Research article Topical Sections

Thermodynamic and geochemical studies of formation water in Rag-e Sefid oil and gas field, Iran

  • Received: 14 June 2023 Accepted: 31 July 2023 Published: 06 September 2023
  • Nowadays, the concentration of mineral cations and anions in the formation water of oil and gas fields is a challenging issue for oil industry technicians managing the formation of mineral deposits during water injection operations. For this reason, the analysis of formation water mineral ions during exploitation operations can be a valuable solution for the efficient management of oil production. Therefore, in this research, the thermodynamic and geochemical evaluation of formation water in the Reg-e Sefid oil and gas field is considered. Based on the results of this study, the formation of calcium sulfate and calcium carbonate can be expected due to the concentration of mineral ions dissolved in the formation water in the Reg-e Sefid oil and gas field according to the StimCad2 software. Also, based on the evaluation of ion ratios, the studied oil and gas field formation has ideal conditions for hydrocarbon production. Based on the results obtained from the comparison of the water and rock formation of the Rag-e Sefid oil and gas field, the source of ions (except calcium and magnesium ions) is related to ancient sea water.

    Citation: Seyed Hossein Hashemi, Abas Niknam, Amir Karimian Torghabeh, Nuno Pimentel. Thermodynamic and geochemical studies of formation water in Rag-e Sefid oil and gas field, Iran[J]. AIMS Geosciences, 2023, 9(3): 578-594. doi: 10.3934/geosci.2023031

    Related Papers:

  • Nowadays, the concentration of mineral cations and anions in the formation water of oil and gas fields is a challenging issue for oil industry technicians managing the formation of mineral deposits during water injection operations. For this reason, the analysis of formation water mineral ions during exploitation operations can be a valuable solution for the efficient management of oil production. Therefore, in this research, the thermodynamic and geochemical evaluation of formation water in the Reg-e Sefid oil and gas field is considered. Based on the results of this study, the formation of calcium sulfate and calcium carbonate can be expected due to the concentration of mineral ions dissolved in the formation water in the Reg-e Sefid oil and gas field according to the StimCad2 software. Also, based on the evaluation of ion ratios, the studied oil and gas field formation has ideal conditions for hydrocarbon production. Based on the results obtained from the comparison of the water and rock formation of the Rag-e Sefid oil and gas field, the source of ions (except calcium and magnesium ions) is related to ancient sea water.



