Correlation between bioactivity and thermodynamic stability of glasses of the molar formula 20.15[(2.038 + x)SiO2-(1.457 - x)Na2O]-2.6P2O5-25.73CaO-1.22MgO

Amadou Kouyaté; Yapo Hermann Aristide Yapi; Aliou Pohan; Ange Privat Ahoussou; Albert Trokourey; Amadou Kouyaté; Yapo Hermann Aristide Yapi; Aliou Pohan; Ange Privat Ahoussou; Albert Trokourey

doi:10.3934/matersci.2020.3.323

AIMS Materials Science

2020, Volume 7, Issue 3: 323-337. doi: 10.3934/matersci.2020.3.323

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Research article

Correlation between bioactivity and thermodynamic stability of glasses of the molar formula 20.15[(2.038 + x)SiO₂-(1.457 - x)Na₂O]-2.6P₂O₅-25.73CaO-1.22MgO

1.
UFR Environnement, Université Jean Lorougnon Guédé, BP 150 Daloa, Côte d’Ivoire
2.
UFR Sciences biologiques, Université Péléforo Gon Coulibaly, BP 1328 Korhogo, Côte d’Ivoire
3.
Laboratoire de Chimie-Physique, UFR-SSMT, Université Félix Houphouët Boigny, 22 BP 582 Abidjan 22, Côte d’Ivoire

Received: 06 March 2020 Accepted: 08 June 2020 Published: 16 June 2020

The purpose of this study is to establish the influence of composition on the glass transition temperature, density, enthalpy of dissolution in an acid bath and bioactivity in glasses of the molar formula 20.15[(2.038 + x)SiO₂-(1.457 − x)Na₂O]-2.6P₂O₅-25.73CaO-1.22MgO. It is also a question of correlating bioactivity and stability in this oxide glass system. Nine samples were prepared by high temperature melting followed by quenching. These samples were characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC), dissolution calorimetry and pycnometry. Their bioactivity was estimated using the Anderson model. The results indicate that the effect of magnesium composition can lead to a decrease in the glass transition temperature (Tg). These results also show that a decrease in glass stability leads to a decrease in bioactivity.
- bioactive glasses,
- phosphosilicate,
- calorimetry,
- free enthalpy of formation,
- bioactivity
Citation: Amadou Kouyaté, Yapo Hermann Aristide Yapi, Aliou Pohan, Ange Privat Ahoussou, Albert Trokourey. Correlation between bioactivity and thermodynamic stability of glasses of the molar formula 20.15[(2.038 + x)SiO2-(1.457 - x)Na2O]-2.6P2O5-25.73CaO-1.22MgO[J]. AIMS Materials Science, 2020, 7(3): 323-337. doi: 10.3934/matersci.2020.3.323

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Abstract

The purpose of this study is to establish the influence of composition on the glass transition temperature, density, enthalpy of dissolution in an acid bath and bioactivity in glasses of the molar formula 20.15[(2.038 + x)SiO₂-(1.457 − x)Na₂O]-2.6P₂O₅-25.73CaO-1.22MgO. It is also a question of correlating bioactivity and stability in this oxide glass system. Nine samples were prepared by high temperature melting followed by quenching. These samples were characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC), dissolution calorimetry and pycnometry. Their bioactivity was estimated using the Anderson model. The results indicate that the effect of magnesium composition can lead to a decrease in the glass transition temperature (Tg). These results also show that a decrease in glass stability leads to a decrease in bioactivity.

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