Research article

The impact of technological parameters of electrolytic-plasma treatment on the changes in the mechano-tribological properties of steel 45

  • Received: 17 June 2024 Revised: 23 July 2024 Accepted: 29 July 2024 Published: 12 August 2024
  • This article presents the results of research on the effects of electrolyte plasma hardening on the structure, phase composition, tribological, and mechanical properties of medium-carbon structural steel 45, which is widely used in the manufacturing of tools and machine parts. Hardening experiments were conducted using an electrolyte plasma hardening setup with electrolytes varying in sodium carbonate (Na2CO3) concentration in distilled water (15%, 20%, and 25%). With a consistent heating duration of 4 s during quenching, significant phase changes in the steel's microstructure were observed, enhancing hardness and wear resistance. The transformation of the initial structure of steel 45, which consists of ferrite and pearlite into martensite on the surface of the samples, led to an increase in microhardness up to 506–690 HV01. This value is 2.5–3.5 times higher compared to the untreated sample, and the thickness of the hardened layer reached up to 3.2 mm. Additionally, wear volume measurements showed that after electrolyte plasma hardening, the wear resistance of the samples increased by 1.3–1.5 times (2.01 × 10−4, 2.26 × 10−4 m3). The obtained results on the changes in microstructure and mechano-tribological properties of steel 45 confirm the potential of electrolyte plasma hardening technology for improving operational characteristics and extending the service life of heavily loaded and critical machine parts.

    Citation: Bauyrzhan Rakhadilov, Rinat Kussainov, Aisulu Kalitova, Zarina Satbayeva, Aibek Shynarbek. The impact of technological parameters of electrolytic-plasma treatment on the changes in the mechano-tribological properties of steel 45[J]. AIMS Materials Science, 2024, 11(4): 666-683. doi: 10.3934/matersci.2024034

    Related Papers:

  • This article presents the results of research on the effects of electrolyte plasma hardening on the structure, phase composition, tribological, and mechanical properties of medium-carbon structural steel 45, which is widely used in the manufacturing of tools and machine parts. Hardening experiments were conducted using an electrolyte plasma hardening setup with electrolytes varying in sodium carbonate (Na2CO3) concentration in distilled water (15%, 20%, and 25%). With a consistent heating duration of 4 s during quenching, significant phase changes in the steel's microstructure were observed, enhancing hardness and wear resistance. The transformation of the initial structure of steel 45, which consists of ferrite and pearlite into martensite on the surface of the samples, led to an increase in microhardness up to 506–690 HV01. This value is 2.5–3.5 times higher compared to the untreated sample, and the thickness of the hardened layer reached up to 3.2 mm. Additionally, wear volume measurements showed that after electrolyte plasma hardening, the wear resistance of the samples increased by 1.3–1.5 times (2.01 × 10−4, 2.26 × 10−4 m3). The obtained results on the changes in microstructure and mechano-tribological properties of steel 45 confirm the potential of electrolyte plasma hardening technology for improving operational characteristics and extending the service life of heavily loaded and critical machine parts.



