This article is dedicated to investigating the impact of different electrolyte compositions on the development of titanium coatings endowed with superior mechanical, tribological, and corrosion properties. An experimental analysis was conducted on three distinct electrolyte formulations, each contributing unique attributes to the coating's structural formation. Advanced analytical techniques, including scanning electron microscopy, hardness testing, wear resistance evaluation, and corrosion trials in harsh environments, were employed to gauge the mechanical, tribological, and anti-corrosive performance of the coatings. The utilization of scanning electron microscopy, X-ray structural analysis, and additional methodologies enabled an in-depth characterization of the microstructure and elucidated the relationship between the physico-mechanical properties and the electrolyte's chemical makeup. Among the electrolytes examined, the composition containing potassium hydroxide emerged as superior, fostering coatings with a distinctively porous structure that augment mechanical attributes. A considerable degree of porosity coupled with relatively small pore dimensions suggests the potential to engineer structures that exhibit optimal mechanical robustness. Furthermore, research findings related to this specific electrolyte composition revealed enhancements in the friction coefficient and wear resistance, indicating its promising prospects for tribological applications. The study also meticulously addressed the corrosion aspects, revealing that the microarc oxidation-derived coatings substantially improve corrosion resistance by offering more favorable potentials and currents than the bare titanium substrate. The efficacy of microarc oxidation as an avant-garde technique to advance the properties of titanium alloys underscores its prospective utility and practical relevance in contemporary industrial applications.
Citation: Bauyrzhan Rakhadilov, Ainur Zhassulan, Daryn Baizhan, Aibek Shynarbek, Kuanysh Ormanbekov, Tamara Aldabergenova. The effect of the electrolyte composition on the microstructure and properties of coatings formed on a titanium substrate by microarc oxidation[J]. AIMS Materials Science, 2024, 11(3): 547-564. doi: 10.3934/matersci.2024027
This article is dedicated to investigating the impact of different electrolyte compositions on the development of titanium coatings endowed with superior mechanical, tribological, and corrosion properties. An experimental analysis was conducted on three distinct electrolyte formulations, each contributing unique attributes to the coating's structural formation. Advanced analytical techniques, including scanning electron microscopy, hardness testing, wear resistance evaluation, and corrosion trials in harsh environments, were employed to gauge the mechanical, tribological, and anti-corrosive performance of the coatings. The utilization of scanning electron microscopy, X-ray structural analysis, and additional methodologies enabled an in-depth characterization of the microstructure and elucidated the relationship between the physico-mechanical properties and the electrolyte's chemical makeup. Among the electrolytes examined, the composition containing potassium hydroxide emerged as superior, fostering coatings with a distinctively porous structure that augment mechanical attributes. A considerable degree of porosity coupled with relatively small pore dimensions suggests the potential to engineer structures that exhibit optimal mechanical robustness. Furthermore, research findings related to this specific electrolyte composition revealed enhancements in the friction coefficient and wear resistance, indicating its promising prospects for tribological applications. The study also meticulously addressed the corrosion aspects, revealing that the microarc oxidation-derived coatings substantially improve corrosion resistance by offering more favorable potentials and currents than the bare titanium substrate. The efficacy of microarc oxidation as an avant-garde technique to advance the properties of titanium alloys underscores its prospective utility and practical relevance in contemporary industrial applications.
