Research article Topical Sections

Energy and tellurium deposits

  • Received: 05 November 2023 Revised: 20 December 2023 Accepted: 11 January 2024 Published: 19 January 2024
  • In this article, we focus on the next generation of green batteries that are closely related to semi-metallic tellurium and its deposits. We briefly summarize the chemical and geochemical characteristics of tellurium that ordinary readers are not familiar with or have never heard of, and its important role in many fields such as high-tech and medical care, current global resource distribution, major mineral extraction and purification technologies and market evolution, etc. The spatiotemporal distribution of the two main types of tellurium deposits, namely associated tellurium deposits and independent tellurium deposits, is introduced in detail. The geological and geochemical characteristics of the only independent tellurium deposit in the world are introduced in detail, so that relevant researchers can use this deposit as an example to discover more independent tellurium deposits around the world, meeting people's increasingly urgent demand for tellurium and realizing the sustainable development of human society. We believe that humans will discover more and more new energy metals in the near future to meet the dual goals of protecting the earth's environment and developing the economy, which are contradictory and mutually reinforcing. New generation of energy metal batteries must be small, compact, easy to carry, charge quickly, and have a long life.

    Citation: Jianzhao Yin, Haoyu Yin, Yuhong Chao, Hongyun Shi. Energy and tellurium deposits[J]. AIMS Geosciences, 2024, 10(1): 28-42. doi: 10.3934/geosci.2024002

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  • In this article, we focus on the next generation of green batteries that are closely related to semi-metallic tellurium and its deposits. We briefly summarize the chemical and geochemical characteristics of tellurium that ordinary readers are not familiar with or have never heard of, and its important role in many fields such as high-tech and medical care, current global resource distribution, major mineral extraction and purification technologies and market evolution, etc. The spatiotemporal distribution of the two main types of tellurium deposits, namely associated tellurium deposits and independent tellurium deposits, is introduced in detail. The geological and geochemical characteristics of the only independent tellurium deposit in the world are introduced in detail, so that relevant researchers can use this deposit as an example to discover more independent tellurium deposits around the world, meeting people's increasingly urgent demand for tellurium and realizing the sustainable development of human society. We believe that humans will discover more and more new energy metals in the near future to meet the dual goals of protecting the earth's environment and developing the economy, which are contradictory and mutually reinforcing. New generation of energy metal batteries must be small, compact, easy to carry, charge quickly, and have a long life.



    Let Mn be the set of n×n complex matrices. Mn(Mk) is the set of n×n block matrices with each block in Mk. For AMn, the conjugate transpose of A is denoted by A. When A is Hermitian, we denote the eigenvalues of A in nonincreasing order λ1(A)λ2(A)...λn(A); see [2,7,8,9]. The singular values of A, denoted by s1(A),s2(A),...,sn(A), are the eigenvalues of the positive semi-definite matrix |A|=(AA)1/2, arranged in nonincreasing order and repeated according to multiplicity as s1(A)s2(A)...sn(A). If AMn is positive semi-definite (definite), then we write A0(A>0). Every AMn admits what is called the cartesian decomposition A=ReA+iImA, where ReA=A+A2, ImA=AA2. A matrix AMn is called accretive if ReA is positive definite. Recall that a norm |||| on Mn is unitarily invariant if ||UAV||=||A|| for any AMn and unitary matrices U,VMn. The Hilbert-Schmidt norm is defined as ||A||22=tr(AA).

    For A,B>0 and t[0,1], the weighted geometric mean of A and B is defined as follows

    AtB =A1/2(A1/2BA1/2)tA1/2.

    When t=12, A12B is called the geometric mean of A and B, which is often denoted by AB. It is known that the notion of the (weighted) geometric mean could be extended to cover all positive semi-definite matrices; see [3, Chapter 4].

    Let A,B,XMn. For 2×2 block matrix M in the form

    M=(AXXB)M2n

    with each block in Mn, its partial transpose of M is defined by

    Mτ=(AXXB).

    If M and Mτ0, then we say it is positive partial transpose (PPT). We extend the notion to accretive matrices. If

    M=(AXYB)M2n,

    and

    Mτ=(AYXC)M2n

    are both accretive, then we say that M is APT (i.e., accretive partial transpose). It is easy to see that the class of APT matrices includes the class of PPT matrices; see [6,10,13].

    Recently, many results involving the off-diagonal block of a PPT matrix and its diagonal blocks were presented; see [5,11,12]. In 2023, Alakhrass [1] presented the following two results on 2×2 block PPT matrices.

    Theorem 1.1 ([1], Theorem 3.1). Let (AXXB) be PPT and let X=U|X| be the polar decomposition of X, then

    |X|(AtB)(U(A1tB)U),t[0,1].

