Research article Topical Sections

Nacre-like ceramic/polymer laminated composite for use in body-armor applications

  • Received: 18 November 2015 Accepted: 11 January 2016 Published: 12 January 2016
  • Nacre is a biological material constituting the innermost layer of the shells of gastropods and bivalves. It consists of polygonal tablets of aragonite, tessellated to form individual layers and having the adjacent layers as well as the tablets within a layer bonded by a biopolymer. Due to its highly complex hierarchical microstructure, nacre possesses an outstanding combination of mechanical properties, the properties which are far superior to the ones that are predicted using the techniques such as the rule of mixture. In the present work, an attempt is made to model a nacre-like composite armor consisting of boron carbide (B4C) tablets and polyurea tablet/tablet interfaces. The armor is next investigated with respect to impact by a solid right-circular-cylindrical rigid projectile, using a transient non-linear dynamics finite element analysis. The ballistic-impact response and the penetration resistance of the armor is then compared with that of the B4C monolithic armor having an identical areal density. Furthermore, the effect of various nacre microstructural features (e.g. surface profiling, micron-scale asperities, mineral bridges between the overlapping tablets lying in adjacent layers, and B4C nano-crystallinity) on the ballistic-penetration resistance of the composite-armor is investigated in order to identify an optimal nacre-like composite-armor architecture having the largest penetration resistance. The results obtained clearly show that a nacre-like armor possesses a superior penetration resistance relative to its monolithic counterpart, and that the nacre microstructural features considered play a critical role in the armor penetration resistance.

    Citation: Mica Grujicic, S. Ramaswami, Jennifer Snipes. Nacre-like ceramic/polymer laminated composite for use in body-armor applications[J]. AIMS Materials Science, 2016, 3(1): 83-113. doi: 10.3934/matersci.2016.1.83

    Related Papers:

  • Nacre is a biological material constituting the innermost layer of the shells of gastropods and bivalves. It consists of polygonal tablets of aragonite, tessellated to form individual layers and having the adjacent layers as well as the tablets within a layer bonded by a biopolymer. Due to its highly complex hierarchical microstructure, nacre possesses an outstanding combination of mechanical properties, the properties which are far superior to the ones that are predicted using the techniques such as the rule of mixture. In the present work, an attempt is made to model a nacre-like composite armor consisting of boron carbide (B4C) tablets and polyurea tablet/tablet interfaces. The armor is next investigated with respect to impact by a solid right-circular-cylindrical rigid projectile, using a transient non-linear dynamics finite element analysis. The ballistic-impact response and the penetration resistance of the armor is then compared with that of the B4C monolithic armor having an identical areal density. Furthermore, the effect of various nacre microstructural features (e.g. surface profiling, micron-scale asperities, mineral bridges between the overlapping tablets lying in adjacent layers, and B4C nano-crystallinity) on the ballistic-penetration resistance of the composite-armor is investigated in order to identify an optimal nacre-like composite-armor architecture having the largest penetration resistance. The results obtained clearly show that a nacre-like armor possesses a superior penetration resistance relative to its monolithic counterpart, and that the nacre microstructural features considered play a critical role in the armor penetration resistance.


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    [1] Lopes-Lima M, Rocha A, Goncxalves F, et al. (2010) Microstructural characterization of inner shell layers in the freshwater bivalve Anodonta Cygnea. J Shellfish Res 29: 969–973. doi: 10.2983/035.029.0431
    [2] Sun J and Bhushan B (2012) Hierarchical structure and mechanical properties of nacre: a review. RSC Adv 2: 7617–7632. doi: 10.1039/c2ra20218b
    [3] Hedegaard C, Wenk H (1998) Microstructure and texture patterns of mollusc shells. J Mollus Stud 64: 133–136. doi: 10.1093/mollus/64.1.133
    [4] Barthelat F, Tang H, Zavattieri PD, et al. (2007) On the mechanics of mother-of-pearl: A key feature in the material hierarchical structure. J Mech Phys Solids 55: 306–337. doi: 10.1016/j.jmps.2006.07.007
    [5] Schäffer TE, Ionescu-Zanetti C, Proksch R, et al. (1997) Does abalone nacre form by heteroepitaxial nucleation or by growth through mineral bridges? Chem Mater 9: 1731–1740. doi: 10.1021/cm960429i
    [6] Li XD, Chang WC, Chao YJ, et al. (2004) Nanoscale structural and mechanical characterization of a natural nanocomposite material: the shell of red abalone. Nano Lett 4: 613–617. doi: 10.1021/nl049962k
    [7] Jackson AP, Vincent JFV, Turner RM (1988) The mechanical design of nacre. P Roy Soc B 234: 415–440. doi: 10.1098/rspb.1988.0056
    [8] Mohanty B, Katti KS, Katti DR, et al. (2006) Dynamic nanomechanical response of nacre. J Mater Res 21: 2045–2051. doi: 10.1557/jmr.2006.0247
    [9] Sun JY, Tong J (2007) Fracture toughness properties of three different biomaterials measured by nanoindentation. J Bionic Eng 4: 11–17. doi: 10.1016/S1672-6529(07)60007-9
    [10] Currey JD (1977) Mechanical properties of mother of pearl in tension. P Roy Soc Ser B 196: 443–463. doi: 10.1098/rspb.1977.0050
    [11] Browning A, Ortiz C, Boyce MC (2013) Mechanics of composite elasmoid fish scale assemblies and their bioinspired analogues. J Mech Behav Biomed 19: 75–86. doi: 10.1016/j.jmbbm.2012.11.003
    [12] Dutta A, Vanderklor A, Tekalur SA (2012) High strain rate mechanical behavior of seashell-mimetic composites: Analytical model formulation and validation. Mech Mater 55: 102–111. doi: 10.1016/j.mechmat.2012.08.003
    [13] Knipprath C, Bond IP, Trask RS (2012) Biologically inspired crack delocalization in a high strain-rate environment. J Roy Soc Interf 9: 665–676. doi: 10.1098/rsif.2011.0442
    [14] Tran P, Ngo TD, Mendis P (2014) Bioinspired composite structures subjected to underwater impulsive loading. Comput Mater Sci 82: 134–139. doi: 10.1016/j.commatsci.2013.09.033
    [15] Flores-Johnson EA, Shen L, Guiamatsia I, et al. (2015) A numerical study of bioinspired nacre-like composite plates under blast loading. Compos Struct 126: 329–336. doi: 10.1016/j.compstruct.2015.02.083
    [16] Grujicic M, Pandurangan B, Coutris N (2012) A computational investigation of the multi-hit ballistic-protection performance of laminated transparent armor systems. J Mater Eng Perform 21: 837–848.
    [17] Grujicic M, Bell WC, Pandurangan B, et al. (2012) Effect of the tin- vs. air-side plate-glass orientation on the impact response and penetration resistance of a laminated transparent-armor structure. J Mater: Des Appl 226: 119–143.
    [18] Grujicic M, Snipes JS, Ramaswami S, et al. (2014) Analysis of steel-with-composite material substitution in military-vehicle hull-floors subjected to shallow-buried landmine-detonation loads. Multidisc Model Mater Struct 10: 416–448. doi: 10.1108/MMMS-01-2014-0001
    [19] Grujicic M, Galgalikar R, Ramaswami S, et al. (2014) Finite-element analysis of horizontal-axis wind-turbine gearbox failure via tooth-bending fatigue. Int J Mater Mech Eng 3: 6–15. doi: 10.14355/ijmme.2014.0301.02
    [20] Grujicic M, Ramaswami S, Snipes JS, et al. (2014) Computer-aided engineering analysis of tooth-bending fatigue-based failure in horizontal-axis wind-turbine gearboxes. Int J Struct Integr 5: 60–82. doi: 10.1108/IJSI-08-2013-0017
    [21] ABAQUS Version 6.14, User Documentation, Dassault Systèmes, 2014.
    [22] Grujicic M, Bell WC, Pandurangan B, et al. (2012) Inclusion of material nonlinearity and inelasticity into a continuum-level material model for soda-lime glass. Mater Des 35: 144–155. doi: 10.1016/j.matdes.2011.08.031
    [23] Grujicic M, Yavari R, Snipes JS, et al. (2014) All-atom molecular-level computational simulations of planar longitudinal shockwave interactions with polyurea, soda-lime glass and polyurea/glass interfaces. Multidisc Model Mater Struct 10: 474–510. doi: 10.1108/MMMS-11-2013-0070
    [24] Grujicic M, Yavari R, Snipes JS, et al. (2014) All-atom molecular-level computational analyses of polyurea/fused-silica interfacial decohesion caused by impinging tensile stress-waves. Int J Struct Integr 5: 339–367. doi: 10.1108/IJSI-01-2014-0001
    [25] Johnson GR, Holmquist TJ (1994) An improved computational constitutive model for brittle materials. In High-Pressure science and technology, 1993: proceedings of the joint International Association for Research and Advancement of High Pressure Science, American Institute of Physics, New York, pp. 981–984.
    [26] Amirkhizi AV, Isaacs J, McGee J, et al. (2006) An experimentally-based viscoelastic constitutive model for polyurea, including pressure and temperature effects. Phil Mag 86: 5847–5866. doi: 10.1080/14786430600833198
    [27] Grujicic M, Bell WC, Pandurangan B, et al. (2010) Blast-wave impact-mitigation capability of polyurea when used as helmet suspension pad material. Mater Des 31: 4050–4065. doi: 10.1016/j.matdes.2010.05.002
    [28] Grujicic M, Chenna V, Galgalikar R, et al. (2014) Wind-turbine gear-box roller-bearing premature-failure caused by grain-boundary hydrogen embrittlement. J Mater Eng Perform 23: 3984–4001. doi: 10.1007/s11665-014-1188-0
    [29] Grujicic M, Chenna V, Galgalikar R, et al. (2014) Computational analysis of gear-box roller-bearing white-etch cracking: a multi-physics approach. Int J Struct Integr 5: 290–327. doi: 10.1108/IJSI-10-2013-0028
    [30] Grujicic M, Pandurangan B, d’Entremont BP, et al. (2012) The role of adhesive in the ballistic/structural performance of ceramic/polymer-matrix composite hybrid armor. Mater Des 41: 380–393. doi: 10.1016/j.matdes.2012.05.023
    [31] Grujicic M, Snipes JS, Galgalikar R, et al. (2015). Multi-length-scale derivation of the room-temperature material constitutive model for SiC/SiC ceramic-matrix composites (CMCs). J Mater: Des Appl [In press]. DOI: 10.1177/1464420715600002
    [32] Grujicic M, Snipes JS, Galgalikar R, et al. (2014). Material-Model Based Determination of the Shock-Hugoniot Relations in Nanosegregated Polyurea. J Mater Eng Perform 23: 357–371. doi: 10.1007/s11665-013-0769-7
    [33] Grujicic M, Ramaswami S, Snipes JS, et al. (2014). Multi-scale computation-based design of nano-segregated polyurea for maximum shockwave-mitigation performance. AIMS Mater Sci 1: 15–27. doi: 10.3934/matersci.2014.1.15
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  • © 2016 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
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