    加载中


    [1] Hashemi SH (2022) Thermodynamic study of interfacial tension between oil and aqueous phases composed of ionic liquids and brine. J Indian Chem Soc 99: 100508. https://doi.org/10.1016/j.jics.2022.100508 doi: 10.1016/j.jics.2022.100508
    [2] Nikseresht S, Farshchi Tabrizi F, Riazi M, et al. (2021)Thermodynamic prediction of interfacial tension of water/oil system with the presence surfactants and salt. Model Earth Syst Environ 8: 2193–2199. https://doi.org/10.1007/s40808-021-01217-1 doi: 10.1007/s40808-021-01217-1
    [3] McCain M (1999) Properties of Petroleum Fluids, 2nd edition. PennWell Corp.
    [4] Bagheri R, Miri M, Khabiri F, et al. (2019) Enhancing volume and salinity of production water in oil and gas wells, Case study: Mozduran gas reservoir. Iran J Petrol Geol 15: 1–18.
    [5] Hashemi SH, Mirzayi B, Mousavi Dehghani SA, et al. (2014) Investigation of the process of formation of mineral deposits in surface and sub-surface installations of oil fields. First International Conference on Oil, Gas and Petrochemicals with Sustainable Development Approach (University Relations with Industry), Tehran.
    [6] Hashemi SH, Mousavi Dehghani SA, Khodadadi H, et al. (2017) Optimization of Extended UNIQUAC Parameter for Activity Coefficients of Ions of an Electrolyte System Using Genetic Algorithms. Korean Chem Eng Res 55: 652–659. https://doi.org/10.9713/kcer.2017.55.5.652 doi: 10.9713/kcer.2017.55.5.652
    [7] Hashemi SH (2017) Thermodynamic Study of water activity of Single Strong Electrolytes. J Appl Comput Mech 3: 150–157. https://doi.org/10.22055/JACM.2017.12425 doi: 10.22055/JACM.2017.12425
    [8] Mirzayi B, Mousavi Dehghani SA, Hashemi SH, et al. (2016) Study and review of formation and removal of scale in oil recovery process. Farayandno 10: 100–112.
    [9] Jones F (1964) Influence of Chemical Composition of Water on Clay Blocking of Permeability. J Pet Technol 16: 441–446. https://doi.org/10.2118/631-PA doi: 10.2118/631-PA
    [10] Mungan N (1965) Permeability Reduction Through Changes in Ph and Salinity. J Pet Techno 17: 1449–1453. https://doi.org/10.2118/1283-PA doi: 10.2118/1283-PA
    [11] Oddo J, Smith J, Tomson M (1991) Analysis of and Solutions to the CaCO3 and CaSO4 Scaling Problems Encountered in Wells Offshore Indonesia. SPE Annual Technical Conference and Exhibition. Dallas, Texas. https://doi.org/10.2118/22782-MS
    [12] Chong TH, Sheikholeslami R (2001) Thermodynamics and Kinetics for Mixed Calcium Carbonate and Calcium Sulfate Precipitation. Chem Eng Sci 56: 5391–5400. https://doi.org/10.1016/S0009-2509(01)00237-8 doi: 10.1016/S0009-2509(01)00237-8
    [13] Bagci S, Kok M, Turksoy U (2001) Effect of brine and Alkaline Fluid on the permeability Damage of Limestone Reservoirs. Spe International Symposium on Oilfield Chemistry. Houston, Texas. https://doi.org/10.2118/65394-MS
    [14] Voloshin I, Ragulin A, Tyabayeva E, et al. (2003) Scaling Problems in Western Siberia. The International Symposium on Oilfield Scale. Aberdeen, UK. https://doi.org/10.2118/80407-MS
    [15] Abu-Khamsin S, Ahmad S (2005) Laboratory Study on Precipitation of Calcium Sulphate in Berea Sandstone Cores. SPE Technical Symposium of Saudi Arabia Section. Dhahran, Saudi Arabia. https://doi.org/10.2118/106336-MS
    [16] Hashemi SH, Din Mohammad M, Mousavi Dehghani SA (2019) Thermodynamic Prediction of Ba and Sr Sulfates Scale Formation in Waterflooding Projects in Oil Reservoirs. J Miner Resour Eng 22: 23–37.
    [17] Hashemi SH, Hashemi SA (2020) Prediction of Scale formation according to water injection operations in Nosrat Oil Field. Model Earth Syst Environ 6: 585–589. https://doi.org/10.1007/s40808-019-00664-1 doi: 10.1007/s40808-019-00664-1
    [18] Hashemi SH, Bagheri M, Hashemi SA (2020) Thermodynamic study of the effect of concentration and ionic strength on osmotic coefficient of aqueous sulfate and chloride solutions at 298.15 K. Model Earth Syst Environ 6: 2189–2196. https://doi.org/10.1007/s40808-020-00834-6 doi: 10.1007/s40808-020-00834-6
    [19] Hashemi SH, Mousavi Dehghani SA, Samimi SE, et al (2020) Performance comparison of GRG algorithm with evolutionary algorithms in an aqueous electrolyte system. Model Earth Syst Environ 6: 2103–2110. https://doi.org/10.1007/s40808-020-00818-6 doi: 10.1007/s40808-020-00818-6
    [20] Hashemi SH, Dinmohammad M, Bagheri M (2020) Optimization of Extended UNIQUAC model parameter for mean activity coefficient of aqueous chloride solutions using Genetic+PSO. J Chem Pet Eng 54: 1–12. https://doi.org/10.22059/jchpe.2020.254905.1225 doi: 10.22059/jchpe.2020.254905.1225
    [21] Rezaie AH, Nogole-Sadat MA (2004) Fracture Modeling in Asmari Reservoir of Rag-e Sefid Oil-Field by using Multiwell Image Log (FMS/FMI). Iranian Int J Sci 5: 107–121.
    [22] Motiei H (1995) Petroleum Geology of Zagros, Treatise on the Geology of Iran, Geological Survey of Iran Publication, 589.
    [23] Bidarvand N, Kohansal ghadimvand N, Jahani D (2011) Microfacies and sedimentary environment of the Asmari Formation in Rag-e-safid oil field, south west Khouzestan. J Environ Geol 5: 45–60.
    [24] Chaldavi AA, Sadeghi A, Amiri Bakhtiar H, et al. (2006) Introduction of the Gorpi formation in the north of Reg Sefid oil field in the southeast of Ahvaz, Dezful subsidence area. 10th Conference of the Geological Society of Iran. Tehran.
    [25] Sepehr M, Cosgrove JW (2004) Structural framework of the Zagros Fold–Thrust Belt, Iran. Mar Pet Geol 21: 829–843. https://doi.org/10.1016/j.marpetgeo.2003.07.006 doi: 10.1016/j.marpetgeo.2003.07.006
    [26] Betz L (1962) Betz Handbook of Industrial Water Conditioning, Sixth Edition. Publisher of Betz, Trevose, Pennsylvania.
    [27] Shariatpanahi SF, Strand S, Austad T (2011) Initial wetting properties of carbonate oil reservoirs: effect of the temperature and presence of sulfate in formation water. Energy Fuels 25: 3021–3028. https://doi.org/10.1021/ef200033h doi: 10.1021/ef200033h
    [28] Ellis A, Mahon W (1967) Natural hydrothermal systems and experimental hot water/rock interactions (Part Ⅱ). Geochim Cosmochim Acta 31: 519–538. https://doi.org/10.1016/0016-7037(67)90032-4 doi: 10.1016/0016-7037(67)90032-4
    [29] Giggenbach WF (1986) Graphical techniques for the evaluation of water/rock equilibration conditions by use of Na, K, Mg and Ca contents of discharge waters. Proc 8th New Zealand Geothermal Workshop, 37–44.
    [30] Gunter W, Perkins E, Hutcheon I (2000) Aquifer disposal of acid gases: modelling of water–rock reactions for trapping of acid wastes. Appl Geochem 15: 1085–1095. https://doi.org/10.1016/S0883-2927(99)00111-0 doi: 10.1016/S0883-2927(99)00111-0
    [31] Ellis A, Mahon W (1964) Natural hydrothermal systems and experimental hot-water/rock interactions. Geochim Cosmochim Acta 28: 1323–1357. https://doi.org/10.1016/0016-7037(64)90132-2 doi: 10.1016/0016-7037(64)90132-2
    [32] Bijani M, Khamechi E (2019) Investigation and Prediction of Corrosion and Scaling Tendency in Wastewater Pipelines and Tubings of Disposal Wells of Rag-e-safid Crude-Oil Desalting Unit. Pet Res 29: 26–28. https://doi.org/10.22078/PR.2019.3662.2672 doi: 10.22078/PR.2019.3662.2672
    [33] De Choudens-Sanchez V, Gonzalez LA (2009) Calcite and aragonite precipitation under controlled instantaneous supersaturation: elucidating the role of CaCO3 saturation state and Mg/Ca ratio on calcium carbonate polymorphism. J Sediment Res 79: 363–376. https://doi.org/10.2110/jsr.2009.043 doi: 10.2110/jsr.2009.043
    [34] Osborn SG, Vengosh A, Warner NR, et al. (2011) Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing. Proc Natl Acad Sci 108: 8172–8176. https://doi.org/10.1073/pnas.1100682108 doi: 10.1073/pnas.1100682108
    [35] Rice CA, Flores RM, Stricker GD, et al. (2008) Chemical and stable isotopic evidence for water/rock interaction and biogenic origin of coalbed methane, Fort Union Formation, Powder River Basin, Wyoming and Montana USA. Int J Coal Geol 76: 76–85. https://doi.org/10.1016/j.coal.2008.05.002 doi: 10.1016/j.coal.2008.05.002
    [36] Ranasinghe PN, Dissanayake CB, Rupasinghe MS (2005) Application of geochemical ratios for delineating gem-bearing areas in high grade metamorphic terrains. Appl Geochem 20: 1489–1495. https://doi.org/10.1016/j.apgeochem.2005.02.009 doi: 10.1016/j.apgeochem.2005.02.009
    [37] Zheng YF (2012) Metamorphic chemical geodynamics in continental subduction zones. Chem Geol 328: 5–48. https://doi.org/10.1016/j.chemgeo.2012.02.005 doi: 10.1016/j.chemgeo.2012.02.005
    [38] Yu HY, Wang ZL, Rezaee R, et al. (2020) Formation water geochemistry for carbonate reservoirs in Ordos basin, China: Implications for hydrocarbon preservation by machine learning. J Pet Sci Eng 185: 106673. https://doi.org/10.1016/j.petrol.2019.106673 doi: 10.1016/j.petrol.2019.106673
    [39] Nader FH, Swennen R (2004) The hydrocarbon potential of Lebanon: new insights from regional correlations and studies of Jurassic dolomitization. J Pet Geol 27: 253–275. https://doi.org/10.1111/j.1747-5457.2004.tb00058.x doi: 10.1111/j.1747-5457.2004.tb00058.x
    [40] Folk RL, Land LS (1975) Mg/Ca ratio and salinity: two controls over crystallization of dolomite. AAPG Bull 59: 60–68. https://doi.org/10.1306/83D91C0E-16C7-11D7-8645000102C1865D doi: 10.1306/83D91C0E-16C7-11D7-8645000102C1865D
    [41] Koleini MM, Mehraban MF, Ayatollahi S (2018) Effects of low salinity water on calcite/brine interface: A molecular dynamics simulation study. Colloids Surf A 537: 61–68. https://doi.org/10.1016/j.colsurfa.2017.10.024 doi: 10.1016/j.colsurfa.2017.10.024
    [42] Lear CH, Rosenthal Y, Slowey N (2002) Benthic foraminiferal Mg/Ca-paleothermometry: A revised core-top calibration. Geochim Cosmochim Acta 66: 3375–3387. https://doi.org/10.1016/S0016-7037(02)00941-9 doi: 10.1016/S0016-7037(02)00941-9
    [43] Nielsen MR, Sand KK, Rodriguez-Blanco JD, et al (2016) Inhibition of calcite growth: combined effects of Mg2+ and SO42–. Cryst Growth Des 16: 6199–6207. https://doi.org/10.1021/acs.cgd.6b00536 doi: 10.1021/acs.cgd.6b00536
    [44] Wilkinson BH, Algeo TJ (1989) Sedimentary carbonate record of calcium-magnesium cycling. Am J Sci 289: 1158–1194. https://doi.org/10.2475/ajs.289.10.1158 doi: 10.2475/ajs.289.10.1158
    [45] Van Voast WA (2003) Geochemical signature of formation waters associated with coalbed methane. AAPG Bull 87: 667–676. https://doi.org/10.1306/10300201079 doi: 10.1306/10300201079
    [46] Yuan BC, Xu XG, Li ZZ, et al (2007) Microbial biomass and activity in alkalized magnesic soils under arid conditions. Soil Biol Biochem 39: 3004–3013. https://doi.org/10.1016/j.soilbio.2007.05.034 doi: 10.1016/j.soilbio.2007.05.034
    [47] Zeebe RE (1999) An explanation of the effect of seawater carbonate concentration on foraminiferal oxygen isotopes. Geochim Cosmochim Acta 63: 2001–2007. https://doi.org/10.1016/S0016-7037(99)00091-5 doi: 10.1016/S0016-7037(99)00091-5
    [48] Deines P, Langmuir D, Harmon RS (1974) Stable carbon isotope ratios and the existence of a gas phase in the evolution of carbonate ground waters. Geochim Cosmochim Acta 38: 1147–1164. https://doi.org/10.1016/0016-7037(74)90010-6 doi: 10.1016/0016-7037(74)90010-6
    [49] Chen T, Neville A, Yuan M (2005) Calcium carbonate scale formation—assessing the initial stages of precipitation and deposition. J Pet Sci Eng 46: 185–194. https://doi.org/10.1016/j.petrol.2004.12.004 doi: 10.1016/j.petrol.2004.12.004
    [50] Kurita Y, Nakada T, Kato A, et al (2008) Identification of intestinal bicarbonate transporters involved in formation of carbonate precipitates to stimulate water absorption in marine teleost fish. Am J Physiol 294: R1402–R1412. https://doi.org/10.1152/ajpregu.00759.2007 doi: 10.1152/ajpregu.00759.2007
    [51] Palandri JL, Reed MH (2001) Reconstruction of in situ composition of sedimentary formation waters. Geochim Cosmochim Acta 65: 1741–1767. https://doi.org/10.1016/S0016-7037(01)00555-5 doi: 10.1016/S0016-7037(01)00555-5
  • Reader Comments
  • © 2023 the Author(s), licensee AIMS Press. This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0)
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Metrics

Article views(10739) PDF downloads(92) Cited by(0)

Article outline

Figures and Tables

Figures(6)  /  Tables(5)

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return

Catalog