    Theorem 1.2 ([1], Theorem 3.2). Let (AXXB) be PPT, then for t[0,1],

    ReX(AtB)(A1tB)(AtB)+(A1tB)2,

    and

    ImX(AtB)(A1tB)(AtB)+(A1tB)2.

    By Theorem 1.1 and the fact si+j1(XY)si(X)sj(Y)(i+jn+1), the author obtained the following corollary.

    Corollary 1.3 ([1], Corollary 3.5). Let (AXXB) be PPT, then for t[0,1],

    si+j1(X)si(AtB)sj(A1tB).

    Consequently,

    s2j1(X)sj(AtB)sj(A1tB).

    A careful examination of Alakhrass' proof in Corollary 1.3 actually revealed an error. The right results are si+j1(X)si(AtB)12sj((A1tB)12) and s2j1(X)sj((AtB)12)sj((A1tB)12). Thus, in this note, we will give a correct proof of Corollary 1.3 and extend the above inequalities to the class of 2×2 block APT matrices. At the same time, some relevant results will be obtained.

    Before presenting and proving our results, we need the following several lemmas of the weighted geometric mean of two positive matrices.

    Lemma 2.1. [3, Chapter 4] Let X,YMn be positive definite, then

    1) XY=max{Z:Z=Z,(XZZY)0}.

    2) XY=X12UY12 for some unitary matrix U.

    Lemma 2.2. [4, Theorem 3] Let X,YMn be positive definite, then for every unitarily invariant norm,

    ||XtY||||X1tYt||||(1t)X+tY||.

    Now, we give a lemma that will play an important role in the later proofs.

    Lemma 2.3. Let M=(AXYB)M2n be APT, then for t[0,1],

    (ReAtReBX+Y2X+Y2ReA1tReB)

    is PPT.

    Proof: Since M is APT, we have that

    ReM=(ReAX+Y2X+Y2ReB)

    is PPT.

    Therefore, ReM0 and ReMτ0.

    By the Schur complement theorem, we have

    ReBX+Y2(ReA)1X+Y20,

    and

    ReAX+Y2(ReB)1X+Y20.

    Compute

    X+Y2(ReAtReB)1X+Y2=X+Y2((ReA)1t(ReB)1)X+Y2=(X+Y2(ReA)1X+Y2)t(X+Y2(ReB)1X+Y2)ReBtReA.

    Thus,

    (ReBtReA)X+Y2(ReAtReB)1X+Y20.

    By utilizing (ReBtReA)=ReA1tReB, we have

    (ReAtReBX+Y2X+Y2ReA1tReB)0.

    Similarly, we have

    (ReAtReBX+Y2X+Y2ReA1tReB)0.

    This completes the proof.

    First, we give the correct proof of Corollary 1.3.

    Proof: By Theorem 1.1, there exists a unitary matrix UMn such that |X|(AtB)(U(A1tB)U). Moreover, by Lemma 2.1, we have (AtB)(U(A1tB)U)=(AtB)12V(U(A1tB)12U). Now, by si+j1(AB)si(A)sj(B), we have

    si+j1(X)si+j1((AtB)(U(A1tB)U))=si+j1((AtB)12VU(A1tB)12U)si((AtB)12)sj((A1tB)12),

    which completes the proof.

    Next, we generalize Theorem 1.1 to the class of APT matrices.

    Theorem 2.4. Let M=(AXYB) be APT, then

    |X+Y2|(ReAtReB)(U(ReA1tReB)U),

    where UMn is any unitary matrix such that X+Y2=U|X+Y2|.

    Proof: Since M is an APT matrix, we know that

    (ReAtReBX+Y2X+Y2ReB1tReA)

    is PPT.

    Let W be a unitary matrix defined as W=(I00U). Thus,

    W(ReAtReBX+Y2X+Y2ReA1tReB)W=(ReAtReB|X+Y2||X+Y2|U(ReA1tReB)U)0.

    By Lemma 2.1, we have

    |X+Y2|(ReAtReB)(U(ReA1tReB)U).

    Remark 1. When M=(AXYB) is PPT in Theorem 2.4, our result is Theorem 1.1. Thus, our result is a generalization of Theorem 1.1.

    Using Theorem 2.4 and Lemma 2.2, we have the following.

    Corollary 2.5. Let M=(AXYB) be APT and let t[0,1], then for every unitarily invariant norm |||| and some unitary matrix UMn,

    ||X+Y2||||(ReAtReB)(U(ReA1tReB)U)||||(ReAtReB)+U(ReA1tReB)U2||||ReAtReB||+||ReA1tReB||2||(ReA)1t(ReB)t||+||(ReA)t(ReB)1t||2||(1t)ReA+tReB||+||tReA+(1t)ReB||2.

    Proof: The first inequality follows from Theorem 2.4. The third one is by the triangle inequality. The other conclusions hold by Lemma 2.2.

    In particular, when t=12, we have the following result.

    Corollary 2.6. Let M=(AXYB) be APT, then for every unitarily invariant norm |||| and some unitary matrix UMn,

    ||X+Y2||||(ReAReB)(U(ReAReB)U)||||(ReAReB)+U(ReAReB)U2||||ReAReB||||(ReA)12(ReB)12||||ReA+ReB2||.

    Squaring the inequalities in Corollary 2.6, we get a quick consequence.

    Corollary 2.7. If M=(AXYB) is APT, then

    tr((X+Y2)(X+Y2))tr((ReAReB)2)tr(ReAReB)tr((ReA+ReB2)2).

    Proof: Compute

    tr((X+Y2)(X+Y2))tr((ReAReB)(ReAReB))=tr((ReAReB)2)tr((ReA)(ReB))tr((ReA+ReB2)2).

    It is known that for any X,YMn and any indices i,j such that i+jn+1, we have si+j1(XY)si(X)sj(Y) (see [2, Page 75]). By utilizing this fact and Theorem 2.4, we can obtain the following result.

    Corollary 2.8. Let M=(AXYB) be APT, then for any t[0,1], we have

    si+j1(X+Y2)si((ReAtReB)12)sj((ReA1tReB)12).

    Consequently,

    s2j1(X+Y2)sj((ReAtReB)12)sj((ReA1tReB)12).

    Proof: By Lemma 2.1 and Theorem 2.4, observe that

    si+j1(X+Y2)=si+j1(|X+Y2|)si+j1((ReAtReB)(U(ReA1tReB)U))=si+j1((ReAtReB)12V(U(ReA1tReB)U)12)si((ReAtReB)12V)sj((U(ReA1tReB)U)12)=si((ReAtReB)12)sj((ReA1tReB)12).

    Finally, we study the relationship between the diagonal blocks and the real part of the off-diagonal blocks of the APT matrix M.

    Theorem 2.9. Let M=(AXYB) be APT, then for all t[0,1],

    Re(X+Y2)(ReAtReB)(ReA1tReB)(ReAtReB)+(ReA1tReB)2,

    and

    Im(X+Y2)(ReAtReB)(ReA1tReB)(ReAtReB)+(ReA1tReB)2.

    Proof: Since M is APT, we have that

    ReM=(ReAX+Y2X+Y2ReB)

    is PPT.

    Therefore,

    (ReAtReBRe(X+Y2)Re(X+Y2)ReA1tReB)=12(ReAtReBX+Y2X+Y2ReA1tReB)+12(ReAtReBX+Y2X+Y2ReA1tReB)0.

    So, by Lemma 2.1, we have

    Re(X+Y2)(ReAtReB)(ReA1tReB).

    This implies the first inequality.

    Since ReM is PPT, we have

    (ReAiX+Y2iX+Y2ReB)=(I00iI)(ReM)(I00iI)0,(ReAiX+Y2iX+Y2ReB)=(I00iI)((ReM)τ)(I00iI)0.

    Thus,

    (ReAiX+Y2iX+Y2ReB)

    is PPT.

    By Lemma 2.3,

    (ReAtReBiX+Y2iX+Y2ReA1tReB)

    is also PPT.

    So,

    12(ReAtReBiX+Y2iX+Y2ReA1tReB)+12(ReAtReBiX+Y2iX+Y2ReA1tReB)0,

    which means that

    (ReAtReBIm(X+Y2)Im(X+Y2)ReA1tReB)0.

    By Lemma 2.1, we have

    Im(X+Y2)(ReAtReB)(ReA1tReB).

    This completes the proof.

    Corollary 2.10. Let (ReAX+Y2X+Y2ReB)0. If X+Y2 is Hermitian and t[0,1], then,

    X+Y2(ReAtReB)(ReA1tReB)(ReAtReB)+(ReA1tReB)2.

    The authors declare they have not used Artificial Intelligence (AI) tools in the creation of this article.

    The work is supported by National Natural Science Foundation (grant No. 12261030), Hainan Provincial Natural Science Foundation for High-level Talents (grant No. 123RC474), Hainan Provincial Natural Science Foundation of China (grant No. 124RC503), the Hainan Provincial Graduate Innovation Research Program (grant No. Qhys2023-383 and Qhys2023-385), and the Key Laboratory of Computational Science and Application of Hainan Province.

    The authors declare that they have no conflict of interest.



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