Mini review

An overview of sustainable green inhibitors for aluminum in acid media

  • Received: 24 July 2022 Revised: 25 September 2022 Accepted: 24 October 2022 Published: 18 November 2022
  • Metal corrosion is a significant and growing area of study in industrial problems, which has found productive research ground in the field of green chemistry. In the last 10 years, green chemistry has been highlighting the importance of safeguarding human as well as the environmental well-being, in an economically advantageous way aiming at keeping away from reducing waste hazardous toxins, and pollutants. The era of metal degradation, commonly faced due to the usage of hazardous chemicals became very relevant and useful in the research area of chemistry. Even though several experiments have been conducted and, several research articles were published on this topic of nature-friendly green and clean inhibitors still there are yet a lot of things to be explored in this field for sustainable eco-friendly existence of human and natural interconnected existence. The main aim of the study is to provide a summary and describe the past authentic research that accounted in the research literature to employ eco-friendly corrosion inhibitors, especially extraction from leaves, stems, seeds, and fruits of the plants for aluminum alloy in acid solutions in the past decade. Weight loss and electrochemical approaches are among the most often utilized methods to measure corrosion rate and to evaluate the effectiveness of green corrosion inhibitors. The relevance of the area prompted the further study, leading to a large number of substances being evaluated.

    Citation: Piyush S. Desai, Falguni P. Desai. An overview of sustainable green inhibitors for aluminum in acid media[J]. AIMS Environmental Science, 2023, 10(1): 33-62. doi: 10.3934/environsci.2023003

    Related Papers:

  • Metal corrosion is a significant and growing area of study in industrial problems, which has found productive research ground in the field of green chemistry. In the last 10 years, green chemistry has been highlighting the importance of safeguarding human as well as the environmental well-being, in an economically advantageous way aiming at keeping away from reducing waste hazardous toxins, and pollutants. The era of metal degradation, commonly faced due to the usage of hazardous chemicals became very relevant and useful in the research area of chemistry. Even though several experiments have been conducted and, several research articles were published on this topic of nature-friendly green and clean inhibitors still there are yet a lot of things to be explored in this field for sustainable eco-friendly existence of human and natural interconnected existence. The main aim of the study is to provide a summary and describe the past authentic research that accounted in the research literature to employ eco-friendly corrosion inhibitors, especially extraction from leaves, stems, seeds, and fruits of the plants for aluminum alloy in acid solutions in the past decade. Weight loss and electrochemical approaches are among the most often utilized methods to measure corrosion rate and to evaluate the effectiveness of green corrosion inhibitors. The relevance of the area prompted the further study, leading to a large number of substances being evaluated.



    加载中


    [1] Shaker RR (2015) The spatial distribution of development in Europe and its underlying sustainability correlations. App Geogr 63: 304–314. https://doi.org/10.1016/j.apgeog.2015.07.009 doi: 10.1016/j.apgeog.2015.07.009
    [2] Shehata OS, Korshed LA, Adel Attia (2018) Green corrosion inhibitors, past, present and future, In: Aliofkhazraei M (Ed.), Corrosion inhibitors, principles and recent applications, London: IntechOpen. https://doi.org/10.5772/intechopen.72753
    [3] Revie RW, Uhlig HH (2008) In: Corrosion and corrosion control: An introduction to corrosion science and engineering, 4 Eds., New Jersey: John Wiley & Sons.
    [4] Hurlen T, Liam H, Odegard OS, et al. (1984) Corrosion and passive behaviour of aluminium in weakly acid solution. Electrochem Acta 29: 579. https://doi.org/10.1016/0013-4686(84)87113-3 doi: 10.1016/0013-4686(84)87113-3
    [5] Rengamani S, Muralidharan S, Kulandainathan MA, et al. (2005) Inhibiting and accelerating effects of aminophenols on the corrosion and permeation of hydrogen through mild steel in acidic solutions. J Appl Electrochem 24: 355–360. https://doi.org/10.1007/BF00242066 doi: 10.1007/BF00242066
    [6] Shehata OS, Korshed LA, Attia A (2018) Green corrosion inhibitors, past, present, and future, In: Aliofkhazraei M (Ed.), Corrosion inhibitors principles and recent application, London: IntechOpen, 121–122. http://doi.org/10.5772/intechopen.72753
    [7] Desai PS, Kapopara SM (2009) Inhibiting effect of anisidines on corrosion of aluminium in hydrochloric acid. Indian J Chem Technol 16: 486–491.
    [8] Desai PS, Vashi RT (2009) Performance of phenylthiourea as corrosion inhibitor for aluminum in trichloroacetic acid. J Indian Chem Soc 86: 547–550.
    [9] Desai PS, Vashi RT (2010) Efficiency of xylenol orange as corrosion inhibitor for aluminium in trichloroacetic acid. Indian J Chem Technol 17: 50–55.
    [10] Bentiss F, Traisnel M, Chaibi N, et al. (2002) 2, 5-Bis(n-methoxyphenyl)-1, 3, 4-oxadiazoles used as corrosion inhibitors in acidic media: Correlation between inhibition efficiency and chemical structure. Corrs Sci 44: 2271–2789. https://doi.org/10.1016/S0010-938X(02)00037-9 doi: 10.1016/S0010-938X(02)00037-9
    [11] Li XM, Tang LB (2005) Synergistic inhibition between OP and NaCl on the corrosion of cold-rolled steel in phoshphoric acid. Mater Chem Phys 90: 286–297.
    [12] Desai PS, Kapopara SM (2014) Inhibitory action of xylenol orange on aluminum corrosion in hydrochloric acid solution. Indian J Chem Technol 21: 139–145
    [13] Desai PS, Vashi RT (2011) lnhibitive efficieney of sulphathiazole for aluminum corrosion in trichloroacetic acid. Anti-Corros Methods M 58: 70–75. https://doi.org/10.1108/00035591111110714 doi: 10.1108/00035591111110714
    [14] Aljourani J, Raeissi K, Golozar MA (2009) Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution. Corros Sci 51: 1836–1843. https://doi.org/10.1016/j.corsci.2009.05.011 doi: 10.1016/j.corsci.2009.05.011
    [15] Vermeirssen ELM, Dietschweiler C, Werner I, et al. (2017) Corrosion protection products as a source of bishphenol A and toxicity to the aquatic environment. Water Res 123: 586–593.