    加载中


    [1] Sharaya O, Vodolazskaya N (2019) Technological aspects of modification of surface layer of agricultural machines parts. Inn Agric Compl Probl Perspect 3: 82–92 (in Russian). Available from: https://www.bsaa.edu.ru/InfResource/library/Journal3(23)2019.pdf.
    [2] Aulov V, Rozhkov Y (2016) On the issue of combining electrospark and thermodiffusion methods for hardening the machine parts surfaces in the agribusiness. Mach Equip Rural Area 2: 28–32 (in Russian). Available from: https://doi.org/10.33267/2072-9642-2022-2-28-32.
    [3] Zobnev V, Markov A, Ivanov S, et al. (2014) Wear resistance of multicomponent diffusion boride coatings on working organs of agricultural machines. Mater Sci Mach Build 1: 435–439 (in Russian). Available from: https://elibrary.ru/download/elibrary_22610860_80996072.pdf.
    [4] Martínez-Vázquez J, Rodríguez-Ortiz G, Hortelano-Capetillo J, et al. (2021) Effect of induction heating on Vickers and Knoop hardness of 1045 steel heat treated. J Mech Eng 5: 8–15. https://doi.org/10.35429/JME.2021.15.5.8.15 doi: 10.35429/JME.2021.15.5.8.15
    [5] Dudnikov I (2011) Ensure the safety properties of parts that define security of agricultural machinery. Tech Audit Prod Res 1: 33–36 (in Russian). https://doi.org/10.15587/2312-8372.2011.4853 doi: 10.15587/2312-8372.2011.4853
    [6] Morshed-Behbahani K, Farhat Z, Nasiri A (2024) Effect of surface nanocrystallization on wear behavior of steels: A review. Materials 17: 1618. https://doi.org/10.3390/ma17071618 doi: 10.3390/ma17071618
    [7] Pour-Ali S, Kiani-Rashid A, Babakhani A, et al. (2018) Severe shot peening of AISI 321 with 1000% and 1300% coverages: A comparative study on the surface nanocrystallization, phase transformation, sub-surface microcracks, and microhardness. Int J Mater Res 109: 451–459. https://doi.org/10.3139/146.111622 doi: 10.3139/146.111622
    [8] Roy R, Ghosh S, Kaisar T, et al. (2022) Multi-response optimization of surface grinding process parameters of AISI 4140 alloy steel using response surface methodology and desirability function under dry and wet conditions. Coatings 12: 104. https://doi.org/10.3390/coatings12010104 doi: 10.3390/coatings12010104
    [9] Stepanova T (2009) Technologies of Surface Hardening of Machine Parts, Ivanovo: Ivanovo State Chemical-Technological University, 64p (in Russian). Available from: https://www.isuct.ru/sites/default/files/department/ightu/ktmio/08.pdf.
    [10] Ostromenskiy P, Aksenov V, Korotaev B, et al. (2001) Prospects for the use of high-energy technologies to increase the lateral wear resistance of rails. Curr Probl Transp Asian Part Russ 2001: 92–98 (in Russian). Available from: https://is.gd/dUCNDS.
    [11] Maisuradze M (2022) Induction and Laser Thermal Treatment of Steel Products: A Textbook, Yekaterinburg: Ural University Publishing, 96p (in Russian). Available from: https://elar.urfu.ru/bitstream/10995/117127/1/978-5-7996-3544-2_2022.pdf.
    [12] Khisamutdinov R, Zvezdin V, Israfilov I, et al. (2016) Study of processes of steels surfaces modification with highly concentrated energy flows. J Phys Conf Ser 669: 012024. https://doi.org/10.1088/1742-6596/669/1/012024 doi: 10.1088/1742-6596/669/1/012024
    [13] Barmin A, Rizakhanov R, Rudstein R (2012) Optimization of quenching regimes for carbon steels by electron beam treatment. Proc Interuniv Sci Sch Young Spec 1: 62–67 (in Russian). Available from: http://nuclphys.sinp.msu.ru/school/s12/12_15.pdf.
    [14] Belinin D, Shchitsyn Y (2012) Features of structurization at plasma surface hardening on big depth of products from 40Cr13. Proc Samara Sci Cent Russ Acad Sci 4: 1200–1205 (in Russian). Available from: https://elar.urfu.ru/bitstream/10995/30926/1/sid_2014_04.pdf.
