Investigation of cementitious composites reinforced with metallic nanomaterials, boric acid, and lime for infrastructure enhancement

Ahmed Al-Ramthan; Ruaa Al Mezrakchi; Ahmed Al-Ramthan; Ruaa Al Mezrakchi

doi:10.3934/matersci.2024025

AIMS Materials Science

2024, Volume 11, Issue 3: 495-514. doi: 10.3934/matersci.2024025

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Research article

Investigation of cementitious composites reinforced with metallic nanomaterials, boric acid, and lime for infrastructure enhancement

Ahmed Al-Ramthan ¹,
Ruaa Al Mezrakchi ^{2
,
,}

1.
Construction Management, School of Human Sciences, Stephen F. Austin State University, 1936 North St, Nacogdoches, TX 75965, USA
2.
Department of Engineering, College of Science and Engineering, University of Houston-Clear Lake, 2700 Bay Area Boulevard, Houston, TX 77058, USA

Received: 17 March 2024 Revised: 17 April 2024 Accepted: 13 May 2024 Published: 16 May 2024

Nanomaterials integration within construction materials could promote the generation of more sophisticated structural materials, as it imbues reinforcement at the nanoscale. This research adopted experimental approaches to assess the influence of metallic nanomaterials on the performance of cementitious composites with various ratios of boric acid (1%, 3%, and 5% by sand's weight) and lime (0.5%, 1.5%, and 2.5% by sand's weight), respectively, for use in construction infrastructure facilities. This research provides valuable insight into the potential of using boric acid and lime as well as metallic nanomaterials to strengthen cement-based composites. Initial curing stages revealed a notable decrease in compressive strength attributed to the inhibitory effects of boric acid and lime on cement hydration. However, the introduction of TiO₂ nanoparticles demonstrated significant enhancements in compressive strength and durability. Statistical analysis emphasized the significance of nanomaterials in augmenting compressive strength, with implications for long-term performance. This study has shown that the addition of nano-titanium dioxide TiO₂ can significantly enhance the compressive strength of Portland cement mortars, particularly when used in conjunction with appropriate ratios of boric acid and lime. The results of the 7 days test indicated that the inclusion of boric acid and lime in the cement mortars significantly decreased the compressive strength. However, the addition of nano-TiO₂ to cement mortars containing 1% boric acid and 0.5% lime resulted in a 31-fold increase in compressive strength compared to cementitious composites without nano-TiO₂. In contrast, the compressive strength significantly increased by 1.2 times, 85.3 times, and 65.1 times, respectively, after 56 days for the addition of boric acid (1%, 3%, and 5%) with lime (0.5%, 1.5%, and 2.5%), respectively, in the presence of nano-TiO₂, compared to the 7 days strength. The results also illustrated that, in general, the incorporation of various types of nano-TiO₂ into cementitious composites containing boric acid and lime increases their compressive strength as the ratios of boric acid and lime increase, as long as sufficient curing time is allowed.
- cementitious composites,
- nanomaterials,
- metallic nanomaterials,
- nano-TiO₂,
- boric acid,
- lime,
- compressive strength,
- cement mortar,
- experimental study,
- infrastructure
Citation: Ahmed Al-Ramthan, Ruaa Al Mezrakchi. Investigation of cementitious composites reinforced with metallic nanomaterials, boric acid, and lime for infrastructure enhancement[J]. AIMS Materials Science, 2024, 11(3): 495-514. doi: 10.3934/matersci.2024025