    [16] Raja PB, Ghoreishiamiri S, Ismail M (2015) Natural corrosion inhibitors for steel reinforcement in concrete—a review. Sufr Rev Lett 22: 1550040.
    [17] Bereket G, Yurt A (2001) The inhibition effect of amino acid and hydroxy carboxylic acid on pitting corrosion of aluminum alloy 7075. Corros Sci 43: 1179–1195. https://doi.org/10.1016/S0010-938X(00)00135-9 doi: 10.1016/S0010-938X(00)00135-9
    [18] Rani BEA, Basu BBJ (2012) Green inhibitors for corrosion protection of metals and alloys: An overview. Int J Corros 2012: 380217. https://doi.org/10.1155/2012/380217 doi: 10.1155/2012/380217
    [19] Radojcic I, Berkovic K, Kovac S, et al. (2008) Natural honey and black radish juice as tin corrosion inhibitors. Corros Sci 50: 1498–1504
    [20] Sanyal B (1981) Organic compound as corrosion inhibitors in different environment—A review. Prog Org Coat 9: 165–236. https://doi.org/10.1016/0033-0655(81)80009-X doi: 10.1016/0033-0655(81)80009-X
    [21] Lai X, Hu JF, Ruan T, et al. (2021) Chitosan derivative corrosion inhibitor for aluminum alloy in sodium chloride solution: A green organic/inorganic hybrid. Carbohyd Polym 265: 118074. https://doi.org/10.1016/j.carbpol.2021.118074 doi: 10.1016/j.carbpol.2021.118074
    [22] UmorenSA, AlAhmaryAA, Gasem ZM, et al. (2018) Evaluation of chitosan and carboxymethyl cellulose as ecofriendly corrosion inhibitors for steel. Int J Biol Macromol 117: 1017–1028. https://doi.org/10.1016/j.ijbiomac.2018.06.014 doi: 10.1016/j.ijbiomac.2018.06.014
    [23] Gupta NK, Joshi PG, Vandana Srivastava V, et al. (2018) Chitosan: A macromolecule as green corrosion inhibitor for mild steel in sulfamic acid useful for sugar industry. Int J Biol Macromol 106: 704–711. https://doi.org/10.1016/j.ijbiomac.2017.08.064. doi: 10.1016/j.ijbiomac.2017.08.064
    [24] Liu HL, Zhu ZM, Hu JF, et al. (2022) Inhibition of Q235 corrosion in sodium chloride solution by chitosan derivative and its synergistic effect with ZnO. Carbohyd Polym 296: 119936. https://doi.org/10.1016/j.carbpol.2022.119936 doi: 10.1016/j.carbpol.2022.119936
    [25] Marzorati S, Verotta L, Trasatti SP (2019) Green corrosion inhibitors from natural sources and biomass wastes. Molecules 24: 48. https://doi.org/10.3390/molecules24010048 doi: 10.3390/molecules24010048
    [26] Zou Y, Wang J, Zheng YY (2011) Electrochemical techniques for determining corrosion rate of rusted steel in seawater. Corros Sci 53: 208–216. https://doi.org/10.1016/j.corsci.2010.09.011 doi: 10.1016/j.corsci.2010.09.011
    [27] Law DW, Millard SG, Bungey JH (2000) Linear polarization resistance measurements using a potentiostatically controlled guard ring. NDT E Int 33: 15–21. https://doi.org/10.1016/S0963-8695(99)00015-8 doi: 10.1016/S0963-8695(99)00015-8
    [28] Andrade C, Alonso C (1996) Corrosion rate monitoring in the laboratory and on-site. Constr Build Mater 10: 315–328. https://doi.org/10.1016/0950-0618(95)00044-5 doi: 10.1016/0950-0618(95)00044-5
    [29] Sadowski L (2010) New non-destructive method for linear polarisation resistance corrosion rate measurement. Arch Civ Mech Eng 10: 109–116. https://doi.org/10.1016/S1644-9665(12)60053-3 doi: 10.1016/S1644-9665(12)60053-3
    [30] Orazem ME, Tribollet B (2008) In: Electrochemical impedance spectroscopy, New Jersey: John Wiley & Sons. https://doi.org/10.1002/9780470381588.scard
    [31] GAMRY (2018) EIS-Electrochemical Impedance Techniques. Available from: https://www.gamry.com/application-notes/EIS/potentiostatic-eis-tutorial/.
    [32] Yadav AP, Nishikata A, Tsuru T (2004) Electrochemical impedance study on galvanized steel corrosion under cyclic wet–dry conditions––influence of time of wetness. Corros Sci 46: 169–181. https://doi.org/10.1016/S0010-938X(03)00130-6 doi: 10.1016/S0010-938X(03)00130-6
    [33] Galal A, Atta NF, Al-Hassan MHS (2005) Effect of some thiophene derivatives on the electrochemical behavior of AISI 316 austenitic stainless steel in acidic solutions containing chloride ions: Ⅰ. Molecular structure and inhibition efficiency relationship. Mater Chem Phys 89: 38–48. https://doi.org/10.1016/j.matchemphys.2004.08.019 doi: 10.1016/j.matchemphys.2004.08.019
    [34] Quarishi MA, Rawat AJ (2002) Inhibition of mild steel corrosion by some macrocyclic compounds in hot and concentrated hydrochloric acid. Mater Chem Phys 73: 118–122. http://doi.org/10.1016/S0254-0584%2801%2900374-1 doi: 10.1016/S0254-0584%2801%2900374-1
    [35] Uma K, Rajapriya V, Rekha S (2016) The effect of inhibitor on the corrosion of aluminium in acidic solutions. SOJ Mater Sci Eng 4: 1–6. http://doi.org/10.15226/sojmse.2016.00140 doi: 10.15226/sojmse.2016.00140
    [36] Raghavendra N, Ishwara Bhat J (2016) Green approach to inhibition of corrosion of aluminum in 0.5 M HCl medium by tender arecanut seed extract: Insight from gravimetric and electrochemical studies. Res Chem Intermed 42: 6351–6372. https://doi.org/10.1007/s11164-016-2467-1 doi: 10.1007/s11164-016-2467-1
    [37] Raghavendra N, Bhat JI (2016) Natural products for material protection: An interesting and efficacious anticorrosive property of dry arecanut seed extract at electrode (aluminum)–electrolyte (hydrochloric acid) interface. J Bio Tribo Corros 2: 21. https://doi.org/10.1007/s40735-016-0051-2 doi: 10.1007/s40735-016-0051-2
    [38] Ladha DG, Wadhwani PM, Kumar S, et al. (2015) Evaluation of corrosion inhibitive properties of Trigonellafoenum-graecum for pure Aluminium in hydrochloric acid. J Mater Environ Sci 6: 1200–1209.