    [15] Belinin D, Verkhorubov V, Kuchev P, et al. (2011) Plasma surface hardening of hard loading constructions made of steel 40Kh13. Bulletin Pnrpu 2: 12–18 (in Russian). Available from: https://cyberleninka.ru/article/n/plazmennaya-zakalka-tyazhelonagruzhennyh-detaley-iz-stali-40h13.
    [16] Sidorov S (1998) Technical level and resource of working organs of agricultural machinery. Tract Agric Mach 3: 29 (in Russian). Available from: https://rusneb.ru/catalog/000200_000018_RU_NLR_PER_B_2381825_1998_3/.
    [17] Kravchenko N (2013) Plasma Methods of Hardening and Restoration of Working Bodies Road-Building and Soil-Cultivating Machines, Moscow: Eco-Press, 328 p (in Russian). Available from: https://expo-books.ru/category/book?id = 12005.
    [18] Kanayev A (2015) Modernization of the surface layer structure of structural steel. Herald Scin Seifullin Kaz Agro Tehn Univ 3: 78–86 (in Russian). Available from: https://bulletinofscience.kazatu.edu.kz/index.php/bulletinofscience/article/view/701.
    [19] Korotkov V (2011) Wear resistance of plasma-hardened materials. J Frict Wear 32: 17–22. https://doi.org/10.3103/S1068366611010077 doi: 10.3103/S1068366611010077
    [20] Jumbad V, Chel A, Verma U (2020) Application of electrolytic plasma process in surface improvement of metals: A review. Letters Appl NanoBioSci 9: 1249–1262. https://doi.org/10.33263/lianbs93.12491262 doi: 10.33263/lianbs93.12491262
    [21] Gupta P, Tenhundfeld G, Daigle E (2007) Electrolytic plasma technology: Science and engineering—An overview. Surf Coat Tech 201: 8746–8760. https://doi.org/10.1016/j.surfcoat.2006.11.023 doi: 10.1016/j.surfcoat.2006.11.023
    [22] Rakhadilov B, Bayatanova L, Kurbanbekov S, et al. (2023) Investigation on the effect of technological parameters of electrolyte-plasma cementation method on phase structure and mechanical properties of structural steel 20X. AIMS Mater Sci 10: 934–947. https://doi.org/10.3934/matersci.2023050 doi: 10.3934/matersci.2023050
    [23] Meletis E, Nie X, Wang F (2002) Electrolytic plasma processing for cleaning and metal-coating of steel surfaces. Surf Coat Tech 150: 246–256. https://doi.org/10.1016/S0257-8972(01)01521-3 doi: 10.1016/S0257-8972(01)01521-3
    [24] Belkin P (2013) Electrolytic-plasma modification of metals and alloys. Bull Kostroma State Univ 5: 5–11 (in Russian). Available from: https://cyberleninka.ru/article/n/elektrolitno-plazmennaya-modifikatsiya-metallov-i-splavov-1.
    [25] Jiang Y, Bao Y, Wang M (2017) Kinetic analysis of additive on plasma electrolytic boriding. Coatings 7: 61. https://doi.org/10.3390/coatings7050061 doi: 10.3390/coatings7050061
    [26] Belkin V, Belkin P, Krit B, et al. (2019) Increasing wear resistance of low-carbon steel by anodic plasma-electrolytic nitroboriding. J Mater Eng Perform 29: 564–572. https://doi.org/10.1007/s11665-019-04521-1 doi: 10.1007/s11665-019-04521-1
    [27] Taheri P, Dehghanian C, Aliofkhazraei M, et al. (2007) Nanocrystalline structure produced by complex surface treatments: plasma electrolytic nitrocarburizing, boronitriding, borocarburizing, and borocarbonitriding. Plasma Process Polym 4: 721–727. https://doi.org/10.1002/ppap.200731805 doi: 10.1002/ppap.200731805
    [28] Skakov M, Rakhadilov B, Sheffler M (2013) Influence of electrolyte plasma treatment on structure, phase composition and microhardness of steel Р6М5. Key Eng Mater 531–532: 627–631. https://doi.org/10.4028/www.scientific.net/KEM.531-532.627 doi: 10.4028/www.scientific.net/KEM.531-532.627
    [29] Luk S, Leung T, Miu W (1999) A study of the effect of average preset voltage on effective case depth during electrolytic surface-hardening. Mater Charact 42: 65–71. https://doi.org/10.1016/S1044-5803(98)00044-8 doi: 10.1016/S1044-5803(98)00044-8
    [30] Tarakci M, Korkmaz K, Gencer Y (2005) Plasma electrolytic surface carburizing and hardening of pure iron. Surf Coat Tech 199: 205–212. https://doi.org/10.1016/j.surfcoat.2005.02.117 doi: 10.1016/j.surfcoat.2005.02.117
    [31] Satbayeva Z (2022) Structure Formation in Alloyed Steels During Electrolytic-Plasma Surface Hardening, Oskemen: Sarsen Amanzholov East Kazakhstan University, 160p (in Russian). Available from: https://nabrk.kz/ru/e-catalog?catalog=4&language=rus&page=8&sphere=3&topic=0&publication_type=13.
    [32] Suminov I (2011) Plasma Electrolytic Modification of the Surface of Metals and Alloys, Moscow: Tekhnosfera, 464 p (in Russian). Available from: https://f.eruditor.link/file/2686301/.
    [33] Cenk Kumruoğlu L, Özel A (2010) Surface modification of AISI 4140 steel using electrolytic plasma thermocyclic treatment. Mater Manuf Process 25: 923–931. https://doi.org/10.1080/10426911003720839 doi: 10.1080/10426911003720839
    [34] Sagdoldina Z, Zhurerova L, Tyurin Y, et al. (2022) Modification of the surface of 40Kh steel by electrolytic plasma hardening. Metals 12: 2071. https://doi.org/10.3390/met12122071 doi: 10.3390/met12122071
    [35] Smirnov M (1999) Fundamentals of Heat Treatment of Steel, Yekaterinburg: Ural Branch of the Russian Academy of Sciences, 494p (in Russian). Available from: http://www.materialscience.ru/shared_folder/matved/books/Smirnov_Osnovy_TO_stali.djvu.
    [36] Kartonova L (2020) Theory and Technology of Heat Treatment, Vladimir: Publishing house of Vladimir State University, 128p (in Russian). Available from: https://dspace.www1.vlsu.ru/bitstream/123456789/8725/1/02082.pdf.
    [37] Rasouli D, Khameneh Asl S, Akbarzadeh A, et al. (2008) Effect of cooling rate on the microstructure and mechanical properties of microalloyed forging steel. J Mater Process Technol 206: 92–98. https://doi.org/10.1016/j.jmatprotec.2007.12.006 doi: 10.1016/j.jmatprotec.2007.12.006
    [38] Sunardi S, Lusiani R, Listijorini E, et al. (2021) The effect of airflow speed as cooling media in the hardening process to the hardness, corrosion rate and fatigue life of medium carbon steel. Mater Sci Forum 1045: 40–49. https://doi.org/10.4028/www.scientific.net/msf.1045.40 doi: 10.4028/www.scientific.net/msf.1045.40
    [39] Jo H, Kang M, Park G, et al. (2020) Effects of cooling rate during quenching and tempering conditions on microstructures and mechanical properties of carbon steel flange. Materials 13: 4186. https://doi.org/10.3390/ma13184186 doi: 10.3390/ma13184186
    [40] Basori I, Pratiwi W, Dwiyati S (2019) Effect of salt quenching on the microstructures and mechanical properties of AISI 1045 steel. J Phys Conf Ser 5: 055102. https://doi.org/10.1088/1742-6596/1402/5/055102 doi: 10.1088/1742-6596/1402/5/055102
    [41] Pérez R, Llano M, Ravagli R, et al. (2018) Effect of machining fluid like quenching media on the friction and wear behavior of AISI 1045 steel. Int J Mech Eng Technol 9: 146–154. Available from: https://iaeme.com/MasterAdmin/Journal_uploads/IJMET/VOLUME_9_ISSUE_7/IJMET_09_07_017.pdf.
    [42] Vieira E, Biehl L, Medeiros J, et al. (2021) Evaluation of the characteristics of an AISI 1045 steel quenched in different concentration of polymer solutions of polyvinylpyrrolidone. Sci Rep 11: 1313. https://doi.org/10.1038/s41598-020-79060-0 doi: 10.1038/s41598-020-79060-0
    [43] Dayanç A, Karaca B, Kumruoğlu L (2017) The cathodic electrolytic plasma hardening of steel and cast iron based automotive camshafts. Acta Phys Pol A 131: 374–378. https://doi.org/10.12693/APhysPolA.131.374 doi: 10.12693/APhysPolA.131.374
    [44] Belkin P, Kusmanov S (2016) Plasma electrolytic hardening of steels: review. Surf Engin Appl Electrochem 52: 531–546. https://doi.org/10.3103/S106837551606003X doi: 10.3103/S106837551606003X
    [45] Bayati M, Molaei R, Janghorban K (2011) Surface alloying of carbon steels from electrolytic plasma. Met Sci Heat Treat 53: 91–94. https://doi.org/10.1007/s11041-011-9347-5 doi: 10.1007/s11041-011-9347-5
    [46] Rakhadilov B, Satbayeva Z, Bayatanova L, et al. (2019) Influence of electrolyte-plasma surface hardening on the structure and properties of steel 40KhN. J Phys Conf Ser 1393: 012119. https://doi.org/101088/1742-6596/1393/1/012119
    [47] Ayday A, Durman M (2013) Surface hardening of ductile cast iron by electrolytic plasma technology. Acta Phys Pol A 123: 291–293. https://doi.org/10.12693/APhysPolA.123.291 doi: 10.12693/APhysPolA.123.291
    [48] Gorelik S (2002) X-ray and Electron-optical Analysis, 4 Eds., Moscow: Publishing house MISIS, 360 p (in Russian). Available from: https://www.geokniga.org/bookfiles/geokniga-rentgenograficheskiy-analiz.pdf.
    [49] Rastkar A, Shokri B (2012) Surface modification and wear test of carbon steel by plasma electrolytic nitrocarburizing. Surf Interface Anal 44: 342–351. https://doi.org/10.1002/sia.3808 doi: 10.1002/sia.3808
    [50] Zhang L, Jin Y, Wang X, et al. (2019) Surface alloys of 0.45 C carbon steel produced by high current pulsed electron beam. High Temp Mater Process 38: 444–451. https://doi.org/10.1515/htmp-2018-0065 doi: 10.1515/htmp-2018-0065
    [51] Zheng B, Huang Z, Xing J, et al. (2016) Three-body abrasive behavior of cementite–iron composite with different cementite volume fractions. Tribol Lett 62: 1–11. https://doi.org/10.1007/s11249-016-0683-x doi: 10.1007/s11249-016-0683-x
    [52] Yaghmazadeh M, Dehghanian C (2009) Surface hardening of AISI H13 steel using pulsed plasma electrolytic carburizing (PPEC). Plasma Processes Polym 6: S168–S172. https://doi.org/10.1002/ppap.200930410 doi: 10.1002/ppap.200930410
    [53] Kurbanbekov S, Skakov M, Baklanov V, et al. (2017) Changes in mechanical properties and structure of electrolytic plasma treated×12 CrNi18 10 Ti stainless steel. Mater Test 59: 361–365. https://doi.org/10.3139/120.111014 doi: 10.3139/120.111014
    [54] Skakov M, Zhurerova L, Scheffler M (2013) Influence of regimes electrolytic-plasma processing on phase structure and hardening of steel 30CrMnSi. Adv Mat Res 601: 79–83. https://doi.org/10.4028/www.scientific.net/AMR.601.79 doi: 10.4028/www.scientific.net/AMR.601.79
    [55] Tabieva E, Zhurerova L, Baizhan D (2020) Influence of electrolyte-plasma hardening technological parameters on the structure and properties of banding steel 2. Key Eng Mater 839: 57–62. https://doi.org/10.4028/www.scientific.net/KEM.839.57 doi: 10.4028/www.scientific.net/KEM.839.57
    [56] Bayati M, Molaei R, Janghorban K (2010) Surface modification of AISI 1045 carbon steel by the electrolytic plasma process. Metall Mater Trans A 41: 906–911. https://doi.org/10.1007/s11661-009-0165-y doi: 10.1007/s11661-009-0165-y
    [57] Nunura C, Santos C, Spim J (2015) Numerical–experimental correlation of microstructures, cooling rates and mechanical properties of AISI 1045 steel during the Jominy end-quench test. Mater Des 76: 230–243. https://doi.org/10.1016/j.matdes.2015.03.031 doi: 10.1016/j.matdes.2015.03.031
    [58] Li Q, Xiao K, Lu Z, et al. (2024) Mechanism of laser carbonitriding enhancing the wear resistance of 45# steel. Mater Today Commun 38: 108327. https://doi.org/10.1016/j.mtcomm.2024.108327 doi: 10.1016/j.mtcomm.2024.108327
    [59] Korotkov V (2015) Wear resistance of carbon steel with different types of hardening. J Frict Wear 36: 149–152. https://doi.org/10.3103/S1068366615020105 doi: 10.3103/S1068366615020105
    [60] Algodi S, Salman A, Al-Helli A (2023) Microstructure and mechanical properties of AISI 1106/AISI 1045 steels drawn arc stud welded joints. Adv Sci Technol Res J 17: 48–55. https://doi.org/10.12913/22998624/171020 doi: 10.12913/22998624/171020
  • Reader Comments
  • © 2024 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(308) PDF downloads(63) Cited by(0)

Article outline

Figures and Tables

Figures(9)  /  Tables(2)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog