A versatile approach towards development of easy-to-clean transparent nanocoating systems with pronounced anti-static properties for various substrates

Nikolaos D. Papadopoulos; Pinelopi P. Falara; Polyxeni Vourna; Nikolaos D. Papadopoulos; Pinelopi P. Falara; Polyxeni Vourna

doi:10.3934/matersci.2023008

AIMS Materials Science

2023, Volume 10, Issue 1: 139-163. doi: 10.3934/matersci.2023008

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Research article

A versatile approach towards development of easy-to-clean transparent nanocoating systems with pronounced anti-static properties for various substrates

1.
BFP Advanced Technologies, 11633, Athens, Attiki, Greece
2.
School of Chemical Engineering, National Technical University of Athens, 9 Ir. Polytech. St., Zografou, 15780, Greece

Received: 30 September 2022 Revised: 25 December 2022 Accepted: 03 January 2023 Published: 18 January 2023

Sol-gel is a widely applied method for the development of hydrophobic anti-soiling coatings. Most of them however suffer from serious drawbacks which restrict their generic applicability, especially on surfaces with limited number of hydroxyl groups. This study aims to propose a facile and straightforward strategy for the development of an "one-fits-all" anti-soiling coating with strong adhesion to a variety of hard, non-absorbent surfaces. The structure of the proposed composition is based on a two-component coating system consisting of an organopolysilazane primer and an alkoxysilane topcoat, based on a quaternarized ammonium silane. Morphology and microstructure were systematically studied, while hydrophobicity, adhesion, stability, abrasion and chemical resistance were determined on aluminum and PC substrates. The anti-soiling behavior of the proposed coating system was also evaluated. It was found that the polysilazane primer provided mechanical and chemical robustness regardless of substrate type, while the quaternarized silane offered pronounced easy-to-clean and anti-static attributes. The combination of such attributes within a single sol-gel coating system is highly beneficial for numerous applications.
- sol-gel,
- anti-soiling coatings,
- easy-to-clean,
- anti-static,
- organopolysilazane,
- quaternary ammonium silane
Citation: Nikolaos D. Papadopoulos, Pinelopi P. Falara, Polyxeni Vourna. A versatile approach towards development of easy-to-clean transparent nanocoating systems with pronounced anti-static properties for various substrates[J]. AIMS Materials Science, 2023, 10(1): 139-163. doi: 10.3934/matersci.2023008

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Abstract

Sol-gel is a widely applied method for the development of hydrophobic anti-soiling coatings. Most of them however suffer from serious drawbacks which restrict their generic applicability, especially on surfaces with limited number of hydroxyl groups. This study aims to propose a facile and straightforward strategy for the development of an "one-fits-all" anti-soiling coating with strong adhesion to a variety of hard, non-absorbent surfaces. The structure of the proposed composition is based on a two-component coating system consisting of an organopolysilazane primer and an alkoxysilane topcoat, based on a quaternarized ammonium silane. Morphology and microstructure were systematically studied, while hydrophobicity, adhesion, stability, abrasion and chemical resistance were determined on aluminum and PC substrates. The anti-soiling behavior of the proposed coating system was also evaluated. It was found that the polysilazane primer provided mechanical and chemical robustness regardless of substrate type, while the quaternarized silane offered pronounced easy-to-clean and anti-static attributes. The combination of such attributes within a single sol-gel coating system is highly beneficial for numerous applications.

References

[1]	Chundi N, Kesavan G, Ramasamy E, et al. (2021) Ambient condition curable, highly weather stable anti-soiling coating for photovoltaic application. Sol Energy Mater Sol Cells 230: 111203. https://doi.org/10.1016/j.solmat.2021.111203 doi: 10.1016/j.solmat.2021.111203
[2]	Ganesh VA, Raut HK, Nair AS, et al. (2011) A review on self-cleaning coatings. J Mater Chem 21: 16304. https://doi.org/10.1039/c1jm12523k doi: 10.1039/c1jm12523k
[3]	Kim D, Kim JG, Kim T, et al. (2021) Long-lasting superhydrophilic and instant hydrophobic micropatterned stainless steel surface by thermally-induced surface layers. Int J Precis Eng Manuf-Green Technol 8: 435–444. https://doi.org/10.1007/s40684-020-00207-5 doi: 10.1007/s40684-020-00207-5
[4]	Zhang H, Liu H, Chen T, et al. (2021) Fabrication of a fast curing super-hydrophobic FEVE/MMA coating and its property research. Mater Sci Eng B 263: 114746. https://doi.org/10.1016/j.mseb.2020.114746 doi: 10.1016/j.mseb.2020.114746
[5]	Zhou Y, Liu C, Gao J, et al. (2019) A novel hydrophobic coating film of water-borne fluoro-silicon polyacrylate polyurethane with properties governed by surface self-segregation. Prog Org Coat 134: 134–144. https://doi.org/10.1016/j.porgcoat.2019.04.078 doi: 10.1016/j.porgcoat.2019.04.078
[6]	Gao M, Wu X, Gao P, et al. (2019) Properties of hydrophobic carbon-PTFE composite coating with high corrosion resistance by facile preparation on pure Ti. Trans Nonferrous Met Soc China 29: 2321–2330. https://doi.org/10.1016/S1003-6326(19)65138-1 doi: 10.1016/S1003-6326(19)65138-1
[7]	Xue Y, Wang S, Xue Y, et al. (2020) Robust self‐cleaning and marine anticorrosion super‐hydrophobic Co-Ni/CeO₂ composite coatings. Adv Eng Mater 22: 2000402. https://doi.org/10.1002/adem.202000402 doi: 10.1002/adem.202000402
[8]	Zhang X, Liang J, Liu B, et al. (2014) Preparation of superhydrophobic zinc coating for corrosion protection. Colloids Surf Physicochem Eng Asp 454: 113–118. https://doi.org/10.1016/j.colsurfa.2014.04.029 doi: 10.1016/j.colsurfa.2014.04.029
[9]	Bi, Li, Zhao, et al. (2019) Robust super-hydrophobic coating prepared by electrochemical surface engineering for corrosion protection. Coatings 9: 452. https://doi.org/10.3390/coatings9070452 doi: 10.3390/coatings9070452
[10]	Bai M, Kazi H, Zhang X, et al. (2018) Robust hydrophobic surfaces from suspension HVOF thermal sprayed rare-earth oxide ceramics Coatings. Sci Rep 8: 6973. https://doi.org/10.1038/s41598-018-25375-y doi: 10.1038/s41598-018-25375-y
[11]	Zhang C, Wu Y, Liu L (2012) Robust hydrophobic Fe-based amorphous coating by thermal spraying. Appl Phys Lett 101: 121603. https://doi.org/10.1063/1.4754140 doi: 10.1063/1.4754140
[12]	Rodič P, Kapun B, Panjan M, et al. (2020) Easy and fast fabrication of self-cleaning and anti-icing perfluoroalkyl silane film on aluminium. Coatings 10: 234. https://doi.org/10.3390/coatings10030234 doi: 10.3390/coatings10030234
[13]	Khodaei M, Shadmani S (2019) Superhydrophobicity on aluminum through reactive-etching and TEOS/GPTMS/nano-Al2O3 silane-based nanocomposite coating. Surf Coat Technol 374: 1078–1090. https://doi.org/10.1016/j.surfcoat.2019.06.074 doi: 10.1016/j.surfcoat.2019.06.074
[14]	Liang Z, Zhou Z, Zhao L, et al. (2020) Fabrication of transparent, durable and self-cleaning superhydrophobic coatings for solar cells. New J Chem 44: 14481–14489. https://doi.org/10.1039/D0NJ01402H doi: 10.1039/D0NJ01402H
[15]	Shang Q, Zhou Y, Xiao G (2014) A simple method for the fabrication of silica-based superhydrophobic surfaces. J Coat Technol Res 11: 509–515. https://doi.org/10.1007/s11998-014-9573-z doi: 10.1007/s11998-014-9573-z
[16]	Das S, Kumar S, Samal SK, et al. (2018) A review on superhydrophobic polymer nanocoatings: recent development and applications. Ind Eng Chem Res 57: 2727-2745. https://doi.org/10.1021/acs.iecr.7b04887 doi: 10.1021/acs.iecr.7b04887
[17]	Bouvet-Marchand A, Graillot A, Abel M, et al. (2018) Distribution of fluoroalkylsilanes in hydrophobic hybrid sol-gel coatings obtained by co-condensation. J Mater Chem A 6: 24899–24910. https://doi.org/10.1039/C8TA10191D doi: 10.1039/C8TA10191D
[18]	Vidal K, Gómez E, Goitandia AM, et al. (2019) The synthesis of a superhydrophobic and thermal stable silica coating via sol-gel process. Coatings 9: 627. https://doi.org/10.3390/coatings9100627 doi: 10.3390/coatings9100627
[19]	Power AC, Barrett A, Abubakar J, et al. (2016) Versatile self-cleaning coating production through sol-gel chemistry: Versatile self-cleaning coating production. Adv Eng Mater 18: 76–82. https://doi.org/10.1002/adem.201500112 doi: 10.1002/adem.201500112
[20]	Purcar V, Rădițoiu V, Rădițoiu A, et al. (2020) Preparation and characterization of some sol-gel modified silica coatings deposited on polyvinyl chloride (PVC) substrates. Coatings 11: 11. https://doi.org/10.3390/coatings11010011 doi: 10.3390/coatings11010011
[21]	Özmen E, Durán A, Castro Y (2018) Hydrophobic and oleophobic sol-gel coatings on glass substrates for usage at high temperatures. Int J Appl Glass Sci 9: 413–420. https://doi.org/10.1111/ijag.12350 doi: 10.1111/ijag.12350
[22]	Yang Y-Q, Liu L, Hu J-M, et al. (2012) Improved barrier performance of metal alkoxide-modified methyltrimethoxysilane films. Thin Solid Films 520: 2052–2059. https://doi.org/10.1016/j.tsf.2011.10.041 doi: 10.1016/j.tsf.2011.10.041
[23]	Liu S, Liu X, Latthe SS, et al. (2015) Self-cleaning transparent superhydrophobic coatings through simple sol-gel processing of fluoroalkylsilane. Appl Surf Sci 351: 897–903. https://doi.org/10.1016/j.apsusc.2015.06.016 doi: 10.1016/j.apsusc.2015.06.016
[24]	Pratiwi N, Zulhadjri, Arief S, et al. (2020) Self-cleaning material based on superhydrophobic coatings through an environmentally friendly sol-gel method. J Sol-Gel Sci Technol 96: 669-678. https://doi.org/10.1007/s10971-020-05389-7 doi: 10.1007/s10971-020-05389-7
[25]	Akustia Widati A, Nuryono N, Kartini I, et al. (2019) Water-repellent glass coated with SiO₂-TiO₂-metyhltrimethoxysilane through sol-gel coating. AIMS Mater Sci 6: 10–24. https://doi.org/10.3934/matersci.2019.1.10 doi: 10.3934/matersci.2019.1.10
[26]	Ghiotti A, Bertolini R, Pezzato L, et al. (2021) Surface texturing to enhance sol-gel coating performances for biomedical applications. CIRP Ann 70: 459–462. https://doi.org/10.1016/j.cirp.2021.04.040 doi: 10.1016/j.cirp.2021.04.040
[27]	Bertolini R, Bruschi S, Ghiotti A, et al. (2019) Ultrasonic vibration turning to increase the deposition efficiency of a silica-based sol-gel coating. Procedia Manuf 34: 101–109. https://doi.org/10.1016/j.promfg.2019.06.126 doi: 10.1016/j.promfg.2019.06.126
[28]	Syafiq A, Vengadaesvaran B, Rahim NAbd, et al. (2019) Transparent self-cleaning coating of modified polydimethylsiloxane (PDMS) for real outdoor application. Prog Org Coat 131: 232–239. https://doi.org/10.1016/j.porgcoat.2019.02.020 doi: 10.1016/j.porgcoat.2019.02.020
[29]	Chen Z, Li G, Wang L, et al. (2018) A strategy for constructing superhydrophobic multilayer coatings with self-cleaning properties and mechanical durability based on the anchoring effect of organopolysilazane. Mater Des 141: 37–47. https://doi.org/10.1016/j.matdes.2017.12.034 doi: 10.1016/j.matdes.2017.12.034
[30]	Sutar RS, Gaikwad SS, Latthe SS, et al. (2020) Superhydrophobic nanocomposite coatings of hydrophobic silica NPs and poly(methyl methacrylate) with notable self‐cleaning ability. Macromol Symp 393: 2000116. https://doi.org/10.1002/masy.202000116 doi: 10.1002/masy.202000116
[31]	Suriano R, Ciapponi R, Griffini G, et al. (2017) Fluorinated zirconia-based sol-gel hybrid coatings on polycarbonate with high durability and improved scratch resistance. Surf Coat Technol 311: 80–89. https://doi.org/10.1016/j.surfcoat.2016.12.095 doi: 10.1016/j.surfcoat.2016.12.095
[32]	Zhang LB, Zhang HX, Liu ZJ, et al. (2023) Nano-silica anti-icing coatings for protecting wind-power turbine fan blades. J Colloid Interface Sci 630: 1–10. https://doi.org/10.1016/j.jcis.2022.09.154 doi: 10.1016/j.jcis.2022.09.154
[33]	Zhan Y, Grottenmüller R, Li W, et al. (2021) Evaluation of mechanical properties and hydrophobicity of room-temperature, moisture-curable polysilazane coatings. J Appl Polym Sci 138: 50469. https://doi.org/10.1002/app.50469 doi: 10.1002/app.50469
[34]	Rossi S, Deflorian F, Fedel M (2019) Polysilazane-based coatings: corrosion protection and anti-graffiti properties. Surf Eng 35: 343–350. https://doi.org/10.1080/02670844.2018.1465748 doi: 10.1080/02670844.2018.1465748
[35]	Arkles B, Silane coupling agents: Connecting across boundaries, Gelest, Inc., 2014. Available from: https://www.gelest.com/wp-content/uploads/Silane_Coupling_Agents.pdf.
[36]	Ogoshi T, Chujo Y (2005) Organic-inorganic polymer hybrids prepared by the sol-gel method. Compos Interfaces 11: 539–566. https://doi.org/10.1163/1568554053148735 doi: 10.1163/1568554053148735
[37]	Gong X, He S (2020) Highly durable superhydrophobic polydimethylsiloxane/silica nanocomposite surfaces with good self-cleaning ability. ACS Omega 5: 4100–4108. https://doi.org/10.1021/acsomega.9b03775 doi: 10.1021/acsomega.9b03775
[38]	Chen Z, Liu X, Wang Y, et al. (2015) Highly transparent, stable, and superhydrophobic coatings based on gradient structure design and fast regeneration from physical damage. Appl Surf Sci 359: 826–833. https://doi.org/10.1016/j.apsusc.2015.10.150 doi: 10.1016/j.apsusc.2015.10.150
[39]	Wu X, Chen Z (2018) A mechanically robust transparent coating for anti-icing and self-cleaning applications. J Mater Chem A 6: 16043–16052. https://doi.org/10.1039/C8TA05692G doi: 10.1039/C8TA05692G
[40]	Lee JW, Heo JH, Lee B, et al. (2019) Enhancement in the adhesion properties of polycarbonate surfaces through chemical functionalization with organosilicon coupling agents. J Mater Sci Mater Electron 30: 17773–17779. https://doi.org/10.1007/s10854-019-02128-9 doi: 10.1007/s10854-019-02128-9

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