    [39] Al-Rudaini KAK, Ai-Saadie KAS (2021) Study the Corrosion behavior of AA7051 Aluminum alloy at different temperatures and inhibitor concentration in Acidic medium. Res J Pharm Technol 14: 4977–4982.
    [40] Prabhu D, Rao P (2013) Coriandrum sativum L.—A novel green inhibitor for the corrosion inhibition of aluminium in 1.0 M phosphoric acid solution. J Environ Chem Eng 1: 676–683. https://doi.org/10.1016/j.jece.2013.07.004 doi: 10.1016/j.jece.2013.07.004
    [41] Babatunde AI, Ogundele O, Oyelola OT, et al. (2012) The inhibitive effect of Irvingia gabonensis extract on the corrosion of aluminium in 1M HCl solution. Adv Appl Sci Res 3: 3944–3949.
    [42] Emran KM, Ahmed NM, Torjoman BA, et al. (2014) Cantaloupe extracts as eco friendly corrosion inhibitors for aluminum in acidic and alkaline solutions. J Mater Environ Sci 5: 1940–1950
    [43] Al-Haj-Ali AM, Jarrah NA, Mu'azu ND, et al. (2014) Thermodynamics and kinetics of inhibition of aluminum in hydrochloric acid by date palm leaf extract. J Appl Sci Environ Manage 18: 543–551.
    [44] Pushpanjali M, Rao SA, Padmalatha (2014) Carica papaya seeds-green inhibitor for corrosion control of aluminium in acid medium. J Appl Chem 2014: 310–323.
    [45] Ali AI (2014) Melia azedarach L as eco-friendly corrosion inhibitor for Aluminum in 2M HCl. J Mater Environ Sci 5: 793–802.
    [46] Al-Turkustani AM, Khadijah ME (2015) Evaluating the behavior of aluminum corrosion in hydrochloric acid in the presence aqueous extract of Olive seeds. IJIRSET 4: 1018–1027. https://doi.org/10.15680/ijirset.2015.0403042 doi: 10.15680/ijirset.2015.0403042
    [47] Pushpanjali, Rao SA, Rao P (2015) Eco friendly green inhibitor Tinosporacordifolia (Linn.) for the corrosion control of aluminum in sulfuric acid medium. IJIRSET 4: 325–333.
    [48] Desai PS (2017) Effect of temperature of Calotropis Gigantea leaves on aluminum corrosion in hydrochloric acid. IJARSE 6: 1055–1064.
    [49] Chahul HF, Ayuba AM, Nyior S (2015) Adsorptive, kinetic, thermodynamic and inhibitive properties of Cissus populnea stem extract on the corrosion of aluminum in acid medium. ChemSearch J 6: 20–30.
    [50] Vashi RT, Prajapati NI (2017) Corrosion inhibition of Aluminium in hydrochloric acid using Bacopa monnieri leaves extract as green inhibitor. Int J ChemTech Res 10: 221–231.
    [51] Prajapati NI, Vashi RT (2017) Ocimum sanctum (Tulsi) leaves extract as corrosion inhibitor for aluminium in hydrochloric acid medium. IJIRSET 6: 16376–16386.
    [52] Desai PS (2017) Thermodynamics of Azardirachta indica (Neem) leaves ark's as corrosion inhibitors for aluminum in HCl. Int J ChemTech Res 10: 131–138.
    [53] Vashi RT, Prajapati NI (2020) Cuminum cyminum (Jeeru) seeds extract as eco-friendly corrosion inhibitor for aluminium in HCl solution. IJRASET 8: 1708–1715.
    [54] Desai PS (2018) Calotropis gigantea leaves ark used as corrosion inhibitor for aluminum in hydrochloric acid. Der Pharma Chem 10: 7–12.
    [55] Al-Turkustani AM, Arab ST, Al-Dahiri RH (2010) Aloe plant extract as environmentally friendly inhibitor on the corrosion of aluminum in hydrochloric acid in absence and presence of iodide ions. Mod Appl Sci 4: 105–124. https://doi.org/10.5539/mas.v4n5p105 doi: 10.5539/mas.v4n5p105
    [56] James AO, Odey FA (2015) Inhibitive effect of bitter kola extract on aluminium corrosion in hydrochloric acid medium. IJSER 6: 996–1004.
    [57] Ayeni FA, Alawode S, Joseph D, et al. (2014) Investigation of Sida acuta (wire weed) plant extract as corrosion inhibitor for aluminium-copper-magnessium Alloy in acidic medium. J Miner Mater Charact Eng 2: 286–291. https://doi.org/10.4236/jmmce.2014.24033 doi: 10.4236/jmmce.2014.24033
    [58] Nithya A, Santhy P, Vijaya N, et al. (2015) Inhibition of corrosion of aluminium by an aqueous extract of beetroot (betanin). Int J Nano Corr Sci Engg 2: 1–11.