[1] | Geetha M, Singh AK, Asokamani R, et al. (2009) Ti based biomaterials, the ultimate choice for orthopaedic implants—A review. Prog Mater Sci 54: 397–425. https://doi.org/10.1016/j.pmatsci.2008.06.004 doi: 10.1016/j.pmatsci.2008.06.004 |
[2] | Chen QZ, Thouas GA (2015) Metallic implant biomaterials. Mater Sci Eng R 87: 1–57. https://doi.org/10.1016/j.mser.2014.10.001 doi: 10.1016/j.mser.2014.10.001 |
[3] | Vieira AC, Ribeiro AR, Rocha LA, et al. (2006) Influence of pH and corrosion inhibitors on the tribocorrosion of titanium in artificial saliva. Wear 261: 994–1001. https://doi.org/10.1016/j.wear.2006.03.031 doi: 10.1016/j.wear.2006.03.031 |
[4] | Souza JCM, Henriques M, Teughels W, et al. (2015) Wear and corrosion interactions on titanium in oral environment: Literature review. J Bio Tribo Corros 1: 13. https://doi.org/10.1007/s40735-015-0013-0 doi: 10.1007/s40735-015-0013-0 |
[5] | Shokouhfar M, Allahkaram SR (2017) Effect of incorporation of nanoparticles with different composition on wear and corrosion behavior of ceramic coatings developed on pure titanium by micro arc oxidation. Surf Coat Technol 309: 767–778. https://doi.org/10.1016/j.surfcoat.2016.10.089 doi: 10.1016/j.surfcoat.2016.10.089 |
[6] | Ao N, Liu DX, Wang SX, et al. (2016) Microstructure and tribological behavior of a TiO2/hBN composite ceramic coating formed via microarc oxidation of Ti–6Al–4V alloy. J Mater Sci Technol 32: 1071–1076. https://doi.org/10.1016/j.jmst.2016.06.015 doi: 10.1016/j.jmst.2016.06.015 |
[7] | Zhang B, Pei X, Zhou C, et al. (2018) The biomimetic design and 3D printing of customized mechanical properties porous Ti6Al4V scaffold for load-bearing bone reconstruction. Mater Design 152: 30–39. https://doi.org/10.1016/j.matdes.2018.04.065 doi: 10.1016/j.matdes.2018.04.065 |
[8] | Kang S, Mauchauffé R, You YS, et al. (2018) Insights into the role of plasma in atmospheric pressure chemical vapor deposition of titanium dioxide thin films. Sci Rep 8: 16684. https://doi.org/10.1038/s41598-018-35154-4 doi: 10.1038/s41598-018-35154-4 |
[9] | Redmore E, Li X, Dong H (2019) Tribological performance of surface engineered low-cost beta titanium alloy. Wear 426: 952–960. https://doi.org/10.1016/j.wear.2019.01.032 doi: 10.1016/j.wear.2019.01.032 |
[10] | İzmir M, Ercan B (2019) Anodization of titanium alloys for orthopedic applications. Front Chem Sci Eng 13: 28–45. https://doi.org/10.1007/s11705-018-1759-y doi: 10.1007/s11705-018-1759-y |
[11] | Khanna S, Patel R, Marathey P, et al. (2020) Growth of titanium dioxide nanorod over shape memory material using chemical vapor deposition for energy conversion application. Mater Today Proc 28: 475–479. https://doi.org/10.1016/j.matpr.2019.10.035 doi: 10.1016/j.matpr.2019.10.035 |
[12] | Jin J, Li XH, Wu JW, et al. (2018) Improving tribological and corrosion resistance of Ti6Al4V alloy by hybrid microarc oxidation/enameling treatments. Rare Met 37: 26–34. https://doi.org/10.1007/s12598-015-0644-9 doi: 10.1007/s12598-015-0644-9 |
[13] | Wei K, Chen L, Qu Y, et al. (2019) Tribological properties of microarc oxidation coatings on Zirlo alloy. Surf Eng 35: 692–700. https://doi.org/10.1080/02670844.2019.1575001 doi: 10.1080/02670844.2019.1575001 |
[14] | Liu L, Zeng D, Chen Y, et al. (2020) Microarc oxidation surface of titanium implants promote osteogenic differentiation by activating ERK1/2-miR-1827-Osterix. In Vitro Cell Dev Biol-Animal 56: 296–306. https://doi.org/10.1007/s11626-020-00444-7 doi: 10.1007/s11626-020-00444-7 |
[15] | Wu Y, Zhu B, Zhang X, et al. (2022) Preparation and characterization of Y-doped microarc oxidation coating on AZ31 magnesium alloys. J Biomater Appl 37: 930–941. https://doi.org/10.1177/08853282221121886 doi: 10.1177/08853282221121886 |
[16] | Butt MS, Maqbool A, Saleem M, et al. (2020) Revealing the effects of microarc oxidation on the mechanical and degradation properties of Mg-based biodegradable composites. ACS Omega 5: 13694–13702. https://doi.org/10.1021/acsomega.0c00836 doi: 10.1021/acsomega.0c00836 |
[17] | Chen J, Li J, Hu F, et al. (2019) Effect of microarc oxidation-treated Ti6Al4V scaffold following low-intensity pulsed ultrasound stimulation on osteogenic cells in vitro. ACS Biomater Sci Eng 5: 572–581. https://doi.org/10.1021/acsbiomaterials.8b01000 doi: 10.1021/acsbiomaterials.8b01000 |
[18] | Yuan W, Li B, Chen D, et al. (2019) Formation mechanism, corrosion behavior, and cytocompatibility of microarc oxidation coating on absorbable high-purity zinc. ACS Biomater Sci Eng 5: 487–497. https://doi.org/10.1021/acsbiomaterials.8b01131 doi: 10.1021/acsbiomaterials.8b01131 |
[19] | Zhao Q, Yi L, Jiang L, et al. (2019) Surface functionalization of titanium with zinc/strontium-doped titanium dioxide microporous coating via microarc oxidation. Nanomedicine 16: 149–161. https://doi.org/10.1016/j.nano.2018.12.006 doi: 10.1016/j.nano.2018.12.006 |
[20] | Pan YK, Chen CZ, Wang DG, et al. (2013) Preparation and bioactivity of micro-arc oxidized calcium phosphate coatings. Mater Chem Phys 141: 842–849. https://doi.org/10.1016/j.matchemphys.2013.06.013 doi: 10.1016/j.matchemphys.2013.06.013 |
[21] | Sedelnikova MB, Sharkeev YP, Komarova EG, et al. (2016). Structure and properties of the wollastonite–calcium phosphate coatings deposited on titanium and titanium–niobium alloy using microarc oxidation method. Surf Coat Technol 307: 1274–1283. https://doi.org/10.1016/j.surfcoat.2016.08.062 doi: 10.1016/j.surfcoat.2016.08.062 |
[22] | Wang Y, Yu D, Ma K, et al. (2023) Self-healing performance and corrosion resistance of a bilayer calcium carbonate coating on microarc-oxidized magnesium alloy. Corros Sci 212: 110927. https://doi.org/10.1016/j.corsci.2022.110927 doi: 10.1016/j.corsci.2022.110927 |
[23] | Muhaffel F, Cimenoglu H (2019) Development of corrosion and wear resistant micro-arc oxidation coating on a magnesium alloy. Surf Coat Technol 357: 822–832. https://doi.org/10.1016/j.surfcoat.2018.10.089 doi: 10.1016/j.surfcoat.2018.10.089 |
[24] | Rakhadilov BK, Baizhan DR, Sagdoldina ZB, et al. (2022) Research of regimes of applying coats by the method of plasma electrolytic oxidation on Ti-6Al-4V. Bull Karaganda Univ 105: 99–106. https://doi.org/10.31489/2022ph1/99-106 doi: 10.31489/2022ph1/99-106 |
[25] | Baizhan DR, Rakhadilov BK, Aldabergenova TM, et al. (2023) Obtaining of calcium-phosphate coatings on the titanium surface by micro-arc oxidation. Eurasian Phys Tech J 20: 34–41. https://doi.org/10.31489/2023No1/34-41 doi: 10.31489/2023No1/34-41 |
[26] | Saikiran A, Hariprasad S, Arun S, et al. (2019) Effect of electrolyte composition on morphology and corrosion resistance of plasma electrolytic oxidation coatings on aluminized steel. Surf Coat Technol 372: 239–251. https://doi.org/10.1016/j.surfcoat.2019.05.047 doi: 10.1016/j.surfcoat.2019.05.047 |
[27] | Toulabifard A, Rahmati M, Raeissi K, et al. (2020) The effect of electrolytic solution composition on the structure, corrosion, and wear resistance of PEO coatings on AZ31 magnesium alloy. Coatings 10: 937. https://doi.org/10.3390/coatings10100937 doi: 10.3390/coatings10100937 |
[28] | Wu T, Blawert C, Serdechnova M, et al. (2022) Role of phosphate, silicate and aluminate in the electrolytes on PEO coating formation and properties of coated Ti6Al4V alloy. Appl Surf Sci 595: 153523. https://doi.org/10.1016/j.apsusc.2022.153523 doi: 10.1016/j.apsusc.2022.153523 |
[29] | Wu T, Blawert C, Serdechnova M (2022) Formation of plasma electrolytic oxidation coatings on pure niobium in different electrolytes. Appl Surf Sci 573: 151629. https://doi.org/10.1016/j.apsusc.2021.151629 doi: 10.1016/j.apsusc.2021.151629 |
[30] | Zehra T, Kaseem M, Hossain S, et al. (2021) Fabrication of a protective hybrid coating composed of TiO2, MoO2, and SiO2 by plasma electrolytic oxidation of titanium. Metals 11: 1182. https://doi.org/10.3390/met11081182 doi: 10.3390/met11081182 |
[31] | Kaseem M, Choe HC (2021) The effect of in-situ reactive incorporation of MoOx on the corrosion behavior of Ti-6Al-4V alloy coated via micro-arc oxidation coating. Corros Sci 192: 109764. https://doi.org/10.1016/j.corsci.2021.109764 doi: 10.1016/j.corsci.2021.109764 |
[32] | Molaei M, Fattah-Alhosseini A, Nouri M, et al. (2023) Role of TiO2 nanoparticles in wet friction and wear properties of PEO coatings developed on pure titanium. Metals 13: 821. https://doi.org/10.3390/met13040821 doi: 10.3390/met13040821 |
[33] | Kim SP, Kaseem M, Choe HC (2020) Plasma electrolytic oxidation of Ti-25Nb-xTa alloys in solution containing Ca and P ions. Surf Coat Technol 395: 125916. https://doi.org/10.1016/j.surfcoat.2020.125916 doi: 10.1016/j.surfcoat.2020.125916 |
[34] | Kasatkin VE, Kasatkina IV, Bogdashkina NL, et al. (2023) Influence of different modes of microarc oxidation of titanium on the electrochemical properties and surface morphology of the obtained coatings. Surf Eng 39: 295–306. https://doi.org/10.1080/02670844.2023.2223451 doi: 10.1080/02670844.2023.2223451 |
[35] | Bayatanova LB, Zhassulankyzy AZ, Magazov NM, et al. (2023) Effect of plasma-electrolytic oxidation on mechanical properties of titanium coatings. Bull Karaganda Univ 111: 65–74. https://doi.org/10.31489/2023ph3/65-74 doi: 10.31489/2023ph3/65-74 |
[36] | Kuroda PA, de Mattos FN, Grandini CR, et al. (2023) Effect of heat treatment on the phases, pore size, roughness, wettability, hardness, adhesion, and wear of Ti-25Ta MAO coatings for use as biomaterials. J Mater Sci 58: 15485–15498. https://doi.org/10.1007/s10853-023-08979-2 doi: 10.1007/s10853-023-08979-2 |
[37] | Ding H (2010) Corrosion wear behaviors of micro-arc oxidation coating of Al2O3 on 2024Al in different aqueous environments at fretting contact. Tribol Int 43: 868–875. https://doi.org/10.1016/j.triboint.2009.12.022 doi: 10.1016/j.triboint.2009.12.022 |
[38] | Zhang D (2018) Investigation of tribological properties of micro-arc oxidation ceramic coating on Mg alloy under dry sliding condition. Ceram Int 44: 16164–16172. https://doi.org/10.1016/j.ceramint.2018.05.137 doi: 10.1016/j.ceramint.2018.05.137 |
[39] | Song SJ, Fan XQ, Yan H, et al. (2023) Facile fabrication of continuous graphene nanolayer in epoxy coating towards efficient corrosion/wear protection. Compos Commun 37: 101437. https://doi.org/10.1016/j.coco.2022.101437 doi: 10.1016/j.coco.2022.101437 |
[40] | Zhang G, Huang S, Li X, et al. (2023) Oxide ceramic coatings with amorphous/nano-crystalline dual-structures prepared by micro-arc oxidation on Ti–Nb–Zr medium entropy alloy surfaces for biomedical applications. Ceram Int 49: 18114–18124. https://doi.org/10.1016/j.ceramint.2023.02.180 doi: 10.1016/j.ceramint.2023.02.180 |
[41] | Sharkeev Y, Komarova E, Sedelnikova M, et al. (2019) Bioactive micro-arc calcium phosphate coatings on nanostructured and ultrafine-grained bioinert metals and alloys, In: Antoniac L, Bioceramics and Biocomposites: From Research to Clinical Practice, New York: John Wiley & Sons, 191–231. https://doi.org/10.1002/9781119372097.ch8 |
[42] | Xie NS, Wang J (2014) Study on properties of Al2TiO5 coating on Ti-6Al-4V titanium alloy. Key Eng Mater 575–576: 348–351. https://doi.org/10.4028/www.scientific.net/KEM.575-576.348 doi: 10.4028/www.scientific.net/KEM.575-576.348 |
[43] | Ma S, Wang T, Qian L, et al. (2018) Microstructure and corrosion properties of ZK60 alloys modified by micro-arc oxidation coatings using phosphate-borate electrolyte in KOH solution. Int J Electrochem Sci 13: 6451–6461. https://doi.org/10.20964/2018.07.13 doi: 10.20964/2018.07.13 |
[44] | Joni MS, Fattah-alhosseini A (2016) Effect of KOH concentration on the electrochemical behavior of coatings formed by pulsed DC micro-arc oxidation (MAO) on AZ31B Mg alloy. J Alloys Compd 661: 237–244. https://doi.org/10.1016/j.jallcom.2015.11.169 doi: 10.1016/j.jallcom.2015.11.169 |
[45] | Muhaffel F, Jarzębska A, Trelka A, et al. (2024) Unveiling the mechanisms of coating formation during micro-arc oxidation of titanium in Na2HPO4 electrolyte. Surf Coat Technol 476: 130224. https://doi.org/10.1016/j.surfcoat.2023.130224 doi: 10.1016/j.surfcoat.2023.130224 |
[46] | Terleeva OP, Sharkeev YP, Slonova AE, et al. (2010) Effect of microplasma modes and electrolyte composition on micro-arc oxidation coatings on titanium for medical applications. Surf Coat Technol 205: 1723–1729. https://doi.org/10.1016/j.surfcoat.2010.10.019 doi: 10.1016/j.surfcoat.2010.10.019 |
[47] | Rakhadilov BK, Kovalevsky P, Baizhan DR, et al. (2022) Investigation of the modes of oxide coating on titanium Ti-6AL-4V by plasma-electrolytic oxidation. Bull D Serikbayev East Kazakhstan State Tech Univ 1: 100–111. https://doi.org/10.51885/1561-4212_2022_1_100 doi: 10.51885/1561-4212_2022_1_100 |
[48] | Collins TJ (2007) ImageJ for microscopy. Biotechniques 43: S25–S30. https://doi.org/10.2144/000112517 doi: 10.2144/000112517 |
[49] | Kulkov AS, Smolin IY, Mikushina VA (2019) Structural features of porous ceramics obtained at different sintering temperatures. International Conference and the VIII All-Russian Scientific and Practical Conference with international participation, dedicated to the 50th anniversary of the founding of the Institute of Petroleum Chemistry, National Research Tomsk State University, Tomsk. https://doi.org/10.17223/9785946218412/93 |
[50] | Dudareva NY, Kolomeichenko AV, Deev VB, et al. (2022) Porosity of oxide ceramic coatings formed by micro-arc oxidation on high-silicon aluminum alloys. J Surf Investig 16: 1308–1314. https://doi.org/10.1134/S1027451022060362 doi: 10.1134/S1027451022060362 |
[51] | Sharkeev YP, Komarova EG, Chebodaeva VV, et al. (2021) Amorphous–crystalline calcium phosphate coating promotes in vitro growth of tumor-derived jurkat T cells activated by anti-CD2/CD3/CD28 antibodies. Materials 14: 3693. https://doi.org/10.3390/ma14133693 doi: 10.3390/ma14133693 |
[52] | Komarova EG, Sharkeev YP, Sedelnikova MB, et al. (2020) Zn-or Cu-containing CaP-based coatings formed by micro-arc oxidation on titanium and Ti-40Nb alloy: Part Ⅰ—Microstructure, composition and properties. Materials 13: 4116. https://doi.org/10.3390/ma13194366 doi: 10.3390/ma13194366 |
[53] | Sharkeev Y, Komarova E, Sedelnikova M, et al. (2017) Structure and properties of micro-arc calcium phosphate coatings on pure titanium and Ti–40Nb alloy. T Nonferr Metal Soc 27: 125–133. https://doi.org/10.1016/s1003-6326(17)60014-1 doi: 10.1016/s1003-6326(17)60014-1 |
[54] | Glazov IE, Krut'ko VK, Musskaya ON, et al. (2022) Calcium phosphate apatites: wet formation, thermal transformations, terminology, and identification. Russ J Inorg Chem 67: 173–182. https://doi.org/10.1134/S0036023622020048 doi: 10.1134/S0036023622020048 |
[55] | Matykina E, Arrabal R, Mohedano M, et al. (2013) Stability of plasma electrolytic oxidation coating on titanium in artificial saliva. Mater Sci: Mater Med 24: 37–51. https://doi.org/10.1007/s10856-012-4787-z doi: 10.1007/s10856-012-4787-z |
[56] | Sodium phosphate (Na3PO4)—Molecular mass, structure, properties and uses. Available from: https://byjus.com/chemistry/sodium-phosphate/. |
[57] | Blau P (2001) The significance and use of the friction coefficient. Tribol Int 34: 585–591. https://doi.org/10.1016/S0301-679X(01)00050-0 doi: 10.1016/S0301-679X(01)00050-0 |
[58] | Cheng YH, Browne T, Heckerman B, et al. (2011) Influence of the C content on the mechanical and tribological properties of the TiCN coatings deposited by LAFAD technique. Surf Coat Technol 205: 4024–4029. https://doi.org/10.1016/j.surfcoat.2011.02.032 doi: 10.1016/j.surfcoat.2011.02.032 |
[59] | Martínez AL, Flamini DO, Saidman SB (2022) Corrosion resistance improvement of Ti-6Al-4V alloy by anodization in the presence of inhibitor ions. Trans Nonferrous Met Soc China 32: 1896–1909. https://doi.org/10.1016/S1003-6326(22)65917-X doi: 10.1016/S1003-6326(22)65917-X |