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Abstract

Nanomaterials integration within construction materials could promote the generation of more sophisticated structural materials, as it imbues reinforcement at the nanoscale. This research adopted experimental approaches to assess the influence of metallic nanomaterials on the performance of cementitious composites with various ratios of boric acid (1%, 3%, and 5% by sand's weight) and lime (0.5%, 1.5%, and 2.5% by sand's weight), respectively, for use in construction infrastructure facilities. This research provides valuable insight into the potential of using boric acid and lime as well as metallic nanomaterials to strengthen cement-based composites. Initial curing stages revealed a notable decrease in compressive strength attributed to the inhibitory effects of boric acid and lime on cement hydration. However, the introduction of TiO₂ nanoparticles demonstrated significant enhancements in compressive strength and durability. Statistical analysis emphasized the significance of nanomaterials in augmenting compressive strength, with implications for long-term performance. This study has shown that the addition of nano-titanium dioxide TiO₂ can significantly enhance the compressive strength of Portland cement mortars, particularly when used in conjunction with appropriate ratios of boric acid and lime. The results of the 7 days test indicated that the inclusion of boric acid and lime in the cement mortars significantly decreased the compressive strength. However, the addition of nano-TiO₂ to cement mortars containing 1% boric acid and 0.5% lime resulted in a 31-fold increase in compressive strength compared to cementitious composites without nano-TiO₂. In contrast, the compressive strength significantly increased by 1.2 times, 85.3 times, and 65.1 times, respectively, after 56 days for the addition of boric acid (1%, 3%, and 5%) with lime (0.5%, 1.5%, and 2.5%), respectively, in the presence of nano-TiO₂, compared to the 7 days strength. The results also illustrated that, in general, the incorporation of various types of nano-TiO₂ into cementitious composites containing boric acid and lime increases their compressive strength as the ratios of boric acid and lime increase, as long as sufficient curing time is allowed.

References

[1]	Pacheco-Torgal F, Diamanti MV, Nazari A, et al. (2019) Nanotechnology in Eco-Efficient Construction: Materials, Processes and Applications, 2 Eds., Amsterdam: Woodhead Publishing. https://doi.org/10.1016/B978-0-08-102641-0.01001-X
[2]	Bartos P, Hughes J, Trtik P, et al. (2004) Nanotechnology in Construction, London: Royal Society of Chemistry. https://doi.org/10.1039/9781847551528
[3]	Al-Mezrakchi R, Al-Ramthan A, Alam S (2020) Designing and modeling new generation of advanced hybrid composite sandwich structure armors for ballistic threats in defense applications. AIMS Mater Sci 7: 608–631. https://doi.org/10.3934/matersci.2020.5.608 doi: 10.3934/matersci.2020.5.608
[4]	Al-Mezrakchi R (2018) An investigation into scalability production of ultra-fine nanofiber using electrospinning systems. Fibers Polym 19: 105–115. https://doi.org/10.1007/s12221-018-7506-z doi: 10.1007/s12221-018-7506-z
[5]	Lee B, Woo BH, Ryou JS (2021) Basic mechanical and neutron shielding performance of mortar mixed with boron compounds with various alkalinity. Sustainability 13: 6252. https://doi.org/10.3390/su13116252 doi: 10.3390/su13116252
[6]	Qadir W, Ghafor K, Mohammed A (2019) Evaluation the effect of lime on the plastic and hardened properties of cement mortar and quantified using Vipulanandan model. Open Eng 9: 468–480. https://doi.org/10.1515/eng-2019-0055 doi: 10.1515/eng-2019-0055
[7]	Golewski GL (2023) Mechanical properties and brittleness of concrete made by combined fly ash, silica fume and nanosilica with ordinary Portland cement. AIMS Mater Sci 10: 390–404. https://doi.org/10.3934/matersci.2023021 doi: 10.3934/matersci.2023021
[8]	Al-Ramthan A (2019) Behavior of walls and piles in cohesive soils under cyclic loads. Texas A & M University. Available from: https://hdl.handle.net/1969.1/185013.
[9]	Akkaya Y, Shah S, Ghandehari M (2003) Influence of fiber dispersion on the performance of microfiber reinforced cement composites. ACI 216: 1–18. https://doi.org/10.14359/12888 doi: 10.14359/12888
[10]	Yang H, Cui H, Tang W, et al. (2017) A critical review on research progress of graphene/cement based composites. Compos Part A Appl Sci Manuf 102: 273–296. https://doi.org/10.1016/j.compositesa.2017.07.019 doi: 10.1016/j.compositesa.2017.07.019
[11]	Jóźwiak-Niedźwiedzka D, Lessing PA (2019) High-density and radiation shielding concrete, In: Mindess S, Developments in the Formulation and Reinforcement of Concrete, 2Eds., Amsterdam: Elsevier, 193–228. https://doi.org/10.1016/B978-0-08-102616-8.00009-5
[12]	Vera-Agullo J, Chozas-Ligero V, Portillo-Rico D, et al. (2009) Mortar and concrete reinforced with nanomaterials. Nanotechnology in Construction 3, Springer, Berlin, Heidelberg, 383–388. https://doi.org/10.1007/978-3-642-00980-8_52
[13]	Zhao Z, Qi T, Zhou W, et al. (2020) A review on the properties, reinforcing effects, and commercialization of nanomaterials for cement-based materials. Nanotechnol Rev 9: 303–322. https://doi.org/10.1515/ntrev-2020-0023 doi: 10.1515/ntrev-2020-0023
[14]	Konsta-Gdoutos MS, Metaxa ZS, Shah SP (2010) Highly dispersed carbon nanotube reinforced cement based materials. Cement Concrete Res 40: 1052–1059. https://doi.org/10.1016/j.cemconres.2010.02.015 doi: 10.1016/j.cemconres.2010.02.015
[15]	Chu SH, Yang EH, Unluer C (2023) Development of nanofiber reinforced reactive magnesia-based composites for 3D printing. Constr Build Mater 366: 130270. https://doi.org/https://doi.org/10.1016/j.conbuildmat.2022.130270 doi: 10.1016/j.conbuildmat.2022.130270
[16]	Chu SH, Li LG, Kwan AKH (2021) Development of extrudable high strength fiber reinforced concrete incorporating nano calcium carbonate. Addit Manuf 37: 101617. https://doi.org/https://doi.org/10.1016/j.addma.2020.101617 doi: 10.1016/j.addma.2020.101617
[17]	Konsta-Gdoutos MS, Batis G, Danoglidis PA, et al. (2017) Effect of CNT and CNF loading and count on the corrosion resistance, conductivity and mechanical properties of nanomodified OPC mortars. Constr Build Mater 147: 48–57. https://doi.org/10.1016/j.conbuildmat.2017.04.112 doi: 10.1016/j.conbuildmat.2017.04.112
[18]	Cuenca E, Rigamonti S, Gastaldo Brac E, et al. (2021) Crystalline admixture as healing promoter in concrete exposed to chloride-rich environments: Experimental study. J Mater Civil Eng 33: 04020491. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003604 doi: 10.1061/(ASCE)MT.1943-5533.0003604
[19]	Cuenca E, Mezzena A, Ferrara L (2021) Synergy between crystalline admixtures and nano-constituents in enhancing autogenous healing capacity of cementitious composites under cracking and healing cycles in aggressive waters. Constr Build Mater 266: 121447. https://doi.org/10.1016/j.conbuildmat.2020.121447 doi: 10.1016/j.conbuildmat.2020.121447
[20]	Alatawna A, Birenboim M, Nadiv R, et al. (2020) The effect of compatibility and dimensionality of carbon nanofillers on cement composites. Constr Build Mater 232: 117141. https://doi.org/10.1016/j.conbuildmat.2019.117141 doi: 10.1016/j.conbuildmat.2019.117141
[21]	Qureshi TS, Panesar DK (2019) Impact of graphene oxide and highly reduced graphene oxide on cement based composites. Constr Build Mater 206: 71–83. https://doi.org/10.1016/j.conbuildmat.2019.01.176 doi: 10.1016/j.conbuildmat.2019.01.176
[22]	Lu L, Zhao P, Lu Z (2018) A short discussion on how to effectively use graphene oxide to reinforce cementitious composites. Constr Build Mater 189: 33–41. https://doi.org/10.1016/j.conbuildmat.2018.08.170 doi: 10.1016/j.conbuildmat.2018.08.170
[23]	Lu Z, Li X, Hanif A, et al. (2017) Early-age interaction mechanism between the graphene oxide and cement hydrates. Constr Build Mater 152: 232–239. https://doi.org/10.1016/j.conbuildmat.2017.06.176 doi: 10.1016/j.conbuildmat.2017.06.176
[24]	Sanchez F, Sobolev K (2010) Nanotechnology in concrete—A review. Constr Build Mater 24: 2060–2071. https://doi.org/10.1016/j.conbuildmat.2010.03.014 doi: 10.1016/j.conbuildmat.2010.03.014
[25]	Rehman F, Zhao C, Jiang H, et al. (2016) Biomedical applications of nano-titania in theranostics and photodynamic therapy. Biomater Sci 4: 40–54. https://doi.org/10.1039/C5BM00332F doi: 10.1039/C5BM00332F
[26]	Hassan MM, Dylla H, Mohammad LN, et al. (2010) Evaluation of the durability of titanium dioxide photocatalyst coating for concrete pavement. Constr Build Mater 24: 1456–1461. https://doi.org/10.1016/j.conbuildmat.2010.01.009 doi: 10.1016/j.conbuildmat.2010.01.009
[27]	Loh K, Gaylarde CC, Shirakawa MA (2018) Photocatalytic activity of ZnO and TiO₂ 'nanoparticles' for use in cement mixes. Constr Build Mater 167: 853–859. https://doi.org/10.1016/j.conbuildmat.2018.02.103 doi: 10.1016/j.conbuildmat.2018.02.103
[28]	Carp O, Huisman CL, Reller A (2004) Photoinduced reactivity of titanium dioxide. Prog Solid State Ch 32: 33–177. https://doi.org/10.1016/j.progsolidstchem.2004.08.001 doi: 10.1016/j.progsolidstchem.2004.08.001
[29]	Cassar L (2004) Photocatalysis of cementitious materials: clean buildings and clean air. MRS Bull 29: 328–331. https://doi.org/10.1557/mrs2004.99 doi: 10.1557/mrs2004.99
[30]	Folli A, Pade C, Hansen TB, et al. (2012) TiO₂ photocatalysis in cementitious systems: Insights into self-cleaning and depollution chemistry. Cement Concrete Res 42: 539–548. https://doi.org/10.1016/j.cemconres.2011.12.001 doi: 10.1016/j.cemconres.2011.12.001
[31]	Gopalan AI, Lee JC, Saianand G, et al. (2020) Recent progress in the abatement of hazardous pollutants using photocatalytic TiO₂-based building materials. Nanomaterials 10: 1854. https://doi.org/10.3390/nano10091854 doi: 10.3390/nano10091854
[32]	Chen J, Poon CS (2009) Photocatalytic construction and building materials: From fundamentals to applications. Build Environ 44: 1899–1906. https://doi.org/10.1016/j.buildenv.2009.01.002 doi: 10.1016/j.buildenv.2009.01.002
[33]	Chen F, Yang X, Mak HKC, et al. (2010) Photocatalytic oxidation for antimicrobial control in built environment: A brief literature overview. Build Environ 45: 1747–1754. https://doi.org/https://doi.org/10.1016/j.buildenv.2010.01.024 doi: 10.1016/j.buildenv.2010.01.024
[34]	Macphee DE, Folli A (2016) Photocatalytic concretes—The interface between photocatalysis and cement chemistry. Cement Concrete Res 85: 48–54. https://doi.org/https://doi.org/10.1016/j.cemconres.2016.03.007 doi: 10.1016/j.cemconres.2016.03.007
[35]	Hamidi F, Aslani F (2019) TiO₂-based photocatalytic cementitious composites: Materials, properties, influential parameters, and assessment techniques. Nanomaterials 9: 1444. https://doi.org/10.3390/nano9101444 doi: 10.3390/nano9101444
[36]	Essawy AA, Abd El.Aleem S (2014) Physico-mechanical properties, potent adsorptive and photocatalytic efficacies of sulfate resisting cement blends containing micro silica and nano-TiO₂. Constr Build Mater 52: 1–8. https://doi.org/10.1016/j.conbuildmat.2013.11.026
[37]	Chen J, Kou SC, Poon CS (2012) Hydration and properties of nano-TiO₂ blended cement composites. Cement Concrete Comp 34: 642–649. https://doi.org/10.1016/j.cemconcomp.2012.02.009 doi: 10.1016/j.cemconcomp.2012.02.009
[38]	Zhang R, Cheng X, Hou P, et al. (2015) Influences of nano-TiO₂ on the properties of cement-based materials: Hydration and drying shrinkage. Constr Build Mater 81: 35–41. https://doi.org/10.1016/j.conbuildmat.2015.02.003 doi: 10.1016/j.conbuildmat.2015.02.003
[39]	ASTM International (2021) Standard specification for standard sand. ASTM C778, West Conshohocken, PA. https://doi.org/10.1520/C0778-21
[40]	Yousefi A, Allahverdi A, Hejazi P (2013) Effective dispersion of nano-TiO₂ powder for enhancement of photocatalytic properties in cement mixes. Constr Build Mater 41: 224–230. https://doi.org/10.1016/j.conbuildmat.2012.11.057 doi: 10.1016/j.conbuildmat.2012.11.057
[41]	ASTM International (2021) Standard test method for compressive strength of hydraulic cement mortars (using 2-in. or 50 mm cube specimens). ASTM C109/C109M, West Conshohocken, PA. https://doi.org/10.1520/C0109_C0109M-21
[42]	Rajadesingu S, Arunachalam KD (2020) Hydration effect of boric acid on the strength of high-performance concrete (HPC). IOP Conf Ser Mater Sci Eng 912: 062073. https://doi.org/10.1088/1757-899X/912/6/062073 doi: 10.1088/1757-899X/912/6/062073
[43]	Davraz M (2015) The effect of boron compound to cement hydration and controllability of this effect. Acta Phys Pol A 128. https://doi.org/10.12693/APhysPolA.128.B-26
[44]	Volkman D, Bussolini P (1992) Comparison of fine particle colemanite and boron frit in concrete for time-strength relationship. J Test Eval 20: 92–96. https://doi.org/10.1520/JTE11903J doi: 10.1520/JTE11903J
[45]	Olgun A, Kavas T, Erdogan Y, et al. (2007) Physico-chemical characteristics of chemically activated cement containing boron. Build Environ 42: 2384–2395. https://doi.org/10.1016/j.buildenv.2006.06.003 doi: 10.1016/j.buildenv.2006.06.003
[46]	Targan Ş, Olgun A, Erdogan Y, et al. (2002) Effects of supplementary cementing materials on the properties of cement and concrete. Cement Concrete Res 32: 1551–1558. https://doi.org/10.1016/S0008-8846(02)00831-1 doi: 10.1016/S0008-8846(02)00831-1
[47]	Jayapalan A, Lee B, Kurtis K (2009) Effect of nano-sized titanium dioxide on early age hydration of Portland cement. Nanotechnology in Construction 3, Springer, Berlin, Heidelberg, 267–273. https://doi.org/10.1007/978-3-642-00980-8_35
[48]	Parveen S (2016) Microstructure and mechanical properties of nanomaterial reinforced cementitious composites. Universidade do Minho (Portugal). Available from: https://hdl.handle.net/1822/45268.

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