    [59] Raghavendra N, Ishwara Bhat J (2018) An environmentally friendly approach towards mitigation of al corrosion in hydrochloric acid by yellow colour ripe arecanut husk extract: Introducing potential and sustainable inhibitor for material protection. J Bio Tribo Corros 4: 2. https://doi.org/10.1007/s40735-017-0112-1 doi: 10.1007/s40735-017-0112-1
    [60] Obi-Egbedi NO, Obot IB, Umoren SA (2012) Spondias mombin L. as a green corrosion inhibitor for aluminium in sulphuric acid: Correlation between inhibitive effect and electronic properties of extracts major constituents using density functional theory. Arab J Chem 5: 361–373. http://doi.org/10.1016%2Fj.arabjc.2010.09.002
    [61] Pushpanjali, Rao SA, Rao P (2017) Corrosion inhibition and adsorption behavior of Murraya koenigii extract for corrosion control of aluminum in hydrochloric acid medium. Surf Engin Appl Electrochem 53: 475–485. https://doi.org/10.3103/S1068375517050088 doi: 10.3103/S1068375517050088
    [62] Nwosu FO, Owate IO, Osarolube E (2018) Acidic corrosion inhibition mechanism of aluminum alloy using green inhibitors. Am J Mater Sci 8: 45–50. https://doi.org/10.5923/j.materials.20180803.01 doi: 10.5923/j.materials.20180803.01
    [63] Nwosu OF, Osarolube E, Nnanna LA, et al. (2014) Acidic corrosion inhibition of Piper guineense seed extract on Al alloy. Am J Mater Sci 4: 178–183. https://doi.org/10.5923/j.materials.20140404.04 doi: 10.5923/j.materials.20140404.04
    [64] Kasuga B, Park E, Machunda RL (2018) Inhibition of aluminium corrosion using Carica papaya leaves extract in sulphuric acid. J Miner Mater Charact Eng 6: 1–14. https://doi.org/10.4236/jmmce.2018.61001 doi: 10.4236/jmmce.2018.61001
    [65] Chaubey N, Singh VK, Quraishi MA (2018) Papaya peel extract as potential corrosion inhibitor for Aluminium alloy in 1 M HCl: Electrochemical and quantum chemical study. Ain Shams Eng J 9: 1131–1140. https://doi.org/10.1016/j.asej.2016.04.010 doi: 10.1016/j.asej.2016.04.010
    [66] Mejeha IM, Nwandu MC, Okeoma KB, et al. (2012) Experimental and theoretical assessment of the inhibiting action of Aspilia africana extract on corrosion aluminium alloy AA3003 in hydrochloric acid. J Mater Sci 47: 2559–2572. https://doi.org/10.1007/s10853-011-6079-2 doi: 10.1007/s10853-011-6079-2
    [67] Zaidi Mat Satar M, Farhan Mohd Noor M, Wahid Samsudin M, et al. (2012) Orrosion inhibition of aluminum by using Nipah (Nypa fruticans) extract solutions in hydrochloric acid (HCl) media. Int J Electrochem Sci 7: 1958–1967.
    [68] Okeke PI, Maduka OG, Emeronye RU, et al. (2015) Corrosion inhibition efficacy of Cninodosculus chayamansa extracts on aluminum metal in acidic and alkaline media. Int J Sci Technol 3: 227–234.
    [69] Molina-Ocampo LB, Valladares-Cisneros MG, Gonzalez-Rodriguez JG (2015) Using Hibiscus sabdariffa as corrosin inhibitor for Al in 0.5 M H2SO4. Int J Electrochem Sci 10: 388–403.
    [70] Ajanaku KO, Aladesuyi O, Ajanaku CO, et al. (2015) Adsorption properties of Azadirachta indicia extract on corrosion of Aluminium in 1.85 M Hydrochloric acid. JIAATS 16: 4.
    [71] Wisdom J, Kelechi D, Ugochukwu J (2018) Green inhibitor for corrosion of Aluminium alloy AA8011A in acidic environment. IRJET 5: 121–124.
    [72] Omotosho OA, Ajayi OO (2012) Investigating the acid failure of aluminium alloy in 2 M hydrochloric acid using Vernonia amygdalina. ITB J Eng Sci 44: 77–92. https://doi.org/10.5614/itbj.eng.sci.2012.44.1.6 doi: 10.5614/itbj.eng.sci.2012.44.1.6
    [73] Loto CA, Joseph OO, Loto RT (2014) Adsorption and inhibitive properties of Camellia sinensis for aluminium alloy in HCl. Int J Electrochem Sci 9: 33637–3649.
    [74] Olawale O, Ogunsemi BT, Agboola OO, et al. (2018) Inhibition effect of orange seed extract on aluminium corrosion in 1M hydrochloric acid solution. IJMET 9: 282–287.
    [75] Vashi RT, Prajapati NI (2019) Corrosion inhibition of aluminium in hydrochloric acid solutions by Azadirachta indica (Neem) leaves extract as green inhibitor. IJGHC 8: 444–452. https://doi.org/10.24214/ijghc/gc/8/2/44452 doi: 10.24214/ijghc/gc/8/2/44452
    [76] Anbarasi CM, Divya G (2017) A green approach to corrosion inhibition of aluminum in acid medium using Azwain seed extract. Mater Today: Proc 4: 5190–5200. https://doi.org/10.1016/j.matpr.2017.05.026 doi: 10.1016/j.matpr.2017.05.026
    [77] Pushpanjali, Rao SA, Rao P (2016) Inhibition study of Andrographis paniculata plants extract for the corrosion control of Aluminum in hydrochloric acid medium. Int J ChemTech Res 9: 291–304.
    [78] Al-Turkustani AM, Al-Solmi MM (2011) Corrosion inhibition of aluminum in acidic solution by aqueous extract of Ajowan plant as green inhibitor. J Asian Sci Res 1: 346–358.
    [79] Al-Bataineh N, Al-Qudah MA, Abu-Orabi S, et al. (2022) Use of Capparis decidua extract as a green inhibitor for pure aluminum corrosion in acidc media. Corros Sci Technol 21: 9–20. https://doi.org/10.14773/cst.2022.21.1.9 doi: 10.14773/cst.2022.21.1.9
    [80] Deng SD, Li XH (2012) Inhibition by Jasminum Nudiflorum Lindl. leaves extract of the corrosion of aluminum in HCl solution. Corros Sci 64: 253–262. https://doi.org/10.1016/j.corsci.2012.07.017 doi: 10.1016/j.corsci.2012.07.017
    [81] Li XH, Deng SD (2012) Inhibition effect of Dendrocalamus brandisii leaves extract on aluminum in HCl, H3PO4 solutions. Corros Sci 65: 299–308. https://doi.org/10.1016/j.corsci.2012.08.033 doi: 10.1016/j.corsci.2012.08.033
    [82] Krishnaveni K, Ravichandran J (2014) Effect of aqueous extract of leaves of Morinda tinctoria on corrosion inhibition of aluminium surface in HCl medium. T Nonferr Metal Soc 24: 2704–2712. https://doi.org/10.1016/S1003-6326(14)63401-4 doi: 10.1016/S1003-6326(14)63401-4
    [83] Khadraoui A, Khelifa A, Hachama K, et al. (2016) Thymus algeriensis extract as a new eco-friendly corrosion inhibitor for 2024 aluminium alloy in 1 M HCl medium. J Mol Liq 214: 293–297. https://doi.org/10.1016/j.molliq.2015.12.064 doi: 10.1016/j.molliq.2015.12.064
    [84] Shah NK, Ladha DG, Wadhwani PM, et al. (2016) Corrosion inhibition performance of Coriander Seeds extract molecules for pure Aluminum in Hydrochloric acid Medium: A combined Experimental and Quantum chemical approach. Res J Recent Sci 5: 27–34.
    [85] Bashir S, Singh G, Kumar A (2017) Shatavari (Asparagus Racemosus) as green corrosion inhibitor of aluminium in acidic medium. J Mater Environ Sci 8: 4284–4291. http://doi.org/10.26872/jmes.2017.8.12.451 doi: 10.26872/jmes.2017.8.12.451
    [86] Ayuba AM, Abdullateef A (2021) Investigating the corrosion inhibition potentials of Strichnos spinosa L. extract on aluminium in 0.3 M hydrochloric acid solution. JASES 4: 336–348. https://doi.org/10.48393/IMIST.PRSM/jases-v4i1.24275 doi: 10.48393/IMIST.PRSM/jases-v4i1.24275
    [87] Petchiammal A, Selvaraj S (2013) Influence of Cassia alata leaves on aluminium in 1.0 N hydrochloric acid. CJST 1: 123–130.
    [88] Sharma A, Choudhary G, Sharma A, et al. (2013) Effect of temperature on inhibitory efficacy of Azadirachta indica fruit on acid corrosion of aluminium. IJIRSET 2: 7982–7992.
    [89] Fouda AEAS, Haleem EA (2020) Tussilago Farfara Extract (TFE) as green corrosion inhibitor for aluminum in hydrochloric acid solution. Biointerface Res App 10: 7023–7041. https://doi.org/10.33263/BRIAC106.70237041 doi: 10.33263/BRIAC106.70237041
    [90] Fouda AEAS, Rashwan SM, Kamel MM, et al. (2020) Juglans Regia Extract (JRE) as eco-friendly inhibitor for aluminum metal in hydrochloric acid medium. Biointerface Res App 10: 6398–6416. https://doi.org/10.33263/BRIAC105.63986416 doi: 10.33263/BRIAC105.63986416
    [91] Sharma S, Parihar PS, Nair RN, et al. (2012) Influence of ion-additives on inhibitory action of extract of Trigonella foenum graceums seeds for AA6063 in acid medium. RJC 5: 16–23.
    [92] Fouda AE-AS, Etaiw SH, Hammouda M (2017) Corrosion inhibition of aluminum in 1 M H2SO4 by Tecoma non-aqueous extract. J Bio Tribo Corros 3: 29. https://doi.org/10.1007/s40735-017-0090-3 doi: 10.1007/s40735-017-0090-3
    [93] El-Katori EE, Al-Mhyawi S (2019) Assessment of the Bassia muricata extract as a green corrosion inhibitor for aluminum in acidic solution. Green Chem Lett Rev 12: 31–48. https://doi.org/10.1080/17518253.2019.1569728. doi: 10.1080/17518253.2019.1569728
    [94] Onen AI, Barminas JT, Jacob J (2013) Inhibitory action of Ficus carica extracts on aluminium corrosion in acidic medium. Chem Sci Trans 2: 1326–1333. https://doi.org/10.7598/cst2013.558 doi: 10.7598/cst2013.558
    [95] Yadav S, Choudhary G, Sharma A (2013) Green Approach to Corrosion Inhibition of aluminium and copper by Ziziphus mauritiana fruit extract in hydrochloric acid solution. Int J ChemTech Res 5: 1815–1823.
    [96] BinYehmed FM, Abdullah AM, Zainal Z, et al. (2018) Green coffee bean extract as a green corrosion inhibitor for aluminium in artificial acid rain medium. Int J Appl Environ Sci 13: 171–183.
    [97] Orie KJ, Christian M (2015) The corrosion inhibition of aluminium metal in 0.5 M sulphuric acid using extract of breadfruit peels. IRJET 2: 1–9.
    [98] Garamon SE (2020) Ziziphus jujube as an eco-friendly organic inhibitor of aluminum corrosion in acidic medium. IJGHC 9: 9–15. https://doi.org/10.24214/ijghc/gc/9/1/00915 doi: 10.24214/ijghc/gc/9/1/00915
    [99] Ali AI, Foaud N (2012) Inhibition of aluminum corrosion in hydrochloric acid solution using black mulberry extract. J Mater Environ Sci 3: 917–924.
    [100] Alinnor IJ, Ukiwe LN (2012) Evaluation of inhibitory effect of different extracts of Vernonia amygdalina on corrosion of aluminium in hydrochloric acid. IJGHC 1: 120–132.
    [101] Alinnor IJ, Ejikeme PM (2012) Corrosion inhibition of aluminum in acidic medium by different extracts of Ocimum gratissimum. Chem Sci Int J 2: 122–135. https://doi.org/10.9734/ACSJ/2012/1835 doi: 10.9734/ACSJ/2012/1835
    [102] Dubey J, Jeengar N, Upadhyay R, et al. (2012) Corrosion inhibitive effects of Withania Somnifera (A medicinal plant) on aluminium in HCl solution. Res J Recent Sci 1: 73–78.
    [103] Kumpawat N, Chaturvedi A, Upadhyay RK (2012) Study on corrosion inhibition efficiency of stem alkaloid extract of different varieties of holy basil on aluminium in HCl solution. J Korean Chem Soc 56: 401–405. https://doi.org/10.5012/jkcs.2012.56.4.401. doi: 10.5012/jkcs.2012.56.4.401
    [104] Umoren SA, Eduok UM, Israel AU, et al. (2012) Coconut coir dust extract: A novel eco-friendly corrosion inhibitor for Al in HCl solutions. Green Chem Lett Rev 5: 303–313. https://doi.org/10.1080/17518253.2011.625980 doi: 10.1080/17518253.2011.625980
    [105] Ladha DG, Naik UJ, Shah NK (2013) Investigation of Cumin (Cuminum Cyminum) extract as an eco-friendly green corrosion inhibitor for pure Aluminium in acid medium. J Mater Environ Sci 4: 701–708. https://www.researchgate.net/publication/279515589
    [106] Petchiammal A, Selvaraj S (2013) Investigation of anti-corrosive effects of Lebbeck seed extract on aluminum in acid environment. Pac J Sci Technol 14: 31–39.
    [107] Adejo SO, Yiase SG, Ahile UJ, et al. (2013) Inhibitory effect and adsorption parameters of extract of leaves of Portulaca oleracea of corrosion of aluminium in H2SO4 solution. Arch Appl Sci Res 5: 25–32. https://www.researchgate.net/publication/274064097
    [108] Adejo SO, Gbertyo JA, Ahile JU (2013) Inhibitive properties and adsorption consideration of ethanol extract of Manihot esculentum leaves for corrosion inhibition of aluminium in 2 M H2SO4. Int J Mod Chem 4: 137–146.
    [109] Adejo SO, Gbertyo JA, Ahile JU, et al. (2013) Manihot esculentum root peels ethanol extract as corrosion inhibitor of aluminium in 2 M H2SO4. Int J Sci Eng Res 4: 2308–2313.
    [110] Shalabi K, Fouda AS, Elewady GY, et al. (2014) Adsorption and inhibitive properties of Phoenix dactylifera L. Extract as a green inhibitor for aluminum and aluminum-silicon alloy in HCl. Prot Met Phys Chem Surf 50: 420–431. https://doi.org/10.1134/S2070205114030174 doi: 10.1134/S2070205114030174
    [111] Al-Mhyawi SR (2014) Corrosion inhibition of aluminum in 0.5 M HCl by Garlic aqueous extract. Orient J Chem 30: 541–552. https://doi.org/10.13005/ojc/300218 doi: 10.13005/ojc/300218
    [112] Nair RN, Monika, Choudhary G, et al. (2014) Effect of elevation in temperature on inhibitory action of Murraya koenigii leaves on acid corrosion of AA6063. Int J Adv Sci Tech Res 4: 975–989.
    [113] Yiase SG, Adejo S, Ahile UJ, et al. (2014) Thermodynamic, kinetic and adsorptive parameters of corrosion inhibition of aluminium using Sorghum bicolor leaf extract in H2SO4. IJARCS 1: 38–46.
    [114] Dominic OO, Chikaodili AV, Sandra OC (2020) Optimum prediction for inhibition efficiency of Sapium ellipticum leaf extract as corrosion inhibitor of aluminum alloy (AA3003) in hydrochloric acid solution using electrochemical impedance spectroscopy and response surface methodology. Bull Chem Soc Ethiop 34: 175–191. https://doi.org/10.4314/BCSE.V34I1.17 doi: 10.4314/BCSE.V34I1.17
    [115] Abakedi OU, Asuquo JE (2016) Corrosion inhibition of aluminium in acidic medium by ethanol leaf extract of Azadirachta indica. JBAAR 2: 556–560.
    [116] Njoku DI, Ukaga I, Ikenna OB, et al. (2016) Natural products for materials protection: Corrosion protection of aluminium in hydrochloric acid by Kola nitida extract. J Mol Liq 219: 417–424. https://doi.org/10.1016/j.molliq.2016.03.049 doi: 10.1016/j.molliq.2016.03.049
    [117] Njoku DI, Onuoha GN, Oguzie EE, et al. (2019) Nicotiana tabacum leaf extract protects aluminium alloy AA3003 from acid attack. Arabian J Chem 12: 4466–4478. https://doi.org/10.1016/j.arabjc.2016.07.017 doi: 10.1016/j.arabjc.2016.07.017
    [118] Omotioma M, Onukwuli OD (2017) Evaluation of pawpaw leaves extract as anti-corrosion agent for aluminium in hydrochloric acid medium. NIJOTECH 36: 496–504. https://doi.org/10.4314/njt.v36i2.24 doi: 10.4314/njt.v36i2.24
    [119] Ejikeme PM, Umana SG, Alinnor IJ, et al. (2014) Corrosion inhibition and adsorption characteristics of Jatropha curcas leaves extract on aluminium in 1M HCl. Am J Mater Sci 4: 194–201.
    [120] Raghavendra NJ, Bhat Ishwara (2017). An experimental approach towards anticorrosive potential of Areca fat species at aluminum/test solution (HCl/NaOH) interface. Int J ChemTech Res 10: 1003–1013.
    [121] Djemoui A, Souli L, Djemoui D, et al. (2017) Alkaloids extract from Peganum harmala plant as corrosion inhibitor of 6063 aluminium alloy in 1 M hydrochloric acid medium. J Chem Pharm Res 9: 311–318.
    [122] Iloamaeke IM, Umeobika CU, Egwuatu CI, et al. (2017) Corrosion inhibition and adsorption behaviour of aluminium in 1M H2SO4 meduim using Persea americana (avocado pear) leaves extract. J Basic Phys Res 7: 47–57.
    [123] Nnabuka EO, Awe F (2018) Experimental and quantum chemical studies on ethanol extract of Phyllanthus amarus (EEPA) as a green corrosion inhibitor for aluminum in 1 M HCl. Port Electrochim Acta 36: 231–247. https://doi.org/10.4152/pea.201804231 doi: 10.4152/pea.201804231
    [124] Suleiman IY, Abdulwahab M, Sirajo MZ (2018) Anti-corrosion properties of ethanol extract of Acacia senegalensis stem on Al-Si-Fe/SiC composite in sulfuric acid medium. J Fail Anal Preven 18: 212–220. https://doi.org/10.1007/s11668-018-0399-3 doi: 10.1007/s11668-018-0399-3
    [125] Sharma S, Sharma YC (2019) Cordia dichotoma as corrosion inhibitor for aluminum alloy (AA6063) in hydrochloric acid. Port Electrochim Acta 37: 1–22. https://doi.org/10.4152/pea.201901001 doi: 10.4152/pea.201901001
    [126] Chung I-M, Malathy R, Kim S-H, et al. (2020) Ecofriendly green inhibitor from Hemerocallis fulva against aluminum corrosion in sulphuric acid medium. J Adhes Sci Technol 34: 1483–1506. https://doi.org/10.1080/01694243.2020.1712770 doi: 10.1080/01694243.2020.1712770
    [127] Meena O, Chaturvedi A, Meena C (2019) Corrosion inhibition effect of aerial parts of Euphorbia neriifolia linn on aluminium in nitric acid solution. IJGHC 8: 801–814. https://doi.org/10.24214/ijghc/gc/8/4/80114 doi: 10.24214/ijghc/gc/8/4/80114
    [128] Meena OP, Nainawat AK, Chaturvedi A (2019) Corrosion inhibition of aluminium by alkaloid extract of aerial part of Euphorbia neriifolia Linn in HCl solutions. Int J ChemTech Res 12: 234–242. https://doi.org/10.20902/ijctr.2019.120231 doi: 10.20902/ijctr.2019.120231
    [129] Prajapati NI, Vashi RT, Desai SA (2020) Fennel (Foeniculum vulgare Mill) seeds extract as green inhibitor for aluminium corrosion in HCl acid solution: Thermodynamic, adsorption and kinetic study. Eur J Biomed Pharm Sci 7: 421–428.
    [130] Thacker H, Ram V (2021) Phoenix Dactylifera L. extracts as green corrosion inhibitor for aluminum in acidic medium. J Sci Res 65: 142–149. https://doi.org/10.37398/jsr.2021.650317 doi: 10.37398/jsr.2021.650317
    [131] Meena AK, Meena AK, Sahay Bairwa B (2021) Inhibitory efficacy of Capparis decidua extract on the corrosion of aluminium in various acidic media. J Adv Sci Res 12: 254–261. https://doi.org/10.55218/ASR.s12021121sup206 doi: 10.55218/ASR.s12021121sup206
    [132] Ejikeme PM, Umana SG, Onukwuli OD (2013) Corrosion inhibition of aluminium by Treculia Africana leaves extract in acid medium. Port Electrochim Acta 30: 317–328. https://doi.org/10.4152/pea.201205317 doi: 10.4152/pea.201205317
    [133] Nathiya RS, Raj V (2017) Evaluation of Dryopteris cochleata leaf extracts as green inhibitor for corrosion of aluminium in 1 M H2SO4. Egypt J Pet 26: 313–323. https://doi.org/10.1016/j.ejpe.2016.05.002 doi: 10.1016/j.ejpe.2016.05.002
    [134] Madueke NA, Iroha NB (2018) Protecting aluminium alloy AA8011 from acid corrosion using extract from Allamanda cathartica leaves. IJIRSET 7: 10251–10258. https://doi.org/10.15680/IJIRSET.2018.0710014 doi: 10.15680/IJIRSET.2018.0710014
    [135] Madufor IC, Itodoh UE, Obidiegwu MU, et al. (2012) Inhibition of aluminium corrosion in acidic medium by Chrysophyllum albidum (African star apple) fruit extract. IOSRJEN 2: 16–23. http://doi.org/10.9790/3021-02951623 doi: 10.9790/3021-02951623
    [136] Ramírez-Arteaga M, Valladares MG, González Rodríguez JG (2013) Use of Prosopis laevigata as a corrosion inhibitor for Al in H2SO4. Int J Electrochem Sci 8: 6864–6877.
    [137] Petchiammal A, Selvaraj S (2013) The corrosion control of aluminium using Lawsonia inermis seed extract in acid medium. Int J ChemTech Res 5: 1566–1574.
    [138] Ayuba AM, Mustapha AA (2013) Inhibitive and synergistic properties of ethanolic extract of anogeissus leiocarpus leaves on the corrosion of aluminium in HCl solution. ChemSearch J 4: 55–65.
    [139] Njoku CN, Onyelucheya OE (2015) Response surface optimization of the inhibition efficiency of Gongronema latifolium as an inhibitor for aluminum corrosion in HCl solutions. Int J Mater Chem 5: 4–13. http://doi.org/10.5923/j.ijmc.20150501.02 doi: 10.5923/j.ijmc.20150501.02
    [140] Prabakaran M, Kim SH, Sasireka A, et al. (2018) Polygonatum odaratum extract as an eco-friendly inhibitor for aluminum corrosion in acidic medium. J Adhes Sci Technol 32: 2054–2069. https://doi.org/10.1080/01694243.2018.1462947 doi: 10.1080/01694243.2018.1462947
    [141] Abegunde SM, Ogede RO, Oluwagbenga Fatile B, et al. (2018) Talinum triangulare leaf and Musa sapientum peel extracts as corrosion inhibitors on ZA-27 alloy. J Part Sci Technol 4: 23–28. https://doi.org/10.22104/JPST.2018.2889.1123 doi: 10.22104/JPST.2018.2889.1123
    [142] Ciobotaru I-E, Benga F-M, Budei D (2020) The enhancement of the corrosion resistance of aluminium and VTES-coated aluminium by using a green inhibitor. UPB Sci Bull, Ser B 82: 179–186.
    [143] Manwani N, Upadhyay RK (2019) A comperative study of inhibition efficiency of extract of leaves and stem of Solanum xanthocarpum on aluminium in 2N HCl solution. IJERT 8: 472–475.
    [144] Méndez-Figueroa HG, Ossandón S, Fernández JAR, et al. (2022) Electrochemical evaluation of an Acanthocereus tetragonus aqueous extract on aluminum in NaCl (0.6 M) and HCl (1 M) and its modelling using forward and inverse artificial neural networks. J Electroanal Chem 918: 116444. https://doi.org/10.1016/j.jelechem.2022.116444 doi: 10.1016/j.jelechem.2022.116444
    [145] Skerget M, Kenz Z, Kenz-Hrncic M (2011) Solubility of solids in sub- and supercritical fluids: A review. J Chem Eng Data 56: 694–714. https://doi.org/10.1021/je1011373 doi: 10.1021/je1011373
    [146] Xhanari K, Finšgar M, Knez Hrnčič M, et al. (2017) Green corrosion inhibitors for aluminium and its alloys: A review. RSC Adv 7: 27299. https://doi.org/10.1039/c7ra03944a doi: 10.1039/c7ra03944a
    [147] Welton T (2015) Solvents and sustainable chemistry. Proc R Soc A 471: 20150502. http://doi.org/10.1098/rspa.2015.0502 doi: 10.1098/rspa.2015.0502
    [148] Maayta AK, Al-Rawashdeh NAF (2004) Inhibition of acidic corrosion of pure aluminum by some organic compounds. Corros Sci 46: 1129–1140. https://doi.org/10.1016/j.corsci.2003.09.009 doi: 10.1016/j.corsci.2003.09.009
    [149] Tsuru T, Haruyama S, Gijutsu B (1978) Corrosion inhibition of iron by amphoteric surfactants in 2M HCl. J Jpn Soc Corros Eng 27: 573–581.
    [150] Adejo SO, Ekwenchi MM, et al. (2014) Adsorption characteristics of ethanol root extract of Portulaca oleracea as eco-friendly inhibitor of corrosion of mild steel in H2SO4 medium. IOSR-JAC 7: 55–60. https://doi.org/10.9790/5736-07415560 doi: 10.9790/5736-07415560
    [151] Eddy NO, Ebenso EE (2008) Adsorption and inhibitive properties of ethanol extracts of Musa sapientum peels as a green corrosion inhibitor for mild steel in H2SO4. Afr J Pure Appl Chem 2: 46–54.
    [152] Obot IB, Obi-Egbedi NO, Umoren SA, et al. (2010) Synergistic and antagonistic effects of anions and Ipomoea invulcrata as green corrosion inhibitor for aluminium dissolution in acidic medium. Int J Electrochem Sci 5: 994–1007.
    [153] Ebenso EE (2003) Effect of halide ions on the corrosion inhibition of mild steel in H2SO4 using methyl red: Part 1. Bull Electrochem 19: 209–216.
    [154] Ating EI, Umoren SA, Udousoro II, et al. (2010) Leaves extract of Ananas sativum as green corrosion inhibitor for aluminium in hydrochloric acid solutions. Green Chem Lett Rev 3: 61–68. https://doi.org/10.1080/17518250903505253 doi: 10.1080/17518250903505253
    [155] Dehri I, Ozcan M (2006) The effect of temperature on the corrosion of mild steel in acidic media in the presence of some sulphur-containing organic compounds. Mater Chem Phys 98: 316–323. https://doi.org/10.1016/j.matchemphys.2005.09.020 doi: 10.1016/j.matchemphys.2005.09.020
    [156] Singh MR, Bhrara K, Singh G (2008) The inhibitory effect of diethanolamine on corrosion of mild steel in 0.5 M sulphuric acidic medium. Port Electrochim Acta 26: 479–492.
    [157] Agrawal D, Gupta KD, Saxena KK (2003) Thermodynamics and equilibrium study of the formation of binary and tertiary complexes of Co+2, Ni+2, Cu+2 and Zn+2 with (DL)-2, 5 Diamino -1-pentanoic acid as secondary ligand and 2', 2'-Biperidine (2', 2'-Bipy) as primary ligand. Trans SAEST 38: 111–114.
    [158] Issa RM, El-Sonbati AZ, El-Bindary AA, et al. (2008) Polymer complexes XXXIV. Potentiometric and thermodynamic studies of monomeric and polymeric complexes containing 2-acrylamidosulphadiazine. Eur Polym J 38: 561–566.
    [159] Khaled KF, Al-Qahtani MM (2009) The inhibitive effect of some tetrazole derivatives towards Al corrosion in acid solution: Chemical, electrochemical and theoretical studies. Mater Chem Phys 113: 150–158. https://doi.org/10.1016/j.matchemphys.2008.07.060 doi: 10.1016/j.matchemphys.2008.07.060
    [160] Amin MA, Mohsen Q, Hazzai OA (2009) Synergistic effect of I ions on the corrosion inhibition of Al in 1.0 M phosphoric acid solutions by purine. Mater Chem Phys 114: 908–914. https://doi.org/10.1016/j.matchemphys.2008.10.057 doi: 10.1016/j.matchemphys.2008.10.057
    [161] Noor EA (2009) Evaluation of inhibitive action of some quaternary N-heterocyclic compounds on the corrosion of Al–Cu alloy in hydrochloric acid. Mater Chem Phys 114: 533–541. https://doi.org/10.1016/j.matchemphys.2008.09.065 doi: 10.1016/j.matchemphys.2008.09.065
    [162] Valand T, Heusler KE (1983) Reactions at the oxide-electrolyte interface of anodic oxide films on aluminum. J Electroanal Chem Interfacial Electrochem 149: 71–82. https://doi.org/10.1016/S0022-0728(83)80559-2 doi: 10.1016/S0022-0728(83)80559-2
    [163] Singh AK, Quraishi MA (2010) Effect of Cefazolin on the corrosion of mild steel in HCl solution. Corros Sci 52: 152–60. https://doi.org/10.1016/j.corsci.2009.08.050 doi: 10.1016/j.corsci.2009.08.050
    [164] Abd El Rehim SS, Hassan HH, Amin MA (2001) Corrosion inhibition of aluminum by 1, 1(lauryl amido)propyl ammonium chloride in HCl solution. Mater Chem Phys 70: 64–72. https://doi.org/10.1016/S0254-0584(00)00468-5 doi: 10.1016/S0254-0584(00)00468-5
    [165] Amin MA, Khaled KF, Mohsen Q, et al. (2010) A study of the inhibition of iron corrosion in HCl solutions by some amino acids. Corros Sci 52: 1684–1695. https://doi.org/10.1016/j.corsci.2010.01.019 doi: 10.1016/j.corsci.2010.01.019
    [166] McCafferty E, Hackerman N (1972) Double-layer capacitance of iron and corrosion inhibition with polymethylene diamines. J Electrochem Soc 119: 146. https://doi.org/10.1149/1.2404150 doi: 10.1149/1.2404150
    [167] Umoren SA, Solomon MM (2015) Effect of halide ions on the corrosion inhibition efficiency of different organic species–A review. J Ind Eng Chem 21: 81–100. https://doi.org/10.1016/j.jiec.2014.09.033 doi: 10.1016/j.jiec.2014.09.033
    [168] Umoren SA, Obot IB, Ebenso EE (2008) Corrosion inhibition of aluminium using exudate gum from Pachylobus edulis in the presence of halide ions in HCl. J Chem 5: 138407. https://doi.org/10.1155/2008/138407 doi: 10.1155/2008/138407
    [169] Umoren SA, Ekanem UF (2010) Inhibition of mild steel corrosion in H2SO4 using exudate gum from Pachylobus edulis and synergistic potassium halide additives. Chem Eng Commun 197: 1339–1356. https://doi.org/10.1080/00986441003626086 doi: 10.1080/00986441003626086
  • Reader Comments
  • © 2023 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(2432) PDF downloads(250) Cited by(6)

Article outline

Figures and Tables

Figures(2)  /  Tables(1)

Other Articles By Authors

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog