. The electroless plating of FeCo was carried out at a temperature of 80 °C for 60 minutes. The content of FeCo in the final product was controlled by varying the initial molar concentration of the electroless plating bath while keeping the SmCo5 particle amount constant. The SmCo5/FeCo composite particles obtained after electroless plating was purified by washing with the de-ionized water then dried in a glove box in an inert argon gas environment.

    To characterize the anisotropic magnetic properties, the nanoscale chips were mixed with epoxy and aligned in a magnetic field of 2 Tesla. The magnetic properties of randomly oriented and aligned samples were measured by a superconducting quantum interference device (SQUID) magnetometer with a maximum applied field of 7 Tesla. Structural characterizations were performed using x-ray diffraction (XRD) (Rigaku Ultima IV diffractometer operating with Cu Kα radiation).The wt % of FeCo in the SmCo5/FeCo nanocomposites samples was estimated from a Rietveld refinement procedure of the XRD patterns using JADE-9 software. Morphological and compositional characterizations were performed using scanning electron microscopy (SEM) and energy dispersive x-ray (EDX) analysis. A Hitachi S-3000N VP-SEM microscope attached with an EDAX EDX system was used for SEM/EDX analysis at the accelerating voltage of 25 kV. Samples for both SEM and EDX analyses were placed on the sample holders supported by silicon substrates without sputter coating

    3. Results and Discussion

    Figure 1 shows the XRD patterns of randomly oriented as-prepared SmCo5 nano-chips and nano-chips after the electroless coating process. It can be seen from the XRD patterns that the coated samples give two sets of peaks with one set matching to the SmCo 1:5 hard magnetic phase (International Center for Diffraction Data (ICDD) PDF # 00-027-1122) and the other to bcc-FeCo phase (ICDD PDF # 00-048-1818), indicating the deposition of a FeCo soft phase on the SmCo5 surface resulting in the formation of a nanocomposite. It is also observed that the relative intensity of the FeCo peaks increases compared to the SmCo peaks with increasing FeCo content on the coated samples, as the coating proceeded. The coated FeCo content on the hard SmCo5 particles was controlled by varying the ratio of electroless bath molar concentrations to the mass of SmCo5 particles. For example, when the ratio was varied as 1:1, 1:3 and 1:4 the wt % of FeCo estimated from a Rietveld refinement procedure of the XRD patterns was 16%, 32% and 48%, respectively.

    Figure 1. XRD pattern of FeCo coated SmCo5 nanoflakes with different content of FeCo coating (wt % estimated from XRD analysis).

    The morphology of SmCo nanochips before and after coating was observed by SEM. The figure 2(a) shows the SEM image of SmCo5 chips with a high aspect ratio obtained after 1 h milling with a diameter in the range 5-10 µm and thickness in the range 20-150 nm (determined by HRSEM analysis, not shown here). Figure 2(b) shows the SEM image of the SmCo5 nanochips obtained after the electroless coating. An analysis of the SEM images shows that there is no considerable difference in the size of the as-prepared particles compared with those obtained after the electroless coating. However, it can be clearly seen that the surface of the particles after electroless process appears to be smoother than that of the as-prepared particles, suggesting a layer of FeCo on the SmCo surface. A clear contrast difference around the edge of particle and the rest of a single FeCo coated SmCo particle further confirms the formation of core/shell morphology (figure 2(c)). Figure 3(a) shows a SEM image and figure 3(b)-3(d) show EDX elemental maps of Co, Sm, and Fe on an FeCo coated single chip. The EDX elemental maps of Co and Fe in figure 3(b) and 3(c) reveal a homogeneous distribution of the Co and Fe that suggest uniform coating of FeCo on the hard-phase particles.

    Figure 2. SEM images of (a) as prepared SmCo5 nano-chips, (b) SmCo5/FeCocore/shell nano-chips and (c) a single SmCo5/FeCocore/shell chip.
    Figure 3. (a) SEM image of a single SmCo5/FeCo core/shell chip, and EDX element maps of the single SmCo5/FeCo core/shellchip for (b) Co, (c) Fe and (d) Sm.

    Figure 4 shows the demagnetization curves of randomly oriented SmCo5/FeCo nanocomposites chips with different wt % of FeCo estimated by XRD. It can be seen that the single-phase SmCo5 chips have the highest coercivity but the lowest magnetization. As expected, an increase in the soft-phase content reduces the coercivity while it leads to an increase in saturation magnetization. Figure 5 summarizes the effects of the soft-phase content on the saturation magnetization (Ms), remanence (Mr) and coercivity (Hc) of isotropic samples at room temperature. It can obviously be seen that the Msincreased with the soft magnetic FeCo content as one would expect since FeCo has a larger moment than SmCo5. The saturation magnetization increased from 57 to 82 emu/g monotonically with increasing soft phase content (from 0 to 48 wt % of FeCo) while the coercivity decreased rapidly from 19 to 4 kOe. The FeCo coated chips have an enhanced remanence (Mr = 44.5 emu/g with 16 wt % of FeCo) compared to the uncoated SmCo5 chips (Mr = 36.7 emu/g), indicating exchange coupling between the hard and soft phases for optimal soft phase coating. With further increasing soft phase coating (wt %) the remanence decreases because of a rapid drop in coercivity. The enhanced remanence in nanocomposite for optimal coating further confirmed the intergranular exchange interaction among those hard magnetic SmCo5 particles and coated soft magnetic FeCo phases. Nevertheless, kinks are observed in all the demagnetization curves, implying the decoupling behavior caused by an over-size of the hard phase and possible inhomogeneity of the soft phase. For effective exchange coupling in a hard/soft nanocomposite, the layer of the soft phase coating should not exceed the critical length which is dependent on both the hard and soft phase properties.[11]Magnetic properties of core/shell hard/soft magnetic nanocomposite particles can be further tailored by controlling the core and shell dimensions.

    Figure 4. Demagnetization curves of FeCo coated SmCo5 nano-chips with different content of FeCo coating (wt % estimated from XRD analysis).
    Figure 5. Dependence of Ms, Mr and Hc on content of FeCo on SmCo5/FeCo nanocomposite chips.

    Figure 6 shows the typical XRD patterns of the aligned and randomly oriented SmCo5/FeCo nanocomposite particles in the epoxy. The samples were aligned in 2 Tesla magnetic field. Compared with the randomly oriented samples, the intensities of (002) of SmCo5 diffraction peaks of the aligned samples are enhanced significantly, while other peaks largely disappear, suggesting a (00l) out-of-plane alignment (of the c-axis). Figures 7 shows the demagnetization curves of the corresponding aligned sample in figure 6. The demagnetization curves with substantial difference measured in parallel and perpendicular to the aligned field direction confirm the strong anisotropy resulting from the grain alignment along the c-axis in the SmCo5/FeCo nanocomposite chips.

    Figure 6. XRD patterns of randomly oriented SmCo5/FeCo nanocomposite and aligned SmCo5/FeCo nanocomposite chips in 2 Tesla magnetic field hardening in epoxy during alignment.
    Figure 7. Demagnetization curves of SmCo5/FeCo nanocomposite chips sample measured parallel and perpendicular to aligned field direction. The sample was aligned in magnetic field of 2 Tesla and was hardened in epoxy during alignment.

    4. Conclusion

    In summary anisotropic SmCo5/FeCo core/shell nanocomposite chip-like particles have been prepared via an electroless coating process. The influence of the soft-phase coating on the magnetic properties of the nanocomposite particles has been studied. The saturation magnetization of SmCo5/FeCo core/shell nanocomposite particles increases while the coercivity decreases with increasing coating of the soft phase. An enhanced remanenceof the FeCo coated SmCo5 nano-chips compared to the uncoated SmCo5 nano-chips indicates exchange coupling between the hard and soft phases for proper soft phase coating. The results show that the anisotropic SmCo5/FeCo core/shell magnetic nanocomposite particles with tailored dimensions can serve as promising building blocks for high-strength anisotropic bonded or fully dense nanocomposite bulk magnets via this bottom-up approach.

    Acknowledgments

    This work has been supported by the U.S. DoD/ARO under Grant No. W911NF-11-1-0507. This work has also been supported by the Center for Nanostructured Materials and Characterization Center for Materials and Biology at the University of Texas at Arlington.

    Conflict of Interest

    All authors declare no conflicts of interest in this paper.

    [1] Zeng H, Li J, Liu JP, et al. (2002) Exchange-coupled nanocomposite magnets by nanoparticle self-assembly. Nature 420: 395-398.
    [2] Kneller EF, Hawig R (1991) The Exchange-Spring Magnet: A New material principle for permanent magnets. IEEE Trans Magn 27: 3588-3600. doi: 10.1109/20.102931
    [3] Skomski R, Coey JMD (1993) Giant energy product in nanostructured two-phase magnets. Phys Rev B 48: 15812-15816. doi: 10.1103/PhysRevB.48.15812
    [4] Poudyal N, Liu JP (2013) Advances in nanostructured permanent magnets research. J Phys D: Appl Phys 46: 043001. doi: 10.1088/0022-3727/46/4/043001
    [5] Rong CB, Nandwana V, Poudyal N, et al. (2007) Bulk FePt based nanocomposite magnets with enhanced exchange coupling. J Appl Phys 102: 023908. doi: 10.1063/1.2756619
    [6] Rong CB, Zhang Y, Poudyal N, et al. (2010) Fabrication of bulk nanocomposite magnets via severe plastic deformation and warm compaction. Appl Phys Lett 96: 102513. doi: 10.1063/1.3358390
    [7] Poudyal N, Xia W, Yue M, et al. (2014) Morphology and magnetic properties of SmCo3/α-Fe nanocomposite magnets prepared via severe plastic deformation. J Appl Phys 115: 17A715.
    [8] Poudyal N, Rong CB, Nguyen VV, et al. (2014) Hard-phase engineering in the hard/soft nanocomposite magnets. Mater Res Express 1: 016103. doi: 10.1088/2053-1591/1/1/016103
    [9] Jones N (2011) The pull of stronger magnets. Nature 472: 22-23. doi: 10.1038/472022a
    [10] Cui WB, Takahashi YK, Hono K (2012) Nd2Fe14B/FeCo Anisotropic Nanocomposite Films with a Large Maximum Energy Product. Adv Mater 24: 6530-6535. doi: 10.1002/adma.201202328
    [11] Liu JP, Fullerton E, Gutfleish O, Sellmyer D J (Eds.), Nanoscale Magnetic Materials and Applications, Springer, New York, 2009 (Chapter 11).
    [12] Zeng H, Sun S, Li J, et al. (2004) Tailoring magnetic properties of core/shell nanoparticles. Appl Phys Lett 85: 792. doi: 10.1063/1.1776632
    [13] Chakka VM, Altuncevahir B, Jin ZQ, et al. (2006) Magnetic Nanoparticles Produced by Surfactant-Assisted Ball Milling. J Appl Phys 99: 08E912.
    [14] Wang YP, Li Y, Rong CB, et al. (2007) Sm-Co hard magnetic nanoparticles prepared by surfactant-assisted ball milling. Nanotechnology 18: 465701. doi: 10.1088/0957-4484/18/46/465701
    [15] Poudyal N, Rong CB, Liu JP (2010) Effects of particle size and composition on coercivity of Sm-Co nanoparticles prepared by surfactant-assisted ball milling. J Appl Phys 107: 09A703.
    [16] Poudyal N, Rong CB, Liu JP (2011) Morphological and magnetic characterization of Fe, Co, and FeCo nanoplates and nanoparticles prepared by surfactants-assisted ball milling. J Appl Phys 109: 07B526.
    [17] Poudyal N, Nguyen VV, Rong CB, et al. (2011) Anisotropic bonded magnets fabricated via surfactant-assisted ball milling and magnetic-field processing. J Phys D: Appl Phys 44: 335002. doi: 10.1088/0022-3727/44/33/335002
    [18] Zheng Q, Zhang Y, Bonder MJ, et al. (2003) Fabrication of Sm-Co/Co (Fe) composites by electroless Co and Co-Fe plating. J Appl Phys 93: 6498. doi: 10.1063/1.1558246
    [19] Lamichanne M, Rai BK, Mishra SR, et al. (2012) Magnetic properties hard-soft SmCo5-FeNi and SmCo5-FeCo composites prepared by Electroless Coating Technique. Open J Compos Mater 2: 119-124. doi: 10.4236/ojcm.2012.24014
  • This article has been cited by:

    1. Lin Lv, Feng-Qing Wang, Qiang Zheng, Juan Du, Xian-Lin Dong, Ping Cui, J. Ping Liu, Preparation and Magnetic Properties of Anisotropic SmCo5/Co Composite Particles, 2018, 31, 1006-7191, 143, 10.1007/s40195-017-0631-2
    2. Yugal Kishore Mohanta, Abeer Hashem, Elsayed Fathi Abd_Allah, Santosh Kumar Jena, Tapan Kumar Mohanta, Bacterial synthesized metal and metal salt nanoparticles in biomedical applications: An up and coming approach, 2020, 34, 0268-2605, 10.1002/aoc.5810
    3. Jimin Lee, Gyutae Lee, Tae-Yeon Hwang, Hyo-Ryoung Lim, Hong-Baek Cho, Jongryoul Kim, Yong-Ho Choa, Phase- and Composition-Tunable Hard/Soft Magnetic Nanofibers for High-Performance Permanent Magnet, 2020, 3, 2574-0970, 3244, 10.1021/acsanm.9b02470
    4. Fengqing Wang, Guiping Tang, Baoru Bian, Lulu Yao, Youhao Liu, Qiang Zheng, Juan Du, Enhanced magnetic properties of anisotropic Nd-Fe-B nanocomposites by Fe(C) coating, 2020, 38, 10020721, 84, 10.1016/j.jre.2019.02.012
    5. Jimin Lee, Jiwon Kim, Danbi Kim, Gyutae Lee, Yeong-Been Oh, Tae-Yeon Hwang, Jae-Hong Lim, Hong-Baek Cho, Jongryoul Kim, Yong-Ho Choa, Exchange-Coupling Interaction in Zero- and One-Dimensional Sm2Co17/FeCo Core–Shell Nanomagnets, 2019, 11, 1944-8244, 26222, 10.1021/acsami.9b02966
    6. P. Saravanan, Sarah Saju, V. T. P. Vinod, Miroslav Černík, Structural and magnetic properties of rare-earth-free MnAl(MCNT)/Fe nanocomposite magnets processed by resin-bonding technique, 2020, 31, 0957-4522, 9878, 10.1007/s10854-020-03532-2
    7. Wei Quan, Lulu Yao, Qiang Zheng, Pingzhan Si, Baoru Bian, Juan Du, High-Performance Anisotropic Nanocomposites with a Novel Core/shell Microstructure, 2022, 14, 1944-8244, 15558, 10.1021/acsami.2c01817
    8. Zhenhui Ma, Jeotikanta Mohapatra, Kecheng Wei, J. Ping Liu, Shouheng Sun, Magnetic Nanoparticles: Synthesis, Anisotropy, and Applications, 2021, 0009-2665, 10.1021/acs.chemrev.1c00860
    9. Yaqin Qie, Yixuan Liu, Fanqi Kong, Zhilin Yang, Hua Yang, Exchange-Coupling of Hard/Soft Magnetic Phases of Co/FeCo Nanocomposites, 2022, 126, 1932-7447, 8826, 10.1021/acs.jpcc.2c00457
  • Reader Comments
  • © 2015 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(6474) PDF downloads(1286) Cited by(9)

Article outline

Figures and Tables

Figures(7)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog